Organic metal borate of ferroelectric material and preparation method and application thereof

A technology of organometallic and ferroelectric materials, applied in the direction of nickel organic compounds, etc., can solve the problems of low ferroelectric coupling coefficient, application limitation, small relative permittivity, etc., achieve good repeatability, high yield, and simple preparation process Effect

Inactive Publication Date: 2010-01-27
GUANGDONG UNIV OF TECH
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Problems solved by technology

However, due to the low ferroelectric coupling coefficient and relatively small relative permittivity of organic ferroelectri

Method used

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Experimental program
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Embodiment Construction

[0011] 1. Preparation of compounds

[0012] Weigh nickel chloride (NiCl 2 ) 0.36g, boric acid (H 3 BO 3 ) 2.74g, measure diethylenetriamine (C 4 h 13 N 3 ) 2.0ml, pyridine (C 5 h 5 N) 8.0ml, water (H 2 (0) 1.0ml as raw material, its molar ratio is 1: 27: 25: 137: 17, stirred for 5min, put into a closed 28mL reaction kettle, warmed up to 200°C, kept at constant temperature for 2 days, took it out and let it cool naturally at room temperature After cooling, crystals can be obtained. Through X-ray single crystal diffraction analysis, it is determined that the crystal is [Ni(C 4 h 10 N 2 )(C 2 h 8 N 2 ) 2 ][B 5 o 6 (OH) 4 ] 2 .

[0013] 2. Performance test

[0014] We conducted research on the obtained organometallic borate and found that the relationship curve between the polarization intensity P and the applied electric field intensity E of the complex shows an obvious ferroelectric effect, Pr=0.075μC / cm 2 , Ps=0.01μC / cm 2 .

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Abstract

The invention discloses organic metal borate of a ferroelectric material and a preparation method and applications thereof. The molecular formula of borate is C8H34B10N6NiO20, the space group is C2(No.5), and the unit cell parameter is indicated as follows: alpha=gamma=90.00 degrees, belta=96.875 (10) degrees, Z=2 and unit cell volume V=1445.6(4) angstroms<3>; the ferroelectric material is prepared under the hydrothermal condition by in situ synthesis; reagents of nickel dichloride (NiCl2), boracic acid (H3BO3) and diethylenetriamine (C4H13N3) serve as raw materials, and water and pyridine are used as solvents; the ferroelectric material is applied to a pagination unit for storing and recovering information, transmitting optical information, displaying image and holography and is applied to storing holography of a ferroelectric light valve array.

Description

technical field [0001] The invention relates to a ferroelectric material organometallic borate and its preparation method and application. Background technique [0002] Ferroelectric material is a kind of multifunctional material with properties of ferroelectricity, piezoelectricity, pyroelectricity, electro-optic and nonlinear optics at the same time. The so-called ferroelectric material refers to a material whose crystal structure has spontaneous polarization when no external electric field is applied, and the direction of its spontaneous polarization can be reversed or reoriented by an external electric field. This property of the material is known as "ferroelectricity" or "ferroelectric effect". In recent years, ferroelectric materials have developed extremely rapidly and have been widely used in electronic technology, laser technology, infrared detection technology, ultrasonic (and microwave acoustics) technology, solid-state memory and display technology, and other en...

Claims

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Application Information

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IPC IPC(8): C07F15/04
Inventor 潘春阳赵丰华李大光欧阳萍
Owner GUANGDONG UNIV OF TECH
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