The invention discloses a preparation method of
phosphorus-doped and closed-pore synergistically regulated
biomass hard carbon and application of the
phosphorus-doped and closed-pore synergistically regulated
biomass hard carbon in a negative
electrode of a
sodium-
ion battery, and belongs to the technical field of
electrode materials. The preparation method comprises the following steps: preparing a water-based
starch suspension with a certain
mass fraction by taking
starch as a
biomass precursor, carrying out a cross-linking reaction through
sodium trimetaphosphate to form a
phosphate ester bond bridged stable
network structure, pre-oxidizing the cross-linked precursor, and then carbonizing in a high-temperature
inert atmosphere to obtain the water-based
starch composite material. And the hard carbon material with expanded interlayer spacing,
phosphorus doping and high closed pore volume is prepared. The material shows high reversible capacity, high initial coulombic efficiency, excellent rate capability and
cycling stability when being used as a
sodium-
ion battery negative
electrode active material. According to the preparation method disclosed by the invention, through a simple cross-linking-carbonizing process, cooperative regulation and control of
heteroatom doping and a closed-pore structure are realized, and a new strategy is provided for large-scale preparation of the high-performance biomass hard carbon negative electrode.