Hydrogen generator and application thereof
A generator and hydrogen technology, applied in hydrogen, chemical instruments and methods, inorganic chemistry, etc., can solve problems such as adverse effects, increased surface area, and limited improvement effects, and achieve extremely rich economic value, uniform temperature distribution, and good heat transfer The effect of potency
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[0059] Example 1: 200 liters / hour hydrogen production test
[0060] Use as figure 1 The cylindrical hydrogen generator 1 shown here uses aluminum alloy (AI-6061) as the first medium constituting the hydrogen generator 1, wherein the hydrogen generator 1 has a diameter of about 51 mm and a depth of about 50 mm, and each hole The shortest distance a between them is about 1 mm. The diameter of the oxidation zone 12 in the center of the hydrogen generator 1 is about 13 mm and the depth is about 50 mm. The oxidation zone 12 is filled with about 9 grams of PBN oxidation catalyst; the diameter of the 8 holes in the preheating zone 14 is about 7 The diameter of the 16 pores in the recombination zone 16 is about 7 mm and the depth is about 50 mm, and the pores in the recombination zone 16 are filled with about 43 grams of recombination catalyst JM-51.
[0061] Use methanol as a raw material for hydrogen production, and use a mixture of methanol and air as a fuel for the oxidation reaction....
Example Embodiment
[0062] Example 2: 200 liters / hour hydrogen production test
[0063] The methanol vapor recombination reaction was carried out in the same hydrogen generator and method as in Example 1. However, brass (70% Cu, 30% Zn, thermal conductivity of about 121W / mK) is used as the first medium of the hydrogen generator 1, and the supply rate of methanol in the fuel is adjusted so that the hydrogen generation rate reaches 200 liters / hour . Measure the temperature distribution of the hydrogen generator 1, calculate the thermal efficiency of hydrogen and total methanol, and analyze the carbon monoxide content in the hydrogen-containing mixed gas, and record the results in Table 1.
Example Embodiment
[0070] Example 4: 200 liters / hour hydrogen production test
[0071] Use as figure 2 The rectangular hydrogen generator 2 shown uses aluminum alloy (Al-6061) as the first medium constituting the hydrogen generator 2. The size of the hydrogen generator 2 is about 55 mm × about 34 mm × about 50 mm, And the shortest distance a between the channels is about 1.5 mm. The pore diameter of the oxidation zone 22 of the hydrogen generating device 2 is about 9 mm and the depth is about 50 mm. The oxidation zone 22 is filled with about 4 grams of PBN oxidation catalyst; the pore diameter of the preheating zone 24 is about 7 mm and the depth is about About 50 mm; the diameter of the pores of the recombination zone 26 is about 9 mm and the depth is about 50 mm, and the pores of the recombination zone 26 are filled with about 29 grams of recombination catalyst JM-51.
[0072] As in Example 1, methanol and water are used as raw materials for hydrogen production, and a mixture of methanol and air ...
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