Metal-coated fabric
A technology of metal cladding and fabric, which is applied in the direction of fabric, textile, textile and papermaking, etc. It can solve the problems of damage to the softness of the fabric and increase the number of processing steps, and achieve the effect of excellent adhesion and excellent electromagnetic wave shielding
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[0093] Preparation of the mixed treatment liquid is not particularly limited. A method capable of uniformly dispersing and mixing various raw materials may be used. Examples thereof include dispersion mixing by propeller stirring, and dispersion mixing by kneading with a kneader, a drum, or the like.
[0094] The flame-retardant metal-clad fabric of the present invention can be produced by forming a layer composed of the composition (G) on the metal-clad fabric by, for example, a direct coating method, a lamination method, or an adhesive method.
[0095] As a coating method, a common method using a knife coater, a roll coater, a slit coater, etc. can be used.
[0096] After coating the mixed treatment liquid on the metal-coated fabric, the solvent is removed by drying or the like to form a flame-retardant coating layer composed of the composition (G).
[0097] The application amount of the mixed treatment solution on the metal-coated fabric can be set to 100 to 300% by weigh...
Embodiment 1
[0128] (Manufacturing of metal clad fabric)
[0129] After refining, drying and heat-treating the polyester fiber fabric (warp yarn 56dtex / 36f, weft yarn 56dtex / 36f), in the 40 After immersing in an aqueous solution at ℃ for 2 minutes, wash with water. Next, it was immersed in fluoboric acid at an acid concentration of 0.1N at 30° C. for 5 minutes, and then washed with water. Then, it was immersed in a 30° C. electroless copper plating solution containing 7.5 g / L of copper sulfate, 30 ml / L of 37% formalin, and 85 g / L of Rochelle salt for 5 minutes, followed by washing with water. Next, in an electroplating nickel solution containing 300g / L of nickel sulfamate, 30g / L of boric acid, and 15g / L of nickel chloride, at 35°C, at 5A / dm 2 Immerse for 10 minutes at a current density of 10 minutes to wash the nickel after lamination. Copper plating 10g / m on the fabric 2 , Nickel 4g / m 2 . The weight per unit area of the resulting metal clad fabric was 64 g / m 2 .
[0130] On both...
Embodiment 2
[0156] A metal-coated fabric and a gasket were obtained in the same manner as in Example 1, except that the mixed treatment liquid of the following formulation 3 was used to form the flame-retardant layer.
[0157] Recipe 3
[0158] Aluminum diethylphosphinate 28 parts
[0159] 2,4,6-trimethoxy-2,4,6-triphenoxycyclotriphosphazene 8 parts
[0160] 8 parts melamine cyanurate
[0161] Thermally expandable graphite (average particle size 50 μm) 12 parts
[0162] 6 parts of biphenyl diphenyl phosphate
[0163] (Phosphorus content 8.8%)
[0164] Rezamin UD-1305 40 parts
[0165] (Ester-based polyurethane resin, manufactured by Dainichi Seika Co., Ltd., with a heat softening temperature of 90 to 100°C)
[0166] Appropriate amount of dimethylformaldehyde
[0167] In addition, the viscosity was adjusted to 8000 cps by adjusting the addition amount of dimethylformaldehyde.
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