The invention belongs to the field of synthesis of organosilicone, and specifically relates to
liquid silicon resin and a preparation method and application thereof. The
liquid silicon resin is particularly applied to the preparation of
silicone sealant as a
plasticizer replacing
simethicone. The preparation method of the
liquid silicon resin is prepared through a reaction kettle which is equipped with an agitating device and a condensing reflowing device. The preparation method comprises the following steps: a, preparing raw materials, namely, mixing methyl
trichlorosilane and dimethyldichlorosilance, and controlling the temperature of the reaction kettle to be below 5 DEG C; b, dropwise adding and reacting, namely, dropwise adding concentrated
hydrochloric acid to the reaction kettle, controlling the temperature of a
reaction system to be -10 to 5 DEG C, reacting until no bubble is produced after dropwise adding concentrated
hydrochloric acid, and separating oil and water of the
reaction system; c, neutralizing oil layer, namely, adding a
solid alkaline substance to the oil layer obtained by separating in step b while agitating in order to neutralize the oil layer to reach the neutrality; d, filtering the oil layer, namely, filtering the neutral oil layer obtained in step c, wherein the filtrate is the primary liquid
silicon resin; finally refining at low temperature to obtain the refined liquid
silicon resin.