Industrial synthesis method for producing high water absorption resin

A technology of superabsorbent resin and polymerization agent, which is applied in the production process of functional polymer materials in fine chemical industry, can solve the problems of low monomer concentration, waste of resources, slow polymerization rate, etc., and achieve simple production process, low energy consumption, The effect of a short reaction cycle

Inactive Publication Date: 2009-05-06
TIANJIN SANNONGJIN TECH
View PDF2 Cites 23 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of this production process are: starch gelatinization requires heating, which wastes resources; the monomer concentration is low, the polymerization rate is slow, nitrogen gas is introduced for a long time, cross-linking agent is added and continuous heating makes the production cost high and the production process is complicated. , the reaction cycle is long so that the energy consumption is large and the production cost is high
However, both of these two production processes still need to add a crosslinking agent for crosslinking, and both require continuous heating, resulting in greater energy consumption and increased production costs.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Example 1: Weigh 150kg of acrylic acid into the reactor, then weigh 200kg of sodium hydroxide solution for neutralization, start stirring, then add 50kg of acrylamide to fully dissolve it, control the reaction temperature at 30-40°C, and then add 50kg of corn in turn , 0.01kg of ammonium persulfate, after 30 minutes of reaction, add 0.2kg of baking soda, 30kg of potassium hydroxide solution, and then put it into the polymerization tank for polymerization.

Embodiment 2

[0016] Example 2: Weigh 220kg of acrylic acid into the reactor, then weigh 320kg of sodium hydroxide solution into the reactor for neutralization, start stirring, then add 140kg of acrylamide to fully dissolve, control the reaction temperature at 30-40°C and then add wheat in turn 100kg, 0.1kg of ammonium persulfate, after 40 minutes of reaction, add 0.3kg of baking soda, and 40kg of potassium hydroxide solution into the polymerization tank for polymerization. After polymerization, the semi-finished product is cooled, cut, dried, and crushed to become the finished product.

Embodiment 3

[0017] Example 3: Weigh 150kg of acrylic acid into the reactor, then weigh 200kg of sodium hydroxide solution for neutralization, start stirring, then add 50kg of acrylamide to fully dissolve it, control the reaction temperature at 30-40°C and then add 50kg of rice in turn , 0.01kg of ammonium persulfate, after 30 minutes of reaction, add 0.2kg of baking soda, 30kg of potassium hydroxide solution, and then put it into the polymerization tank for polymerization.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to an industrial synthesis method for producing absorbent resin. The method comprises the following steps: alkali liquor is used to neutralize acrylic acid; acrylamide is added into the reaction solution, is fully dissolved, is orderly added with starch and a catalyst for reaction at controlled temperature of between 30 and 40 DEG C for 30 to 60 minutes; a foam beater and a polymerizing agent are added into the mixture; the mixture is added into a polymerizing device for polymerization; and the polymerized semi-finished product is subjected to cooling, cutting, drying and crushing to obtain the finished product. The industrial synthesis method has the advantages of simple production process, short reaction period, less energy consumption, long product guarantee period, degradability, no pollution, low input cost and high profit value, and can produce the absorbent resin through self cross linking by utilizing heat released by chemical reaction without adding a cross-linking agent and heating on the basis of not introducing nitrogen at the prior normal pressure.

Description

Technical field: [0001] The invention relates to a production process of functional polymer materials in fine chemical industry, in particular to an industrial synthesis method for producing superabsorbent resin. Background technique: [0002] Superabsorbent resin is a new type of functional polymer material developed in the past 30 years. It has excellent water absorption and water retention properties. It can absorb water hundreds to thousands of times its own weight. Strong, loses little water even under high pressure. It can be widely used in fields such as agriculture, forestry, animal husbandry, medical and health care, petroleum, construction and food, but due to its complicated production process and high price, it has not been widely promoted. [0003] The traditional production process of superabsorbent resin is: mixing starch and water, blowing nitrogen, heating and gelatinizing. After cooling, under the protection of nitrogen, add ethylene monomer initiator and...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00C08J9/08C08L51/02
Inventor 王辰韩文彬张克森王木兰
Owner TIANJIN SANNONGJIN TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products