Zirconium oxide foam ceramic filter

A foamed ceramic and filter technology, which is applied in filtration and separation, ceramic products, chemical instruments and methods, etc., can solve the problems of low refractoriness and strength, unstable filtering effect, application limitations, etc., and achieve good high temperature stability and resistance. Thermal shock, good filtering and adsorption capacity, good filtering and purification effect

Inactive Publication Date: 2008-04-23
晋城市富基新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, all these filters can only filter out large inclusions and very few small inclusions in molten metal through mechanical sieving
Due to the low refractoriness and strength of the aluminum silicate fiber filter, it can only be used for filtering non-ferrous alloys, cast iron and small steel castings, and it is difficult to withstand the impact of high-temperature metal fluid for a long time; the molybdenum wire and Although the boron nitride fibrous filter screen developed in the United States can be used to filter high-temperature alloys such as cast steel, its application is limited because of its high price.
There are also straight-hole core-type ceramic filters and refractory particle filters used for casting alloy filtration, but their porosity is small, and the filtration efficiency of the former is still low, and the filtration effect is unstable. Bonding effect makes it easy to leak particles and inconvenient to use
Although the sintered porous ceramic filter first successfully developed in the United States in the early 1970s solved the problems of easy particle leakage and inconvenient use of the refractory particle filter, it is different from the honeycomb straight-hole ceramic filter successfully developed in the early 1980s in the United States. Like the container, the porosity is still small, generally less than 50%, so that the flow rate of the molten metal is low
[0014] Although the research on the above-mentioned foamed ceramic filters has achieved certain results, they all have the disadvantages of high temperature resistance and poor impact resistance, and there are still defects when filtering a large amount of molten steel.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] According to the weight ratio of 78.5:13:6.5:1, zirconium oxide, aluminum oxide, calcium oxide and yttrium oxide are fully mixed to make ceramic powder.

[0054] Mix ceramic powder, carboxymethyl cellulose, polyvinyl alcohol and water according to the weight ratio of 60:0.5:1:40, put into a mixer and stir for 2-3 hours to make the stirring evenly, and make a ceramic slurry.

[0055] Choose 10PPI soft polyurethane foam, process it into a size of 50mm×50mm×22mm, soak it in a 60°C alkali solution with a pH value of 7.5 for 20min to remove the film in the foam hole, and then rinse with water to remove the alkali solution, and then naturally dried to remove moisture, as a carrier for ceramic slurry.

[0056] Using the roll pressing and dipping process, add ceramic slurry to the foam plastic carrier, and then input the carrier into the slurry dipping machine for squeezing and dipping, and squeeze out excess slurry to make a foam ceramic filter blank.

[0057] Put the ceramic...

Embodiment 2

[0060] According to the weight ratio of 80:12:7:1, zirconium oxide, aluminum oxide, calcium oxide and yttrium oxide are fully mixed to make ceramic powder.

[0061] Mix ceramic powder, carboxymethyl cellulose, polyvinyl alcohol and water according to the weight ratio of 63:0.8:1:37, put them into a mixer and stir for 2-3 hours to make the stirring even, and make a ceramic slurry.

[0062] Choose 10PPI soft polyurethane foam, process it into a size of 50mm×50mm×22mm, soak it in a 60°C alkali solution with a pH value of 7.5 for 20min to remove the film in the foam hole, and then rinse with water to remove the alkali solution, and then naturally dried to remove moisture, as a carrier for ceramic slurry.

[0063] Using the roll pressing and dipping process, add ceramic slurry to the foam plastic carrier, and then input the carrier into the slurry dipping machine for squeezing and dipping, and squeeze out excess slurry to make a foam ceramic filter blank.

[0064] Put the ceramic ...

Embodiment 3

[0067] According to the weight ratio of 75:15:8:2, zirconium oxide, aluminum oxide, calcium oxide and yttrium oxide are fully mixed to make ceramic powder.

[0068] Mix ceramic powder, carboxymethyl cellulose, polyvinyl alcohol and water according to the weight ratio of 65:0.8:0.8:35, put into a mixer and stir for 2-3 hours to make the stirring even, and make a ceramic slurry.

[0069] Choose 10PPI soft polyurethane foam, process 50mm×50mm×22mm in size, soak in 60°C alkali solution with a pH value of 7.5 for 20 minutes to remove the film in the foam plastic holes, and then rinse with water to remove the alkali solution , and then dried naturally to remove moisture, as a carrier for ceramic slurry.

[0070] Using the roll pressing and dipping process, add ceramic slurry to the foam plastic carrier, and then input the carrier into the slurry dipping machine for squeezing and dipping, and squeeze out excess slurry to make a foam ceramic filter blank.

[0071] Put the ceramic foa...

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PUM

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Abstract

The present invention relates to a zirconium oxide foamed ceramic filter. It is made up by adopting the following steps: using zirconium oxide, aluminium oxide, calcium oxide and yttrium oxide to form ceramic powder, adding methyl cellulose, polyvinyl alcohol and water to prepare slurry, using soft polyurethane foamed plastics as carrier, impregnating said carrier with said slurry, extruding to obtain blank material, drying and sintering so as to obtain the invented zirconium oxide foamed ceramic filter. The invented foamed ceramic filter has good high-temperature stability and thermal shocking resistance in the high-temperature molten steel, does not contaminate alloy and can obtain good filtering purification effect.

Description

technical field [0001] The invention relates to the purification of molten metal, in particular to a foam ceramic filter. More specifically, the present invention relates to a ceramic foam filter containing zirconia as a ceramic component, and the filter prepared by the present invention is used for filtering and purifying metal melts such as cast steel and superalloy. Background technique [0002] During the smelting and pouring process of various metal liquid alloys, the casting reject rate caused by casting defects such as non-metallic inclusions and shrinkage holes is generally as high as 50-60% of the total rejects. Inclusion defects not only seriously reduce the mechanical properties and casting properties of castings, but also have harmful effects on the machining and appearance of castings. Purifying liquid casting alloys, reducing or eliminating various non-metallic inclusions and exhaust gases are undoubtedly important technical measures to obtain high-quality cas...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D39/20C04B35/48C04B38/06B22D11/119
Inventor 李军虎关晋军逯文强刘志刚田建刚秦胜利
Owner 晋城市富基新材料股份有限公司
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