Method for sequencing batch type nitrogen, phosphorus, and COD pollution burthen of high concentration waste water

A high-concentration wastewater and pollution load technology, applied in the field of environmental engineering, can solve problems such as increased processing costs, excessive land occupation, and easy blockage of stripping towers

Inactive Publication Date: 2007-09-26
RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, for the treatment of high-concentration septic tank sewage and aquaculture wastewater, it is difficult to achieve efficient removal of wastewater nitrogen or phosphorus by flocculation sedimentation or biological single technology; the method of combining flocculation sedimentation and biological treatment is complicated in operation and management due to the complexity of the process. It is cumbersome, the treatment cost is high, and the biological treatment is limited by geographical conditions, so the treatment effect is not ideal; generally, the A2 / O (anoxic / aerobic / anaerobic process) method has a better effect of removing nitrogen and phosphorus in wastewater treatment, but for ammonia nitrogen When the concentration reaches 300mg / l and the effluent requirements meet the secondary standard of "Pollutant Discharge Standards for Urban Sewage Treatment Plants--GB 18918-2002", theoretically a wastewater reflux ratio >10 is required. Such a high reflux ratio requirement makes the treatment cost obvious. increase, otherwise the standard discharge cannot be achieved; due to the high nitrogen load in the influent and the poor nitrogen removal effect, a considerable number of wastewater treatment plants cannot operate stably and discharge up to the standard; the calcium oxide treatment tower stripping absorbs high-concentration wastewater for denitrification, and the equipment is complex and High requirements for operation and management, easy clogging of stripping towers, secondary pollution caused by ammonia emissions from stripping, and high costs limit its application; free surface absorption denitrification method occupies too much land resources, cannot efficiently denitrify and significantly reduce other pollutant load

Method used

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  • Method for sequencing batch type nitrogen, phosphorus, and COD pollution burthen of high concentration waste water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] 10L of farm wastewater was placed in the stripping tank. The pH value of the wastewater was 7.90, the ammonia nitrogen was 823.67mg / l, the total nitrogen was 831.32mg / l, the total phosphorus was 29.83mg / l, and the COD was 5679.9mg / l. Using milk of lime with a mass ratio of calcium oxide to water of 1:20, the pH value of the wastewater was adjusted to 10.56 under stirring conditions, the stripping time was 20 hours, and the gas-liquid ratio was 5000:1. After treatment, the pH value of the effluent was 9.35, and the removal rates of pollutant indicators ammonia nitrogen, total nitrogen, total phosphorus and COD were 82.9%, 83.0%, 85.0% and 75.4%, respectively.

Embodiment 2

[0016] 20L of farm wastewater was placed in the stripping tank. The pH value of the wastewater was 8.26, the ammonia nitrogen was 947.67mg / l, the total nitrogen was 950.67mg / l, the total phosphorus was 52.94mg / l, and the COD was 5896.2mg / l. Using milk of lime with a mass ratio of calcium oxide to water of 1:50, the pH value of the wastewater is adjusted to 10.39 under stirring conditions, the stripping time is 20 hours, and the gas-liquid ratio is 5000:1. After treatment, the pH value of the effluent was 8.66, and the removal rates of pollutant indicators ammonia nitrogen, total nitrogen, total phosphorus and COD were 66.4%, 66.3%, 77.9% and 59.6%, respectively.

Embodiment 3

[0018] 20L of farm wastewater was placed in the stripping tank. The pH value of the wastewater was 8.04, the ammonia nitrogen was 903.38mg / l, the total nitrogen was 910.6mg / l, the total phosphorus was 31.16mg / l, and the COD was 6328.7mg / l. Using milk of lime with a mass ratio of calcium oxide to water of 1:50, the pH value of the wastewater was adjusted to 11.18 under stirring conditions, the stripping time was 20 hours, and the gas-liquid ratio was 5000:1. After treatment, the pH value of the effluent was 8.66, and the removal rates of pollutant indicators ammonia nitrogen, total nitrogen, total phosphorus and COD were 98.5%, 98.4%, 88.5% and 69.2%, respectively.

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Abstract

The invention discloses a highly effective denitrification, synchronizing dephosphorize, sterilization disinfection, effectively remove COD contaminant and one-step realize pH discharge disposing method of high concentration septic tank domestic sewage and breeding waste water in environmental engineering technology domain, which comprises the following steps: making calcium oxide as dominant water treatment agent; adjusting pH value of waste water; transforming nitrogen compound to free ammonia; proceeding blending flocculation and chemical precipitation with deposit contaminant; proceeding surface blow-off continually; dissolving free ammonia into absorption liquid; reclaiming. The contaminant clearance is 82.2%-90.3% ammonia nitrogen, 82.0%-90.2% total nitrogen, 84.4%-97.0% total phosphor, 52.5%-78.8% COD, waste water pH<=9, which can realize synchronizing disinfection. The discharging water can discharge directly or proceed future dispose.

Description

Technical field [0001] The invention belongs to the technical field of environmental engineering, relates to a method for treating wastewater containing high pollutant load, especially high-concentration ammonia nitrogen pollutants, and is a process method for strengthening primary wastewater treatment. Background technique [0002] The concentration of pollutants such as nitrogen, phosphorus, and COD in septic tank domestic sewage and aquaculture wastewater is very high. Domestic sewage generally has ammonia nitrogen > 100mg / l, total phosphorus > 15mg / l, and COD > 600mg / l. The concentration of pollutants in aquaculture wastewater is as high as Several times or even dozens of times that of domestic sewage. The discharge of high-concentration domestic sewage and aquaculture wastewater has deteriorated the water environment, and eutrophication of a considerable number of natural water bodies has occurred frequently, resulting in a shortage of water resources including...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/66C02F1/20C02F1/52C02F101/16C02F103/20
Inventor 穆环珍张占业黄衍初
Owner RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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