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Low-nickel austenitic stainless steel and manufacturing method thereof

A technique for austenitic stainless steel and its manufacturing method, which is applied in the field of austenitic stainless steel, can solve problems such as not being very high and reducing the stability of austenite, and achieve the effects of reducing raw material costs, improving formability, and avoiding delayed cracking

Inactive Publication Date: 2010-06-09
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] In Table 1 and Table 2, the patent ZL98117555.4 describes the chemical composition of a nickel-saving austenitic stainless steel, in which the nickel content is reduced to an extremely low content (0.1%≤Ni≤2.0%), but The manganese content (5.0%≤Mn≤9.0%) is not very high and the range is too wide, which will reduce the stability of austenite, making it difficult to avoid excessive strain-induced martensite during room temperature deformation and reduce the formability of stainless steel

Method used

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  • Low-nickel austenitic stainless steel and manufacturing method thereof
  • Low-nickel austenitic stainless steel and manufacturing method thereof
  • Low-nickel austenitic stainless steel and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] Adopt electric arc furnace and AOD two-step method to smelt stainless steel, feed Ca-Si-Ba wire and Fe-B wire before continuous casting to realize Ca treatment and B alloying treatment, continuous casting into slab, hot rolling into 3.00mm thick of hot-rolled coils. After intermediate annealing, the intermediate annealing temperature is 100-1100°C, and then the volume fraction of strain-induced martensite after annealing and at different cold rolling reductions is tested respectively. The specific results are shown in Table 4. The chemical composition of the nickel-saving austenitic stainless steel in this embodiment is shown in Table 3.

[0071]

[0072] Table 4 Comparison of strain-induced martensite volume fraction between Example 1 and 4% Ni-free austenitic stainless steel at different cold rolling reductions

[0073]

Embodiment 2

[0075] Stainless steel is smelted by electric furnace, AOD, VOD three-step method. Feed Ca-Si-Ba wire and Fe-B wire before continuous casting to realize Ca treatment and B alloying treatment, continuous casting into slab, hot rolling into 3.00mm thick hot-rolled coil. Through intermediate annealing, pickling, then carry out cold rolling, test gained nickel-saving type austenitic stainless steel cold after passing through 50% cold rolling reduction, the changing situation of the cold-rolled sheet hardness of stainless steel of the present invention, its result is as table 5 shown. The chemical composition of the nickel-saving austenitic stainless steel in this embodiment is shown in Table 3.

[0076] Table 5 Hardness comparison between Example 2 and 4% Ni-free austenitic stainless steel at different cold rolling reductions

[0077]

Embodiment 3

[0079] Stainless steel is smelted by electric arc furnace single smelting method, and continuously cast into slabs. Ca treatment and B alloying treatment are achieved by feeding Ca-Si-Ba wire and Fe-B wire before continuous casting. Then cut a slab of 200mm×200mm×100mm from the central part of the continuous casting slab, and keep it at 1000°C, 1050°C, 1100°C, 1150°C, 1200°C, and 1250°C for 30 minutes respectively, and then adopt rapid water cooling. The high-temperature structure was fixed and the content of high-temperature ferrite was tested with a ferrite meter. The results are shown in Table 6.

[0080] Table 6 High-temperature ferrite content of Example 3 after high-temperature heating

[0081] Test conditions

[0082] Test conditions

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Abstract

The invention relates to a low-nickel austenitic stainless steel, which comprises the following chemical components by weight percent: no less than 0.05% and no more than 0.15% of C, less than 1.00% of Si, more than 9.00% and less than 10.00% of Mn, no less than 14.00% and no more than 16.00% of Cr, no less than 0.50% and less than 1.00%, more than 0.15% and no more than 0.25% of N, more than 1.50% and no more than 2.00% of Cu, no less than 10*10<-4>% and no more than 30*10<-4>% of B, no less than 1*10<-4> and no more than 50*10<-4>% of Ca, less than 0.030% of P, no less than 0.020% of S and the balance of Fe and inevitable impurities. For the stainless steel, heat processing performance of materials is improved through B alloying treatment on premise of further reducing the content of precious metal of nickel, and the purity of the liquid steel is enhanced through Ca treatment. The formability of stainless steel is enhanced through the reasonable alloy system design and a micro-alloy treatment method, the defects of sand buckle, sand holes, and the like are avoided in the forming process, the delayed rupture phenomenon is lightened, and the application scope of the festival nickel austenitic stainless steel is further broadened.

Description

technical field [0001] The invention relates to austenitic stainless steel, in particular to a nickel-saving austenitic stainless steel with excellent hot workability and formability. Background technique [0002] At present, the austenitic stainless steels widely used at home and abroad are mainly 300 series and 200 series, such as AISI304 and AISI201 and other austenitic stainless steels. However, these austenitic stainless steels contain more nickel, and the addition of a large amount of nickel leads to The cost of raw materials of these austenitic stainless steels increases, thus limiting the application range and sustainable development of these steels. [0003] Traditional nickel-saving austenitic stainless steels, including AISI201 and AISI301, etc., as shown in Table 2, generally adopt the alloying method of nitrogen and manganese replacing nickel, which obviously reduces the cost of raw materials, but due to the austenite stabilizing elements The reduction of nicke...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/58C21C7/04C21C7/072C21D1/26
Inventor 秦效华
Owner BAOSHAN IRON & STEEL CO LTD
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