Chemical resistance table slab rubber, preparation and use thereof

A corrosive and chemical-resistant technology, which is applied in the field of chemical corrosion-resistant countertop rubber sheet and its preparation, can solve the problems of high price and low thermal deformation temperature, so as to reduce production cost, increase thermal deformation temperature, and improve the smoothness of the board surface The effect of wear resistance and chemical corrosion resistance

Active Publication Date: 2008-12-17
GUANGDONG FUSHENG INNOVATIVE MATERIAL TECH LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Most of the epoxy test benchtops in the domestic market now have an important material index, heat distortion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] (1) Mix 5g E-54 of liquid low-molecular-weight epoxy resin and 2g of pigment carbon black to form pigment paste at room temperature;

[0054] (2) Add 370g of E-54 epoxy resin to the mixing container, add the prepared pigment slurry, stir evenly, and then heat up to 70°C;

[0055] (3) Add 100g of methylhexahydrophthalic anhydride and 157g of maleic anhydride, heat to maintain the temperature of the feed solution at 70°C, and stir evenly;

[0056] (4) Add 300g of 20 mesh mica powder and 100g of 300 mesh barium sulfate, 4g of silane coupling agent, and stir at high speed for 15 minutes;

[0057] (5) Add curing accelerator 2,4,6-tris(dimethylaminomethyl)phenol 4.2g, wetting and dispersing agent 8g, defoaming agent 20g, and benzoyl peroxide 4g, and the dispersion is uniform;

[0058] (6) Pouring the mold into the oven, curing at 100°C for 2 hours, then rising to 160°C for curing for 20 hours, cooling to room temperature, demolding, and cutting according to the required specifica...

Embodiment 2

[0060] (1) At room temperature, 5g E-54 of liquid low molecular epoxy resin and 2g of carbon black are mixed to form a pigment paste;

[0061] (2) Add 80g of E-54 epoxy resin and 20g of ethylene glycol diglycidyl ether into the mixing container, add the prepared pigment slurry, stir evenly, and then heat to 110°C;

[0062] (3) Add 30g of methyltetrahydrophthalic anhydride, 20g of methylnadic anhydride and 30g of maleic anhydride, heat to maintain the temperature of the material liquid at 110°C, and stir evenly;

[0063] (4) Add 820g of 100 mesh silica, 8.2g of silane coupling agent, and stir at high speed for 15min;

[0064] (5) Add curing accelerator 2.4.6-tris(dimethylaminomethyl)phenol 1.2g, wetting and dispersing agent 20g, defoaming agent 20g, and benzyl alcohol tert-butyl peroxide 1.8g, and the dispersion is uniform;

[0065] (6) Fill the mold into the oven, vibrate to promote bubble discharge, cure at 110°C for 2 hours, then rise to 170°C for 15 hours, then cool to room tem...

Embodiment 3

[0067] (1) At room temperature, 5g E-44 of liquid low-molecular-weight epoxy resin and 2g of carbon black are mixed to form a pigment paste;

[0068] (2) Weigh 600g of 100 mesh silica, and add the prepared pigment paste to 200g of E-44 epoxy resin;

[0069] (3) Add 70g of methyltetrahydrophthalic anhydride and 70g of maleic anhydride, heat to maintain the temperature of the material liquid at 90°C, and stir evenly;

[0070] (4) Add 600g of 100 mesh silica, 6g of silane coupling agent, and stir at high speed for 15min;

[0071](5) Add 3g of curing accelerator 2-ethyl-4-methylimidazole, 8g of wetting and dispersing agent, 20g of defoamer, and 3g of benzoyl peroxide, and the dispersion is uniform;

[0072] (6) Pouring the mold into the oven, curing at 100°C for 2 hours and then rising to 160°C for 14 hours, cooling to room temperature, demoulding, and cutting according to the required specifications.

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PUM

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Abstract

The invention discloses a chemical corrosion-resistant table rubber sheet, a preparation method and applications thereof. The table rubber sheet mainly consists of the following raw materials by weight percentage: 2 percent to 40 percent of anhydride curing agent, 2 percent to 40 percent of other types of acid anhydrides, 2 percent to 50 percent of epoxy resin systems, 40 percent to 93 percent of filler and 0.01 percent to 1 percent of initiator, wherein, the anhydride curing agent is maleic anhydride and the initiator is hydroperoxide or dialkyl peroxide. The preparation method of the invention includes the steps that maleic anhydride is introduced in common acid anhydrides and added with a peroxide initiator to initiate the free radical polymerization and form an interpenetrating network structure so as to improve the heat distortion temperature of products. Meanwhile, by adopting the preparation method of the invention, the products can be made from raw materials with lower prices, thus having relatively high market competitiveness. When being applied to an experiment table top in a laboratory, the table rubber sheet of the invention can has relatively good flatness on the sheet surface, good wearing resistance and chemical corrosion resistance as well as comparatively high heat distortion resistance.

Description

Technical field [0001] The invention relates to an artificial stone slab product, in particular to an epoxy resin-based chemical corrosion-resistant countertop rubber sheet, and a preparation method and application thereof. Background technique [0002] At present, the materials that can be used as countertops on the market are natural marble, granite, stainless steel, fireproof board, ceramic tile, physical and chemical board and artificial stone countertop. These materials have disadvantages of one kind or another when used in laboratories or other chemical-resistant applications. Natural marble, granite and ordinary ceramics have poor resistance to acid and alkali corrosion, and are relatively brittle; stainless steel products not only have poor decorative effects, but are also easy to scratch and have insufficient corrosion resistance; ordinary fireproof boards have corrosion resistance and high temperature resistance. The repairability is poor; the physical and chemical plat...

Claims

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Application Information

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IPC IPC(8): C08J5/18C08L63/00C08K7/14C08K3/36C08K5/092C08K5/3445
Inventor 罗飞龚学锋
Owner GUANGDONG FUSHENG INNOVATIVE MATERIAL TECH LTD
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