SiO2 enriched nano composite inorganic flame-retardant heat insulating thermal preserving board and manufacturing process thereof

An inorganic flame-retardant, heat-insulating and heat-insulating technology is applied in the field of inorganic composite composite sheets and their production technology, which can solve the problems of long-term drying process, limitation, waste of energy, etc., and achieves low bulk density, environmental protection in the production process, and simple production process. Effect

Inactive Publication Date: 2009-07-01
上海暄洋化工材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the widely used inorganic insulation materials include calcium silicate insulation board and aluminum magnesium silicate board. The bulk density of the product is generally above 180 kg/m3, and the thermal conductivity at room temperature is above 0.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] SiO 2 Airgel 40g, SiO 2 23 grams of nano powder, 12 grams of zirconia superfine powder, 10 grams of glass bead material, 3 grams of expanded perlite, 1 gram of ethyltriethoxysilane, 8 grams of high modulus potassium silicate solution, silicic acid 3 grams of calcium fiber microporous slurry, the above components are dispersed, mixed, billeted, and dried for 48 hours to obtain a block with a bulk density of 89 kg / m3 and a thermal conductivity (tested by hot wire method) of 0.039w / m.k. Calcined in a muffle furnace at 1000°C for 100 hours, the weight loss was 2 wt%, and the green body was still intact.

Embodiment 2

[0013] SiO 2 Airgel 60g, SiO 2 5 grams of nano powder, 15 grams of zirconia superfine powder, 5 grams of ceramic microbead material, 3 grams of expanded perlite, 1 gram of methyltrimethoxysilane, 7 grams of tetraethylorthosilicate acidic hydrolyzate, silicic acid Aluminum magnesium fiber 4 grams. The above components are dispersed, mixed, billeted, and dried for 48 hours to obtain a block with a bulk density of 86 kg / m3 and a thermal conductivity (tested by hot wire method) of 0.038w / m.k. Calcined in a muffle furnace at 1000°C for 100 hours, the weight loss was 1.5wt%, and the green body was intact;

[0014] Calcined in the air atmosphere of a silicon carbide furnace at 1200°C for 1 hour, the weight loss was 4 wt%, and the green body was still intact.

Embodiment 3

[0016] SiO 2 Airgel 35g, SiO 2 25 grams of nano powder, 15 grams of zirconia superfine powder, 5 grams of expanded perlite, 8 grams of vermiculite, 1.5 grams of ethyl triethoxysilane, 5 grams of ethyl orthosilicate acidic hydrolyzate, aluminum phosphate solution 3 grams, magnesium aluminum silicate fiber 2.5 grams. The above components are dispersed, mixed, billeted, and dried at 80°C for 10 hours to obtain a block with a bulk density of 90 kg / m3 and a thermal conductivity (tested by hot wire method) of 0.039w / m.k. Calcined in a muffle furnace at 1000°C for 100 hours, the weight loss was 1.4wt%, and the green body was intact.

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PUM

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Abstract

The invention relates to a nano composite inorganic flame-retardant heat insulated board rich in SiO2, which is characterized in that the form of the board is a planar or allotypic inorganic nano composite board, and the board is a compound of micron holes and granules, nano holes and granules and fiber structure. The board comprises the following components by weight percentage: 40 to 80 percent of SiO2 powder, 10 to 30 percent of zirconium oxide superfine powder, 0 to 20 percent of inorganic closed-hole micro-bead material, 2 to 15 percent of expanded perlite, 0 to 15 percent of vermiculite, 0.1 to 2 percent of coupling agent, 2 to 10 percent of adhesive, 0 to 6 percent of calcium silicate fiber, 0 to 10 percent of magnesium aluminum silicate fiber, and 0 to 10 percent of aluminum silicate fiber; and the components are subjected to dispersion, blending, blank forming, airing or drying to prepare the board, wherein the drying temperature is no more than 120 DEG C. Preparation equipment comprises a vacuum powder suction device, a mixing machine, and an automatic blank manufacturing machine.

Description

technical field [0001] The present invention relates to an inorganic thermal insulation material and its preparation process, in particular to a light-weight inorganic composite composite plate rich in nanopores and particles, micropores and particles, and fiber structure and its production process. The composition is silicon dioxide and zirconium dioxide, which can be widely used in aviation, petroleum, chemical industry, electric power, construction, metallurgy and other fields. Background technique [0002] At present, the widely used inorganic insulation materials include calcium silicate insulation board and aluminum magnesium silicate board. The bulk density of the product is generally above 180 kg / m3, and the thermal conductivity at room temperature is above 0.07, and the thermal conductivity at high temperature is even higher. Moreover, a long drying process is required in the production process, which not only wastes energy, but also restricts its use in aviation an...

Claims

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Application Information

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IPC IPC(8): C04B28/34C04B26/00C04B20/06C04B14/38C04B24/40
CPCC04B2111/28C04B28/34C04B28/00C04B2111/00008
Inventor 汪培庆汪庆锋汪国庆谢志勇
Owner 上海暄洋化工材料科技有限公司
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