Method for preparing photochromic WO3 film using malic acid induction
A photochromic and malic acid technology, applied in the direction of tungsten oxide/tungsten hydroxide, etc., can solve the problems of lack of clear characterization of the color changing effect, demanding photochromic excitation light source, etc., achieve good color changing effect and improve photochromic reaction Activity, effect of inhibiting aggregation
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Embodiment 1
[0017] First, prepare 0.2mol / L Na 2 WO 4 Solution 25ml, Na 2 WO 4 After the solution passes through the cation exchange resin, adjust the pH value to 1.0 with concentrated hydrochloric acid with a concentration of 36% by mass percent, and add 10 ml of n-propanol and 15 ml of polyacrylic acid dropwise under the magnetic stirrer at a speed of 400 r / min, and then dropwise Add 25ml of 3mol / L inducer malic acid solution, then stir and homogenize the reaction system for 4 hours, then put it in a dark place and let it stand for 24h, then use the dipping and pulling method (the pulling speed is 20mm / s, the coating time is 120s ) and dried at 50°C. Finally, put the coated glass slide into a vacuum drying oven and keep it warm for 1 hour under the conditions of a vacuum degree of 0.085 and a temperature of 150°C to obtain the photochromic WO 3 film. Utilize SC-80C full-automatic color difference meter (Beijing Kang Guang Instrument Co., Ltd.) to measure film chromaticity to be 12.4...
Embodiment 2
[0019] The amount of the malic acid solution added in this embodiment is 0.5 times of the amount used in Example 1, that is, 12.5ml of malic acid solution is added, and other conditions are the same as in Example 1 to prepare photochromic WO 3 The measured chromaticity value of the film is 12.45. After being irradiated with ultraviolet light for 5 hours, its chromaticity value is 13.30. After being moved into a dark place for 2 hours, it fades, and its chromaticity value is 12.44.
Embodiment 3
[0021] Get the photochromic WO that embodiment 1 makes 3 The photochromic performance of the film sample was tested between 12:00 and 14:00 on a sunny summer day in southern China. The chromaticity value was 13.15 after 2 hours of light, and faded after 2 hours in the dark, and the chromaticity value was 12.45.
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