Epoxy organosilicon phosphoester compound modified acrylic resin

A technology of organosilicon phosphate ester and acrylic resin, which is applied in coatings, anti-corrosion coatings, metal material coating processes, etc., can solve the problems of affecting solubility, affecting corrosion resistance, and decreasing adhesion, so as to improve cross-linking density, The effect of excellent anti-corrosion performance

Inactive Publication Date: 2009-04-22
CHINA NAT OFFSHORE OIL CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because a small amount of cross-linked structure will obviously affect its solubility in solvents, and problems such as decreased adhesion will also occur, thereby affecting corrosion resistance.

Method used

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  • Epoxy organosilicon phosphoester compound modified acrylic resin
  • Epoxy organosilicon phosphoester compound modified acrylic resin
  • Epoxy organosilicon phosphoester compound modified acrylic resin

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~6

[0023] Embodiment 1~6 prepares epoxy organosilicon phosphate composite modified acrylic resin

[0024] (1) See Table 1 for the amount of raw materials, where the amounts are parts by weight

[0025] Table 1

[0026] components

raw material name

Dosage

Example

1 Dosage

Example

2 Dosage

Example

3 Dosage

Example

4 Dosage

Example

5 Dosage

Example

6 Acrylic Mono

body

Methacrylate

methyl ester

Butyl acrylate

Isooctyl acrylate

ester

acrylic acid 30

15

10

5 40

25

12

3 49

30

15

2 30

20

10

5 35

25

12

3 49

30

15

2 epoxy resin

E12

E44 20

/ 10

/ 2

/ /

20 /

10 /

2 Silicone monomer

KH-570

DL-151 10

/ 5

/ 1

/ /

10 /

5 /

1

[0027] Phosphate monomer PM-100 10 5 1 5 10 1 Initiator

B...

Embodiment 7

[0044] Embodiment 7 prepares one-component anticorrosion coating

[0045] 100 parts by weight of resin A prepared in Example 1, 17.6 parts by weight of iron red, 6.5 parts by weight of zinc yellow, 6.0 parts by weight of zinc phosphate, 29.1 parts by weight of calcined kaolin, 0.8 parts by weight of bentonite, and 0.6 parts by weight of dispersant BYK-163 After mixing with 40 parts by weight of xylene solvent, grind it to a fineness of less than 50 microns with a sand mill to obtain a single-component anti-corrosion coating, numbered as coating A.

Embodiment 8

[0046] Embodiment 8 prepares one-component anticorrosion coating

[0047] A single-component anti-corrosion coating was prepared basically the same as in Example 7, and the number was coating B, the difference being that the resin used was the resin B prepared in Example 2.

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PUM

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Abstract

The invention relates to epoxy silicon phosphate ester composite modified acrylic resin, which is characterized in that epoxy groups, phosphate ester groups and siloxane groups are introduced into acrylic resin; and the weight percentage of resin solid is between 40 and 60 percent, and the balance being a solvent. The acrylic resin comprises the following compositions with the percentage content: as calculated by the total weight of the resin solid, acrylate monomers account for 60 to 96 percent; epoxy resin accounts for 2 to 20 percent; silicon monomers account for 1 to 10 percent; phosphate monomers account for 1 to 10 percent; and an initiator is 0.5 to 1.5 percent of the amount of the acrylate monomers. After the resin is prepared into single-component anticorrosive coating, the anticorrosive property of a film coating is superior to that of the prior single-component anticorrosive coating, and the salt water resistance and the salt fog resistance of the film coating are even superior to those of the prior double-component anticorrosive coating. The epoxy silicon phosphate ester composite modified acrylic resin overcomes the defects of trivial use of the prior double-component coating and poor anticorrosive effect of the single-component coating.

Description

technical field [0001] The invention relates to an epoxy organosilicon phosphate composite modified acrylic resin, which is especially suitable for preparing single-component anticorrosion coatings. Background technique [0002] The current anti-corrosion coatings include two-component and one-component, and the commonly used film-forming base materials for two-component anti-corrosion coatings are epoxy-polyamide resin, acrylate-polyurethane resin, chlorosulfonated polyethylene resin, etc. These resins have been used to formulate anti-corrosion coatings for many years, and their anti-corrosion performance is much better than that of single-component anti-corrosion coatings. However, the two components need to be weighed and mixed in proportion before construction, and there is a certain degree of stability after preparation. Application period, once the application period is exceeded, the mechanical properties and anti-corrosion properties of the coating film will be greatl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/10C08F220/10C08F230/08C08F230/02C09D151/08C09D5/08C23C22/03
Inventor 周铭张玉兴陈斌张东阳李焕
Owner CHINA NAT OFFSHORE OIL CORP
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