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Inorganic nano particle modified building emulsion and preparation method thereof
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A technology of inorganic nanoparticles and architectural emulsions, used in latex paints, coatings, etc., to achieve a huge market with promising prospects, highlighting calcium ion stability and good compatibility.
Inactive Publication Date: 2009-02-11
JIANGSU UNIV OF SCI & TECH
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Problems solved by technology
In the present invention, inorganic nanoparticles are surface-modified and organic monomers are pre-emulsified and seed emulsion polymerized to prepare inorganic nanoparticles modified architectural emulsion, so that inorganic nanoparticles are uniformly dispersed in the emulsion monomer, and the gap between the inorganic phase and the organic phase It has good intercompatibility, prevents nanoparticle agglomeration, and overcomes the defects in the prior art. Such related research has not yet been reported.
Method used
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[0042] (2) Put 1 / 5 deionized water in the emulsification container, when the temperature is 50°C, add some potassiumpersulfate initiator, raise the temperature to 80-88°C, and keep it warm for ...
[0078] Two, preparation method is identical with embodiment 1.
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Abstract
The invention provides an inorganic nanometer particle modified architectural emulsion and a preparation method thereof, belonging to the technical field of building coating. The inorganic nanometer particle is improvement of the prior art; according to the mass percentage, the inorganic nanometer particle consists of 1-5% of methyl methacrylate, 15-25% of cinnamene, 15-25% of butyl acrylate, 35-60% of deionized water, 1-5% of OP-10 emulsifying agent, 1-3% of methacrylic acid, 0.2-1% of emulsifying agent A, 0.1-0.6% of emulsifying agent B, 0.5-3% of wet attaching monomer, 0.1-0.3% of reactive emulsifying agent, 0.2-0.6% of sodiumbicarbonateregulator, 0.3-0.8% of potassiumpersulfate initiator, 0.1-0.2% of ammonia and 0.5-1.5% of nanometer TiO2 modifying liquid. The inorganic nanometer particle modified architectural emulsion and the preparation method thereof have the advantages of water resistance, scrubbing resistance, good stability, simple process, low cost, environmental protection and good application prospect.
Description
technical field [0001] The invention relates to the field of architectural coatings, in particular to an inorganic nanoparticle modified architectural styrene-acrylic emulsion and a preparation method of the emulsion. Background technique [0002] There have been studies on emulsion polymerization and modification of inorganic nanomaterials at home and abroad, but the research on the modification of inorganic nanoparticles and polymer emulsions is still in its infancy. Therefore, more and more researchers are attracted to study this type of emulsion, and many explorations have been made in the polymerization process of nanoparticle modified emulsion, but there are still few effective modification methods, and there are still some problems. , mainly because the nanoparticles are not uniformly dispersed in the polymer matrix, and the nanoparticles are agglomerated or phase separated. In order to solve the existing problems of inorganic nanoparticles modified architectural emu...
Claims
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Application Information
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