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A rare earth permanent magnet with high magnetic performance and high resistivity and its preparation method

A technology of rare earth permanent magnets and high resistivity, which is applied in the direction of mixing methods, chemical instruments and methods, inductance/transformer/magnet manufacturing, etc. It can solve the problems of magnet difficulty, magnet magnetic performance decline, low resistivity, etc., and achieve high resistance efficiency, improvement of surface insulation properties, and high magnetic properties

Active Publication Date: 2011-11-30
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the bonded magnet is applied in a high-frequency alternating field, due to its low resistivity, strong eddy currents are likely to be generated on the surface of the magnet, resulting in a rapid increase in the temperature of the magnet, and the magnetic properties of the magnet will be seriously affected. Therefore, ordinary bonded rare earth It is difficult for permanent magnets to be applied in high-frequency fields
[0003] In the prior art, one method is a multi-pole electrical insulation R-Fe-B permanent magnet introduced in Japanese Patent Publication No. 8-279407, which is a sintered magnet, which is formed after the magnet is sintered. The method of vacuum evaporation is used to coat a layer of 2-10 μm polyimide resin film on the surface of the magnet to improve its insulation performance, but the magnet obtained by this method still cannot be used under a higher frequency alternating magnetic field. Avoid the loss of magnetic properties caused by the internal heating of the eddy current of the magnet
In addition, Chinese patents such as CN97121777.7 and CN02157615.7 all mentioned the method of adding insulating additives to rare earth permanent magnets to improve their electrical insulation performance. From the results, the electrical insulation performance has indeed been significantly improved, but due to The addition of a large amount of insulating additives has caused a serious decline in the magnetic properties of the magnet, and at the same time its molding process is a non-oriented molding method, which also makes it difficult to further improve the magnetic properties of the magnet, making it difficult for the magnet mentioned in the invention to be widely used in practice

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] (1) Surface coupling of magnetic powder: The magnetic powder used is NdFeB, and its composition is Nd with an average particle size of 20 μm 2 Fe 14 B, 0.1 part of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 30 parts by weight of xylene organic solvent were added to 100 parts by weight of magnetic powder, and stirred by high-speed shear at a speed of 2000 rpm for 0.5h. The above solution is mixed evenly, and the magnetic powder and the coupling agent can be fully mixed by ultrasonic vibration for 0.5h, and then the mixture is heated while stirring until the solvent is volatilized, and the modified magnetic powder is dried and ground for use; (2) 1 weight part of 725-2-A bisphenol A epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation, 725-2-F bisphenol F epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation Add the mixed solution of 0.2 parts ...

Embodiment 2

[0024] (1) Surface coupling of magnetic powder: the magnetic powder used is samarium cobalt magnetic powder, and its composition is Sm 2 co 17 , with an average particle size of 40 μm, 2 parts by weight of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 35 parts by weight of alcohol are added to 100 parts by weight of magnetic powder, and stirred by high-speed shear at a speed of 500 rpm Mix the above solution evenly for 1 hour, and vibrate the magnetic powder and the coupling agent through ultrasonic vibration for 1 hour to fully mix, then heat the mixture while stirring until the solvent is evaporated, dry the modified magnetic powder and grind it for use; (2 ) 6.5 parts by weight of 725-2-A bisphenol A epoxy resin produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation, 725-2-F bisphenol F ring produced by the No. 725 Research Institute of China Shipbuilding Industry Corporation Add the mixture of 1.3 parts b...

Embodiment 3

[0027](1) Surface coupling of magnetic powder: the magnetic powder used is samarium cobalt magnetic powder, and its composition is SmCo 5 , 5 parts by weight of titanate coupling agent NDZ401 produced by Nanjing Shuguang Chemical Co., Ltd. and 30 parts by weight of xylene were added to 100 parts by weight of magnetic powder, and the above-mentioned The solution is mixed evenly, and the magnetic powder and the coupling agent can be fully mixed by ultrasonic vibration for 1.5 hours, and then the mixture is heated while stirring until the solvent is volatilized, and the modified magnetic powder is dried and ground for use; (2) 725-2-A bisphenol A epoxy resin produced by the No.725 Research Institute of China Shipbuilding Industry Corporation, 2 parts by weight of 725-2-F bisphenol F epoxy resin produced by the No.725 Research Institute of China Shipbuilding Industry Corporation Add the mixed solution with the organic solvent acetone to 105 parts by weight of the magnetic powder a...

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PUM

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Abstract

The invention relates to a rare earth permanent magnet material technology, and specifically introduces a rare earth permanent magnet with high magnetic performance and high resistivity and a preparation method thereof. 100 parts, 0.1-5 parts of titanate coupling agent, 1-10 parts of bisphenol A epoxy resin, and 0.2-2 parts of bisphenol F epoxy resin are uniformly mixed at 20-200 ℃ temperature field and magnetic field strength: The cured product is formed under the orientation field of 0.5-3T; the preparation process includes coupling the surface of the magnetic powder with the coupling agent, then mixing with the resin, drying and grinding, and forming under the temperature field and the orientation field. Compared with the high-end bonded NdFeB magnet, the magnetic performance of the permanent magnet of the present invention maintains a relatively high level, and the magnetic performance is not significantly decreased, and the magnet resistivity is increased by more than 10 times; there is no obvious temperature rise under a high-frequency alternating field for 1 hour.

Description

technical field [0001] The invention relates to a technology in the field of rare earth permanent magnet materials, in particular to a rare earth permanent magnet with high magnetic performance and high resistivity and a preparation method thereof. Background technique [0002] Compared with sintered permanent magnets, bonded magnets have many advantages such as high cost performance, convenient forming of special-shaped magnets, high processing precision, good toughness, small magnetic deviation, and easy miniaturization. Therefore, bonded magnets have been widely used in the fields of computers, mobile communications, high-end audio, micro-special motors, sensors, and magnetoelectric instruments. When the bonded magnet is applied in a high-frequency alternating field, due to its low resistivity, strong eddy currents are likely to be generated on the surface of the magnet, resulting in a rapid increase in the temperature of the magnet, and the magnetic properties of the mag...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F7/02H01F41/02B01F3/12B22F3/00
Inventor 谢述锋王岳王德义
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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