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Supplementary decoloration process for dye-containing waste water

A dye wastewater and process technology, applied in the field of supplementary decolorization process, can solve the problems of high treatment cost of decolorization process, interference with wastewater reuse effect, and inability to be popularized.

Inactive Publication Date: 2007-10-24
XIAMEN ZHONGMIN GLOBAL ENVIRONMENTAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing decolorization process has high treatment costs and slow reaction speed, so additional treatment equipment and places are required, and the investment cost is relatively high; and the residual substances such as hypochlorite and iron ions after treatment seriously interfere with the wastewater reuse effect
Some foreign companies use NaBH 4 The reduction method is used to decolorize wastewater in affiliated sites, the effect is very good and the wastewater can be reused after decolorization, but NaBH 4 The price is expensive (the price is about 180 yuan / kg), and it cannot be promoted
Common cheap and strong reducing substances such as Diaobai powder are highly toxic, and the general aqueous solution of sodium dithionite is extremely unstable, so they have not been used in the decolorization of dye-containing wastewater.
In addition, the problem of excess drug removal during reductive decolorization in practical applications has not yet been resolved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] The supplementary decolorization process of the dye-containing wastewater of the present invention is realized through the following steps:

[0014] One, use sodium dithionite, sodium carbonate and water to prepare an alkaline sodium dithionite solution with a pH value of 12 and a weight percentage of sodium dithionite of 10%, and set it in the outlet channel of the discharge water at the connection pipe mouth Store air-tight in plastic containers. Be mixed with sulfuric acid and water and be made into the sulfuric acid solution that pH value is 2 with another container that also is to connect pipeline mouth and be arranged in the outlet channel of discharge water and preserve.

[0015] 2. Use a multi-blade stirring machine to mix the alkaline sodium dithionite solution prepared in step 1 with the colored wastewater from printing and dyeing after passing through the sand filter (chroma 60 degrees, the main colored components are reactive brilliant red X-3, bright yellow...

Embodiment 2

[0017] The supplementary decolorization process of the dye-containing wastewater of the present invention is realized through the following steps:

[0018] 1. Use sodium dithionite, trona and water to prepare an alkaline sodium dithionite solution with a pH value of 10 and a weight percentage of sodium dithionite of 15%. Store air-tight in plastic containers. Be mixed with sulfuric acid and water and be made into the sulfuric acid solution that pH value is 1 with another container that also is to connect pipeline mouth and be arranged in the outlet channel of discharge water and preserve.

[0019] Two, use the multi-blade stirring machine to mix the alkaline sodium dithionite solution prepared in step 1 with the dye factory dye wastewater (chromaticity 83 degrees, colored components are active black KN-B, active bright yellow B-4GLN) after the sand filter Mixture) is quickly mixed to form mixed water, wherein the consumption of alkaline sodium dithionite is 0.007% of the wast...

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PUM

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Abstract

The invention discloses a supplementing decoloring technique of waste water with dye, which comprises the following steps: reserving alkali solution and acid solution of sodium dithionite in the seal container separately; blending the waste water with dye and alkali solution of sodium dithionite under high-speed stirring condition; leading the acid solution to neutrallize the waste water with dye; supplementing the decoloring; bubbling the decolored water through aerating pipe; oxidizing the excessive reduced material; placing the seal container and aerating pipe in the water outlet canal of waste water with dye. The invention reduces cost without changing the present equipment, which is benefit to recycle the waste water directly.

Description

technical field [0001] The invention relates to a supplementary decolorization process for dye-containing wastewater. Background technique [0002] Dyestuffs and dye intermediate production plants, bleaching and dyeing industry is a light industry in a pillar position in our country. Textile printing and dyeing wastewater has a large amount of water, high chroma, and complex components. The wastewater contains dyes, sizing, auxiliaries, acids, alkalis, fiber impurities, and inorganic salts. Common decolorization methods include biochemical decolorization (lowest cost, but cannot decolorize biologically toxic dyes), oxidative decolorization (better effect, slower decolorization speed), reductive decolorization (for biologically toxic dyes such as unsaturated bonds, Aldehyde dyes have a particularly good decolorization effect). At present, most printing and dyeing factories adopt biochemical treatment methods, that is, the use of microbial methods to degrade conventional dye...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F1/70C02F1/74C02F1/66C02F103/30
Inventor 陈楷翰袁建军张清渊连海林庄光耀陈清施陈延民
Owner XIAMEN ZHONGMIN GLOBAL ENVIRONMENTAL
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