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Zirconium chromium corundum honeycomb ceramic heat accumulator

A technology of zirconium-chromium corundum and honeycomb ceramics, which is applied in the field of ceramics, can solve the problems of low temperature resistance of honeycomb ceramic regenerators, affecting the energy-saving effect of regenerative heating furnaces, and low stability of resistance to rapid cooling and rapid heating, etc. Economic and social benefits, rapid and uniform heat exchange, good shock resistance and thermal stability

Inactive Publication Date: 2008-02-20
萍乡市中天化工填料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The small-diameter spherical or spot-welded ceramic ball regenerator developed in the 1980s can make the regenerative heating furnace compact in structure, and better solve the problems of large system volume and low thermal efficiency of the traditional checker brick regenerator. However, the specific surface area of ​​the small-diameter spherical or spot-welded ceramic ball regenerator is small, and the pressure drop generated during use is large, so the use is limited
However, there are still some shortcomings in the use of the above-mentioned honeycomb ceramic regenerators: First, the temperature resistance of the honeycomb ceramic regenerators is not high. The heat body works in an environment above 1500°C; the second is that the heat capacity is low, generally below 1300J / KgK, the resistance to rapid cooling and rapid heating is low, and it cannot be used for a long time, which affects the energy-saving effect of the regenerative heating furnace and the emission of flue gas The amount is relatively high, but the economic and social benefits are not high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Example 1, the zirconium chromium corundum new honeycomb ceramic regenerator is made of corundum powder, α-Al 2 o 3 powder, clay, MgO, organic cellulose, tung oil, Cr 2 o 3 Powder and ZrO 2 Powder composition, the weight percentage of each component is: corundum powder 45%, α-Al 2 o 3 Powder 25%, clay 7%, MgO 6%, organic cellulose 5%, tung oil 4%, Cr 2 o 3 Powder 4% and ZrO 2 Powder 4%, the weight percentage of the chemical composition of the new honeycomb ceramic regenerator made of zirconium chromium corundum is: Al 2 o 3 58.6%, SiO 2 23.5%, ZrO 2 4%, Cr 2 o 3 4% and MgO 8%, its impurity Fe 2 o 3 0.5%, Na 2 O+K 2 The content of O+CaO is 0.8%, and it is prepared according to the following steps of the preparation method.

[0014] 1. Combine corundum powder, α-Al 2 o 3 Powder, clay, organic cellulose, MgO, Cr 2 o 3 Powder and ZrO 2 After the powder is uniformly mixed according to the percentage by weight described in Example 1, then add tung oil in...

Embodiment 2

[0023] Example 2, the zirconium chromium corundum new honeycomb ceramic regenerator is made of corundum powder, α-Al 2 o 3 powder, clay, MgO, organic cellulose, tung oil, Cr 2 o 3 Powder and ZrO 2 Powder composition, the weight percentage of each component is: corundum powder 50%, α-Al 2 o 3 Powder 20%, clay 5%, MgO3%, organic cellulose 3%, tung oil 7%, Cr 2 o 3 Powder 6% and ZrO 2 Powder 6%, the above-mentioned components are mixed, rolled, extruded and calcined according to the proportion, and the weight percentage of the chemical composition of the new honeycomb ceramic regenerator made of zirconium chromium corundum is: Al 2 o 3 57.5%, SiO 2 24.3%, ZrO 2 6%, Cr 2 o 3 6% and MgO 5%, impurity Fe 2 o3 0.65%, Na 2 O+K 2 O+CaO is 0.55%, prepared according to the steps of the preparation method in Example 1.

[0024] Present embodiment 2 detects each technical index is:

[0025] Compressive strength: 16.2MPa, heat capacity (20-1000°C) / J / KgK: 1450,

[0026] Temp...

Embodiment 3

[0028] Example 3, the zirconium chromium corundum new honeycomb ceramic regenerator is made of corundum powder, α-Al 2 o 3 powder, clay, MgO, organic cellulose, tung oil, Cr 2 o 3 Powder and ZrO 2 Powder composition, the weight percentage of each component is: corundum powder 40%, α-Al 2 o 3 Powder 30%, clay 8%, MgO 8%, organic cellulose 5%, tung oil 3%, Cr 2 o 3 Powder 3% and ZrO 2 Powder 3%, the above-mentioned components are mixed, rolled, extruded and calcined according to the proportion, and the weight percentage of the chemical composition of the zirconium chromium corundum new honeycomb ceramic regenerator is: Al 2 o 3 66.2%, SiO 2 17.5%, ZrO 2 3%, Cr 2 o 3 3% and MgO 9%, impurity Fe 2 o 3 0.45%, Na 2 O+K 2 O+CaO is 0.6%. Prepared according to the steps of the preparation method in Example 1.

[0029] Present embodiment 3 is through detecting each technical index is:

[0030] Compressive strength: 14.8MPa, heat capacity (20-1000°C) / J / KgK: 1350,

[00...

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Abstract

The invention discloses a novel zirconium and cadmium corundum honeycomb ceramics heat retainer consisting of schmigel, Alpha-Al2O3 powder, clay, MgO, organic fibrin, tung oil, Cr2O3 and ZrO2 powder, with weight ratio of each component of 40-50 percent, 20-30 percent, 5-10 percent, 3-10 percent, 3-8 percent, 3-7 percent, 3-7 percent and 3-7 percent in sequence. The weight percentage of heat retainer chemical components is that: 48-60 percent of Al2O3, 16-25 percent of SiO2, 3-7 percent of ZrO2, 3-7 percent of Cr2O3, 3-15 percent of MgO. The invention can be arranged into a regenerative heating furnace and applicable to the invention of temperature below 1500 DEG C, save fuel up to 40-70 percent, improve output more than 15 percent, decrease the discharge of NOX gas to less than 100ppm and lead the smog discharge temperature to be less than 150 DEG C, thereby obviously improving firing effect, greatly reducing the discharge of harmful gas, prolonging the service life of the regenerative heating furnace, improving the environment and enhancing economic benefit and social benefit.

Description

technical field [0001] The invention relates to ceramics, in particular to a novel honeycomb ceramic regenerator made of zirconium chromium corundum. Background technique [0002] At present, the regenerative high-temperature air combustion technology (HTAC) with dual effects of energy saving and environmental protection has been widely used in various industrial furnaces such as steel and petrochemical furnaces. It can improve the combustion effect and save energy. It can also reduce harmful gas emissions and reduce environmental pollution. As the key component in the regenerative heating furnace - the regenerator, the performance index and thermal efficiency of the regenerative heating furnace directly depend on the performance of the regenerator. The small-diameter spherical or spot-welded ceramic ball regenerator developed in the 1980s can make the regenerative heating furnace compact in structure, and better solve the problems of large system volume and low thermal eff...

Claims

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Application Information

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IPC IPC(8): C04B35/105C04B35/106F28D20/00
CPCY02E60/142Y02E60/14
Inventor 潘国明谭焕斌邬树其钟余萍施志才邬梅虎
Owner 萍乡市中天化工填料有限公司