Method forpreparing iron concentrate for making iron from phosphorus-containing oolitic hematite

A technology for oolitic hematite and iron concentrate, applied in the direction of improving process efficiency, etc., can solve the problem of low iron grade and recovery rate of iron concentrate, unexplored iron concentrate for ironmaking, complicated intercalation relationship, etc. problem, to achieve the effect of improving the sorting effect, low cost and good dephosphorization effect

Inactive Publication Date: 2007-10-17
CENT SOUTH UNIV
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Problems solved by technology

[0003] In recent years, with the rapid development of my country's iron and steel industry, the supply of iron ore has become increasingly tight, and the research on using domestic phosphorus-containing oolitic hematite resources to prepare iron concentrates for ironmaking has been put on the agenda. From the research situation that has been carried out From the point of view, so far, the research work of using phosphorus-containing oolitic hematite ore to prepare iron concentrate for ironmaking mainly includes: reverse flotation process, selective agglomeration-reverse flotation, high gradient magnetic separation, ultra-fine Grinding-selective flocculation (agglomeration)-weak magnetic separation or flotation, fine grinding-gravity separation-magnetic separation, fine grinding-multiple gravity separation, direct reduction method, acid leaching, chlorination roasting-acid leaching process, etc., However, due to the complex intercalation relationship between hematite and quartz, kaolinite and collophosite in oolitic hematite ore, most of these methods have low iron grade and recovery rate of the obtained iron concentrate, high phosphorus content, and technical problems. Long process, high cost, etc. Although some scholars have used Thiobacillus to dephosphorize the obtained iron concentrate, the dephosphorization rate is only about 42%.
It can be said that an effective method for preparing iron concentrates for ironmaking by using oolitic hematite resources that can be used in large-scale industrial applications has not yet been explored.

Method used

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  • Method forpreparing iron concentrate for making iron from phosphorus-containing oolitic hematite

Examples

Experimental program
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Effect test

Embodiment 1

[0012] Example 1, referring to the accompanying drawings, the "Ningxiang type" oolitic hematite with a TFe of 35.27% and a P of 0.82%, is wet-ground to a particle size of less than 0.074mm and accounts for 40% of the mass percentage of the whole hematite %, adjust the pulp concentration to 20%, add water glass with an amount of 0.5kg / t as a dispersant and stir to fully disperse the pulp, use spiral chute for sorting, and regrind the obtained primary concentrate until the particle size is less than 0.074mm, accounting for 80% About 0.2kg / t of water glass is added as a dispersant, and the shaker is used for separation. The obtained iron concentrate is dephosphorized by leaching with 0.5% sulfuric acid for 5 minutes, and the obtained iron grade is 62.21%, and the recovery rate is 52.30%. Iron concentrate with a P content of 0.058%.

Embodiment 2

[0013] Embodiment 2, see accompanying drawing, TFe is 35.27%, P is the oolitic hematite of 0.82%, and the hematite of grain size less than 0.074mm accounts for about 50% of the mass percentage of whole hematite by wet grinding, adjusts the slurry When the concentration reaches 25%, add 0.7kg / t of water glass as a dispersant and stir to fully disperse the ore pulp. Use spiral chute for separation, and then grind the obtained primary concentrate until the particle size is less than 0.074mm, accounting for about 80%. The added amount is 0.3kg / t water glass is used as dispersant, separated by shaking table, and the obtained iron concentrate is dephosphorized by leaching with 1.0% sulfuric acid for 10 minutes. The obtained iron grade is 63.12%, the recovery rate is 51.50%, and the P content is 0.055%. of iron concentrate.

Embodiment 3

[0014] Example 3, referring to the accompanying drawings, TFe is 37.51%, P is oolitic hematite of 0.88%, wet grinding until the hematite with particle size less than 0.074mm accounts for about 60% of the mass percentage of the whole hematite, adjust the slurry When the concentration reaches 30%, add water glass at an amount of 1kg / t as a dispersant and stir to fully disperse the ore pulp, and use a spiral chute for separation. kg / t of water glass as dispersant, separated by shaking table, the obtained iron concentrate is dephosphorized by leaching with 1% sulfuric acid for 10 minutes, and the grade of iron can be 63.35%, the recovery rate is 50.89%, and the P content is 0.050%. iron concentrate.

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Abstract

The invention discloses a method of producing iron ore concentrate containing roe - like phosphorus hematite for iron manufacture, comprising crashing the roe - like ore, wet grinding until the hematite of granularity < 0.074mm are 40-60 mass% of whole hematite, adjusting the pulp mass percent concentration to 20%-30%, adding the water glass as dispersant of 0.5-1.0kg / t, agitating adequately, selecting by helix shoot, grinding produced ore concentrate until the one with the granularity < 0.074mm are more than 80 mass%, having the water glass as dispersant of 0.2-0.5kg / t, agitating to disperse uniformly, then selecting by shaking table, washing produced iron ore concentrate in room temperature by 0.5%-1.5% dilute sulfuric acid solution for 5-15 minutes, centrifugal separation, in which the solid are iron ore concentrate. The invention treats the roe - like phosphorus hematite to obtain the iron ore concentrate with a tenor of 62%, P content less than 0.06%. The invention can fully and reasonably apply rich roe - like phosphorus hematite resource in our country, has a good effect of dephosphorization and a low cost. And produced iron ore concentrate have a high recovery ratio.

Description

technical field [0001] The invention relates to a method for preparing iron concentrate for ironmaking from oolitic hematite, in particular to a method for preparing iron concentrate for ironmaking from oolitic hematite with higher phosphorus content. Background technique [0002] my country's oolitic hematite ore reserves are abundant, but due to the complex intercalation relationship between hematite and quartz, kaolinite and collophosite, it is recognized as one of the most difficult iron ore types. At the same time, the ore belongs to high Phosphate ore, qualified iron ore concentrate that can be directly used for blast furnace ironmaking can not be obtained after sorting. Therefore, oolitic hematite resources are basically not utilized at present. [0003] In recent years, with the rapid development of my country's iron and steel industry, the supply of iron ore has become increasingly tight, and the research on using domestic phosphorus-containing oolitic hematite reso...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/08C22B1/14
CPCY02P10/20
Inventor 姜涛郭宇峰邱冠周张亦军李光辉杨永斌董海刚范晓慧黄柱成付刚华张元波
Owner CENT SOUTH UNIV
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