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Silicon-nitrogen-oxygen ceramic transmitted wave material and method for producing the same

A technology of silicon oxynitride ceramics and wave-transmitting materials, which is applied in functional ceramics and special fields, can solve the comprehensive performance requirements such as heat, electricity, structural strength and stiffness, increase the difficulty of material research, production and product molding, and cover processing High precision is required to achieve the effect of scientific and reasonable preparation method, increased strength and improved thermal performance

Active Publication Date: 2010-09-29
ZHONGCAI HIGH NEW MATERIAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its comprehensive properties such as heat, electricity, structural strength and rigidity are very demanding, the wall thickness tolerance is small, and the processing accuracy of the cover body is high, so it increases the difficulty of material research, production and product molding
Traditional ceramic materials cannot meet the above comprehensive requirements. Therefore, it has been a difficult problem for domestic and foreign scholars to overcome the wave-transparent composite ceramic materials that can be applied to the 8 mm wave band.

Method used

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  • Silicon-nitrogen-oxygen ceramic transmitted wave material and method for producing the same
  • Silicon-nitrogen-oxygen ceramic transmitted wave material and method for producing the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The preparation method of silicon oxynitride ceramic wave-transparent material of the present invention is as follows:

[0028] Weigh 108 grams of 0.45-2 micron silicon nitride powder, the weight content of α-phase silicon nitride is 95%, 86 grams of quartz powder passed through a 1000 mesh sieve, the weight content of silicon dioxide is 99.99%, and the particle size of 12 grams is less than 0.5 micron Yttrium oxide powder, the weight content of yttrium oxide is 99.99%, the ingredients are mixed with absolute ethanol by ball milling, and the binder with the weight of 0.6% of the ingredients is added to granulate, and the particle size is controlled to be 70-80 microns, wherein the binder It is an aqueous solution of polyvinyl alcohol with a degree of polymerization of 1600-1800, and the weight concentration is 35%. The granulated granules are formed by cold isostatic pressing under a pressure of 100MPa, and then sintered under a nitrogen atmosphere without pressure at a...

Embodiment 2

[0033] The preparation method of silicon oxynitride ceramic wave-transparent material of the present invention is as follows:

[0034] Weigh 12 grams of 0.5-2 micron silicon nitride powder, the weight content of α-phase silicon nitride is 94%, 10 grams of quartz powder with a particle size of 2-10 μm, the weight content of silicon dioxide is 99.98%, and the weight content of 1.3 grams is less than 0.6 micron yttrium oxide powder, the weight content of yttrium oxide is 99.99%, the ingredients are mixed with absolute ethanol by ball milling, and 0.5% of the weight of the ingredients is added for granulation. The particle size is controlled to be 60-70 microns. The adhesive is an aqueous solution of polyvinyl alcohol with a degree of polymerization of 1600-1800, and the weight concentration is 35%. The granulated granules are formed by cold isostatic pressing under 120 MPa pressure, and then sintered under a nitrogen atmosphere without pressure at a maximum temperature of 1700-17...

Embodiment 3

[0039] The preparation method of silicon oxynitride ceramic wave-transparent material of the present invention is as follows:

[0040] Ingredients powder weight composition: 93% of silicon nitride powder with a particle size of 0.5-1.5 microns and 95% of α-phase silicon nitride by weight, 7% of yttrium oxide powder with a particle size of less than 0.8 microns and a weight content of yttrium oxide of 99.98% 78% of quartz powder with a particle size of 2-8 μm and a silicon dioxide weight content of 99.98%.

[0041] Adopt ball milling to mix the ingredients evenly with absolute ethanol, add a binder with a weight of 0.7% of the ingredients to granulate, and the particle size is controlled to be 60 to 80 microns, wherein the binder is an aqueous solution of polyvinyl alcohol with a polymerization degree of 1600 to 1800, and the weight The concentration is 25%. The granulated granules are formed by cold isostatic pressing under a pressure of 120MPa, and then sintered under a nitr...

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Abstract

The invention relates to silicon nitrogen oxygen ceramic wave penetrating material and belongs to the special type and functional ceramics technical field. The invention comprises the components in weight proportion that: 90 to 95 percent of silicon nitride, 5 to 10 percent of yttria, and 70 to 80 percent of adscititious quartz. The product is produced by compounding, moulding and burning, wherein, the mixed powder is shaped by firstly producing the granule of the mixed power lot by utilizing the adhesives and then being pressed, the granularity is controlled between 60 and 90 micron; the material product is shaped by adopting the cold isostatic compaction with the pressure being 100 to 160 MPa, and is sintered without pressure under the nitrogen ambience with the sintering temperature being 1700 to 1750 DEG C and the high temperature heat preserving time being 60 to 90 minutes. The material product not only has good dynamical and thermal property, high intensity, low conducting and small heat swelling, but also has excellent dielectric capacity; the dielectric constant Epsilon is less than 3.5 and the electric medium wastage is less than 2.3 multiple 10E-3, so that the invention can satisfy the applying requirements of the high penetrating rate of 8 mm wave band. The invention has scientific and reasonable preparing method, simple and easy operation and easy implementation.

Description

technical field [0001] The invention relates to a silicon oxynitride ceramic wave-transmitting material and a preparation method thereof, belonging to the technical field of special and functional ceramics. Background technique [0002] Millimeter wave guidance has quasi-all-weather characteristics and good low-altitude, ultra-low-altitude overlooking tracking and the ability to deal with stealth targets. However, due to the short wavelength of millimeter waves (8mm), the required high-performance millimeter-wave materials must have high electromagnetic wave penetration capabilities, and at the same time require light weight and high strength. Its thermal, electrical, structural strength and rigidity are very demanding, the wall thickness tolerance is small, and the processing accuracy of the cover body is high, which increases the difficulty of material research, production and product molding. Traditional ceramic materials cannot meet the above comprehensive requirements,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/14
Inventor 廖荣程之强王重海刘建袁维军栾艺娜张训虎纪娟
Owner ZHONGCAI HIGH NEW MATERIAL