Comprehensive utilization method for bittern
A brine and process technology, applied in the field of salt chemical industry, can solve the problems of waste of resources, pollution of the environment, unavailability of other components, etc.
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Embodiment 1
[0044] The deep marine potassium-rich brine is pressurized and sprayed from the upper part of the aeration tower, and the air enters from the lower part of the tower to release the H released from the brine. 2 S gas carried out, H carried out with the air 2 S enters the boiler's air intake system under negative pressure and is oxidized to SO in the high temperature zone of the furnace. 2 , to remove SO through the boiler tail gas desulfurization unit 2 ; Under stirring conditions, add the 10% emulsion made of calcium oxide water into the 2 Magnesium is precipitated in the brine of S and separated by filtration. The temperature of the solution during precipitation is 35° C., and the pH of the precipitation end point is 10.0; a sodium carbonate solution with a saturation of 70% is added to precipitate calcium in the brine in which magnesium has been removed, and the amount of sodium carbonate added is the same as The molar ratio of calcium is 1.2:1, the reaction temperature is...
Embodiment 2
[0047] The pressurized brine is sprayed from the upper part of the aeration tower, and the air enters from the lower part of the tower to release the H released from the brine 2 S gas is brought out. H carried out with the air 2 S enters the secondary air intake system of the boiler under negative pressure conditions, and is oxidized into SO in the high temperature zone of the furnace. 2 , to remove SO through the boiler tail gas desulfurization unit 2 ; Under stirring conditions, add the 20% emulsion made of calcium oxide water into the 2Magnesium is precipitated in the brine of S, the temperature of the solution during precipitation is 50°C, and the pH of the precipitation end point is 11.5; a sodium carbonate solution with a saturation of 90% is added to precipitate calcium in the brine that has been removed from magnesium, and the amount of sodium carbonate added is related to the mole of calcium. The ratio is 1.8:1, the reaction temperature is 50°C, filtered, washed an...
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