Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for increasing selectivity and yield of ethylene and propylene

A selectivity and propylene technology, which is applied in the field of improving the selectivity and yield of ethylene and propylene, and can solve the problems of low yield and low selectivity

Active Publication Date: 2008-04-23
CHINA PETROLEUM & CHEM CORP +1
View PDF2 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The technical problem to be solved by the present invention is the low yield and low selectivity of the target product ethylene and propylene in the prior literature and technology, and a new method for improving the selectivity and yield of ethylene and propylene is provided

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Using methanol as raw material, the first reaction zone and the second reaction zone both use riser reactors, with SAPO-34 molecular sieve as the catalyst, the reaction temperature in the first reaction zone is 450°C, the contact time is 2 seconds, and the reaction pressure is 0.05MPa; The reaction temperature in the second reaction zone is 480°C, the contact time is 3 seconds, and the reaction pressure is 0.02MPa; the reaction temperature in the third zone reaction zone is 450°C, the contact time is 3 seconds, and the reaction pressure is 0.03MPa. In the experiment, after the reaction gas mixture in the first reaction zone is separated from the solid catalyst, the gas phase directly enters the second reaction zone for reaction, and the reaction product from the second reaction zone is separated and C4 and above hydrocarbons enter the third reaction zone. The gas-solid mixture in the three reaction zones directly enters the first reaction zone, and the reaction results a...

Embodiment 2

[0019] Using dimethyl ether as raw material, the first reaction zone and the second reaction zone both use riser reactors, with SAPO-34 molecular sieve as the catalyst, the reaction temperature in the first reaction zone is 400 ° C, the contact time is 1 second, and the reaction pressure is 0.4 MPa; the reaction temperature in the second reaction zone is 500°C, the contact time is 5 seconds, and the reaction pressure is 0.3MPa; the reaction temperature in the third zone reaction zone is 400°C, the contact time is 1 second, and the reaction pressure is 0.04MPa. In the experiment, after the reaction gas mixture in the first reaction zone is separated from the solid catalyst, the gas phase directly enters the second reaction zone for reaction, and the reaction product from the second reaction zone is separated and C4 and above hydrocarbons enter the third reaction zone. The gas-solid mixture in the three reaction zones directly enters the first reaction zone, and the reaction resu...

Embodiment 3

[0021] Methanol and dimethyl ether are used as raw materials, the weight ratio of methanol and dimethyl ether is 1:1, the first reaction zone and the second reaction zone both adopt fast fluidized bed reactors, and SAPO-34 molecular sieve is used as the catalyst. The reaction temperature in the reaction zone is 500°C, the contact time is 3 seconds, and the reaction pressure is 1.2MPa; the reaction temperature in the second reaction zone is 550°C, the contact time is 6 seconds, and the reaction pressure is 1.0MPa; the reaction temperature in the third zone is 500°C, The contact time was 5 seconds, and the reaction pressure was 1.2 MPa. In the experiment, after the reaction gas mixture in the first reaction zone is separated from the solid catalyst, the gas phase directly enters the second reaction zone for reaction, and the reaction product from the second reaction zone is separated and C4 and above hydrocarbons enter the third reaction zone. The gas-solid mixture in the three ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The present invention relates to one kind of ethylene and propylene producing process with high selectivity and high yield. The production process includes the following steps: 1. reaction of oxygen compound material in the first reaction region through contacting with catalyst to produce gas-solid mixture I, and separating in the fast separator I to obtain the catalyst I to be regenerated and the effluent I containing ethylene and propylene; 2. reaction of the effluent I in the second reaction region through contacting with catalyst II to produce gas-solid mixture II, separating in the fast separator II to obtain the catalyst II to be regenerated and the effluent II containing ethylene, propylene and C4 and C4+ hydrocarbons, and further separating to obtain effluent III of C4 and C4+ hydrocarbons, ethylene product and propylene product; 3. reaction of the effluent III in the third reaction region through contacting with catalyst III to produce gas-solid mixture III, and returning mixture III to the first reaction region; and 4. regenerating the catalysts, and returning the regenerated catalysts to the reaction regions separately. The production process may be applied in industrial production.

Description

technical field [0001] The present invention relates to a method for improving the selectivity and yield of ethylene and propylene, especially the method for improving the selectivity and yield of ethylene and propylene by catalytic reaction of methanol or dimethyl ether, complex butene and ethylene metathesis and olefin catalytic cracking technology . Background technique [0002] Petrochemical industry is an important pillar industry in the national economy. It provides a large amount of chemical raw materials for industry, agriculture, transportation and national defense. It is one of the most relevant and leading industrial sectors in the national economy. Propylene and ethylene are the two most important basic raw materials for modern petrochemical industry. [0003] Propylene is mainly used to produce polypropylene, cumene, carbonyl alcohol, acrylonitrile, propylene oxide, acrylic acid, isopropanol, etc. Among them, polypropylene accounts for more than half of the wor...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C07C1/20C07C11/04C07C11/06
CPCY02P20/52Y02P20/584Y02P30/20Y02P30/40
Inventor 谢在库刘俊涛钟思青张惠明
Owner CHINA PETROLEUM & CHEM CORP