Flame-resistant vinyl benzene polymer foam plastic

A technology of styrene polymer and foamed polymer, applied in the field of flame-retardant polystyrene foam, can solve the problems of physical and chemical properties, structure, apparent production process influence, physical properties decline, molecular weight reduction, etc. Good application prospects, lower glass transition temperature, and satisfactory flame retardant properties

Inactive Publication Date: 2008-04-09
TIANJIN FIRE RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] Composite flame retardants are very effective in improving the flame retardancy of thermoplastic polystyrene foam (XPS), but their additions have a greater impact on the physical and chemical properties, structure, appearance, and production process of the product, resulting in 1) Poor dispersibility of powder flame retardants in foam plastics, resulting in non-uniform expansion and poor skin quality, 2) High degradation of styrene polymers and high regrinding of materials in extrusion process due to overheating, resulting in styrene polymerization The molecular weight of the foamed plastics and regrinded styrene polymers is reduced, and the physical properties are reduced. The flame retardant of the composite flame retardant should not exceed 30%. At the same time, the composite flame retardant contains a certain modifier to improve the flow of the plastic performance etc.

Method used

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  • Flame-resistant vinyl benzene polymer foam plastic

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0036]Firstly, the recycled polystyrene plastic and various flame retardants of the following formula (Table 1) are uniformly mixed mechanically, and then added into the KSJ-30 twin-screw plastic extruder with a length-to-diameter ratio of 30:1 by a feeder , Control screw speed: 30 rpm, feed temperature: 170°C, mid-section temperature: 180-195°C, outlet temperature: 145°C. The pressure of HCFC is 20mpa.

[0037] The process route taken in the test is as follows:

[0038]

[0039] Among them, the polystyrene masterbatch particles obtained by recycling waste polystyrene foam plastics through a general treatment process have an average particle size of not less than 50 mesh.

[0040] The thickness of the polystyrene foam plastic board is controlled by the export mold, the experimental thickness is 2.0cm, and the cutting length is 2.4m. The density of the finally obtained flame-retardant polystyrene foam plastic board is measured with a balance and a vernier caliper, and t...

Embodiment and comparative Embodiment A

[0043] Embodiment and comparative examples A~C:

[0044] The closed-cell flame-retardant polystyrene foam according to the present invention is prepared by using a KSJ-30 twin-screw plastic extruder (length-to-diameter ratio of 30:1), during which foaming agent is injected, and a mold with a certain thickness is provided at the exit. Embodiments 1~3 and comparative examples A~C are processed according to the above-mentioned technical process, and the performance of its finished product is shown in Table 2:

[0045] The performance of table 2 finished products

[0046]

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Abstract

The invention relates to a flame-retardant styrene polymer foam plastics, which comprises styrene polymer and flame-retardant agent compound. The weight of phosphorus-containing compound takes up 2 percent to 4 percent of the total weight of the styrene polymer. The weight of HBCD takes up at least 5 percent to 8 percent of the total weight of the styrene polymer. The weight of antimony oxide compound takes up at least 2 percent of the total weight of the styrene polymer; the weight of expansion flame-retardant compound takes up at least 6 percent to 12 percent of the total weight of the styrene polymer. The invention, by recycling the styrene polymer foam plastics and through the extrusion production technique of common styrene polymer foam plastics, gets the styrene polymer foam plastics with good flame-retardant performance (the flame-retardant performance meets the requirement on heat insulation foam plastics of GB8624). The extruded type flame-retardant styrene polymer foam plastics the invention gets has low coefficient of thermal conductivity ( high energy saving efficiency), high intensity, and the flame retardance which can meet the requirement of national building fireproof standard, replaces molded type styrene polymer foam plastics and has good prospect on building insulation and pipe sandwich heat thermal insulation, etc.

Description

technical field [0001] The invention relates to flame-retardant polystyrene foam plastics, in particular to a flame-retardant styrene polymer foam plastic, which is produced by ordinary polystyrene extrusion foaming process by using recycled styrene polymer foam plastics and has excellent flame-retardant properties. And a certain thickness of the flat plate. Background technique [0002] For decades, with the wide application of polystyrene foam in building insulation, packaging (industrial and daily necessities), etc., a large amount of waste polystyrene foam has caused a large area of ​​"white pollution", which has brought great harm to people's lives. and production hazards. Therefore, most domestic manufacturers use recycled waste PS to produce extruded polystyrene foam boards, which solves the environmental protection problems of waste polystyrene foam from one aspect. At the same time, my country's construction industry management department has proposed that the ori...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L25/06C08K5/521C08J9/00C08K5/3492C08K5/05C08K3/00
Inventor 胡胜利卓萍支洋波
Owner TIANJIN FIRE RES INST
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