Pyrogenic pretreatment method for low-grade laterite nickel mine
A laterite nickel ore, low-grade technology, applied in the field of beneficiation and smelting, can solve the problems of low nickel content in nickel pig iron, restricted development and utilization, large equipment investment, etc., achieve high grade and recovery rate, improve comprehensive utilization rate, and equipment investment. effect of province
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Embodiment 1
[0025] Embodiment 1: Under the conditions of solid sulfur at a vulcanization temperature of 400°C:
[0026] (1) The chemical composition of ferrous laterite nickel ore is as follows: Ni1.0%, MgO13.33%, TFe18.0%, Co0.041%, Al 2 o 3 9.44%, SiO 2 23.57%.
[0027] (2) Crushing the iron low-grade lateritic nickel ore to 10mm. According to route one: put it and solid sulfur in the same heating container (vulcanization container) for heating and vulcanization pretreatment.
[0028] In the vulcanization pretreatment process, the addition of vulcanization agent is 20% of the low-grade laterite nickel ore in terms of elemental sulfur by weight; the vulcanization pretreatment temperature is controlled at 400±2°C; the vulcanization pretreatment time is 300 minutes, and iron Heating sulfidation pretreatment of laterite nickel ore.
[0029] The lateritic nickel ore pretreated by pyrosulfurization, when the grinding fineness is -0.074mm, accounting for 90%, undergoes one roughing, four ...
Embodiment 2
[0044] Embodiment 2: Under the conditions of solid iron sulfide at a vulcanization temperature of 1200°C:
[0045] (1) The chemical composition of ferrous laterite nickel ore is as follows: Ni1.0%, MgO13.33%, TFe18.0%, Co0.041%, Al 2 o 39.44%, SiO 2 23.57%.
[0046] (2) Crushing the iron low-grade lateritic nickel ore to 10mm. According to route two: place it and solid iron sulfide in different heating containers and heat them separately, and then add them into the same vulcanization container with a feeder for vulcanization pretreatment.
[0047] In the vulcanization pretreatment process, the addition of vulcanization agent is 10% of the low-grade laterite nickel ore in terms of elemental sulfur by weight; the vulcanization pretreatment temperature is controlled at 1200±2°C; the vulcanization pretreatment time is 30 minutes, and the iron Heating sulfidation pretreatment of laterite nickel ore.
[0048] The lateritic nickel ore pretreated by pyrosulfurization, when the gr...
Embodiment 3
[0064] Embodiment Three: Under the conditions of solid sodium sulfide at a vulcanization temperature of 800°C:
[0065] (1) The chemical composition of ferrous laterite nickel ore is as follows: Ni1.0%, MgO13.33%, TFe18.0%, Co0.041%, Al 2 o 3 9.44%, SiO 2 23.57%.
[0066] (2) Crushing the iron low-grade laterite nickel ore to 2mm. According to route one: put it and solid sodium sulfide in the same heating container (curing container) for heating and vulcanization pretreatment.
[0067] In the vulcanization pretreatment process, the amount of vulcanization agent added is 18% of the low-grade laterite nickel ore in terms of elemental sulfur by weight; the vulcanization pretreatment temperature is controlled at 800±2°C; the vulcanization pretreatment time is 80 minutes, and the iron Heating sulfidation pretreatment of laterite nickel ore.
[0068] The lateritic nickel ore pretreated by pyrosulfurization, when the grinding fineness is -0.074mm, accounting for 90%, undergoes o...
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