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Use of a duplex steel alloy

A duplex stainless steel and alloy technology, applied in the field of stainless steel alloys, can solve problems such as microstructure imbalance, and achieve good thermal processing performance and good machinability

Inactive Publication Date: 2009-09-16
SANDVIK INTELLECTUAL PROPERTY AB
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Mainly due to the unbalanced microstructure caused by the precipitation of σ (sigma) crystal phase, the super duplex alloy Zeron 100 has problems during welding

Method used

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  • Use of a duplex steel alloy
  • Use of a duplex steel alloy
  • Use of a duplex steel alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] The test specimens for this example were produced by casting an ingot weighing 170 kg in the laboratory and subsequently hot forging it into a round bar. They were hot extruded into bars (flat bars as well as round bars) from which the test material was selected. In addition, the flat bars were annealed prior to cold rolling and subsequently other experimental materials were obtained. From a materials engineering point of view, the process can be taken as representative of larger-scale fabrication, such as the production of stainless steel tubes by extrusion followed by cold rolling. Table 1 shows the composition of the first experimental samples.

[0049] Table 1 Experimental sample composition, wt%

[0050] C

mn

Cr

Ni

Mo

W

co

N

605193

1.03

27.90

8.80

4.00

0.01

0.02

0.36

605195

0.97

27.90

9.80

4.00

0.01

0.97

0.48

...

Embodiment 2

[0071] In the following examples, the composition of other test samples produced in order to find the optimal composition is given. These samples were varied starting from the properties of the samples with good structural stability and high corrosion resistance from the results shown in the examples. All samples in Table 7 include the components described in the present invention, wherein the samples numbered as No. 1-8 only include the statistical test mode, and the samples numbered as e-n have added the components described in the present invention. alloy.

[0072] The sample is obtained from a 270kg steel ingot by casting and hot forging into round steel. Test specimens were selected by extruding these round bars into bars. The bars are then annealed before being cold rolled into flat bars, after which material is selected for further testing. Table 7 shows the composition of these test samples.

[0073] Table 7

[0074] sample

mn

Cr

Ni

Mo...

Embodiment 3

[0105] The petroleum refining process is very complex and includes many steps, where non-hydrocarbons such as inorganic chlorides cause substantial corrosion problems. Besides Na-, Mg and Ca-chlorides, crude oil also contains different kinds of salts. Inorganic salt MgCl 2 and CaCl 2 The most dangerous because of the hydrolysis of inorganic salts during heating to produce hydrochloric acid (HCl). In refinery equipment in refineries, hydrochloric acid can condense on material used in overhead condensers. The formation of hydrochloric acid can lead to serious corrosion problems, especially in combination with solid salts present on material surfaces, which also occur frequently. Corrosion problems in overhead condensers in refineries involve general corrosion, pitting corrosion, and crevice corrosion.

[0106] In some production facilities, it is the cooling water rather than the process fluid that causes corrosion problems. The chloride content in cooling water can vary fr...

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Abstract

A method of providing corrosion resistance, structural stability, mechanical strength and workability in applications with aggressive environments such as chloride-containing environments, are realized by providing at least one article formed from a composition which includes (in weight- %) up to 0.03% C, up to 0.5% Si, 24.0-30.0% Cr, 4.9-10.0% Ni, 3.0-5.0% Mo, 0.28-0.5% N, 0-3.0% Mn, 0-0.0030% B, up to 0.010%, 0-0.03% Al, 0-0.010% Ca, 0-3.0% W, 0-2.0% Cu, 0-3.5% Co, 0-0.3% Ru, balance Fe and inevitable impurities. The ferrite content is 40 to 65 volume % and a PRE number of at least between 46 and 50 in both the austenite and ferrite phase, and with an optimum ratio or relationship between PRE austenite and PRE ferrite in the range of 0.90 to 1.15; preferably between 0.9 and 1.05.

Description

technical field [0001] The present invention relates to a stainless steel alloy, more precisely to a duplex stainless steel containing a ferritic-austenitic matrix together with high corrosion resistance, good structural stability and mechanical properties which make it suitable for In highly corrosive environments containing chlorides such as petroleum refining and hydrometallurgical processing. Background technique [0002] Considering that naturally accessible natural resources such as ores and metals have become more and more limited, and the mineral deposits are becoming less and less and the quality is getting worse day by day, human beings are committed to finding new mines or so far due to the high cost of mining and later finishing. High and unexplored mineral deposits. For example, rocks containing minerals are very hard and their conventional unbearable mining conditions prevail such as high temperature, polluted environment and saline groundwater. Specifically,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/44C22C38/52C22C38/54B23K35/30C22C38/00C22C38/58
CPCC22C38/54B23K35/3086C22C38/44C21D2211/005C22C38/52C22C38/58C21D2211/001
Inventor 安·森德斯特龙安娜-莱娜·奈斯特龙帕西.坎加斯
Owner SANDVIK INTELLECTUAL PROPERTY AB