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Compatilizer, application thereof in polyphenyleneoxide/nylon alloy and preparation method of polyphenyleneoxide/nylon alloy

A polyphenylene ether and compatibilizer technology, applied in chemical instruments and methods, compounds containing elements of group 3/13 of the periodic table, organic chemistry, etc. Insufficient compatibility and other problems, to achieve excellent compatibilization effect, improve compatibility, and improve system compatibility

Active Publication Date: 2011-04-20
山东三岭汽车内饰有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the content of reactive functional groups and insufficient reactivity, a more satisfactory compatibility modification effect has not been achieved.

Method used

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  • Compatilizer, application thereof in polyphenyleneoxide/nylon alloy and preparation method of polyphenyleneoxide/nylon alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Preparation of borate esters with dual active functional groups

[0026] Add 100 parts of boric acid and 50 parts of gluconic acid into a three-necked glass flask with a stirrer, thermometer and water separation and reflux device, and add 10 parts of toluene as a solvent, heat in an oil bath, and stir the reaction at 90 ° C. Toluene and The water generated by the reaction forms an azeotrope and gradually evaporates, and the generated water is separated through the water separation and reflux device. After reacting for 8 hours, distill under reduced pressure at 88 kPa for 40 minutes to remove the remaining toluene, a small amount of water and excess polyhydric acid. Carboxylic acid or its derivatives are used to obtain borate ester products with dual active functional groups, which are sealed and dried.

[0027] (2) Mix 100 parts of dried polyphenylene ether, 1 part of boric acid ester, 1 part of maleic anhydride, and 0.2 part of dicumyl peroxide at 60°C, and then ad...

Embodiment 2

[0030] (1) Preparation of borate esters with dual active functional groups

[0031]Add 100 parts of boric acid and 150 parts of tartaric acid into a three-neck glass flask with a stirrer, thermometer and water separation and reflux device, and add 50 parts of toluene as a solvent, heat in an oil bath, and stir the reaction at 60 ° C. Toluene and The water generated by the reaction forms an azeotrope and gradually evaporates, and the water generated is separated by a water separation and reflux device. After reacting for 9 hours, it is distilled under reduced pressure at 60 kPa for 40 minutes to remove the remaining toluene, a small amount of water and excess polyhydric acid. Carboxylic acid or its derivatives are used to obtain borate ester products with dual active functional groups, which are sealed and dried.

[0032] (2) Mix 100 parts of dried polyphenylene ether, 5 parts of borate ester and 0.1 part of dicumyl peroxide uniformly at 60°C, and then add them into a twin-scre...

Embodiment 3

[0035] (1) Preparation of borate esters with dual active functional groups

[0036] Add 100 parts of boric acid and 300 parts of citric acid into a three-neck glass flask equipped with a stirrer, thermometer and water separation and reflux device, and add 100 parts of toluene as a solvent, heat in an oil bath, and stir at 120°C. Toluene Form an azeotrope with the water generated by the reaction and gradually distill it out, and separate the generated water through a water separation and reflux device. After reacting for 8 hours, distill under reduced pressure at 90 kPa for 40 minutes to remove the remaining toluene, a small amount of water and excess Polybasic carboxylic acid or its derivatives are used to obtain borate ester products with dual active functional groups, which are sealed and dried for storage.

[0037] (2) Mix 100 parts of dried polyphenylene ether, 2 parts of boric acid ester, 5 parts of maleic anhydride, and 0.5 parts of dicumyl peroxide at 60°C, and then ad...

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Abstract

The invention relates to a compatilizer, an application of the compatilizer in a polyphenyleneoxide / nylon alloy and a preparation method of the polyphenyleneoxide / nylon alloy. The compatilizer provided by the invention is boronic acid ester prepared from boronic acid and substances containing hydroxy groups and carboxyl groups, can be directly used for preparing the polyphenyleneoxide / nylon alloy, and also can be subjected to melt extrusion with polyphenyleneoxide to be prepared into a polyphenyleneoxide blending compatibilization system which is used for preparing the polyphenyleneoxide / nylon alloy. The preparation method of the polyphenyleneoxide / nylon alloy is implemented as follows: drying and evenly stirring the compatilizer or the polyphenyleneoxide blending compatibilization system, polyphenyleneoxide and nylon; and feeding the mixture in a double screw extruder for extrusion to obtain the compatibilization modified polyphenyleneoxide / nylon alloy, wherein the screw temperature is 170-295 DEG C and the screw revolving speed is 70-120 revolutions / minute. The invention has the advantages of being convenient in processing, having simple process, notable compatibilization effect, remarkably improved tensile property and bending property, favorable and stable comprehensive property and wide industrial application prospect, and satisfying strength requirements of common applications.

Description

technical field [0001] The invention relates to a compatibilizer, the application of the compatibilizer in polyphenylene ether / nylon alloy and the preparation method of the alloy. Background technique [0002] Polyphenylene oxide (PPO) is an amorphous polymer obtained by polymerization of 2,6-dimethylphenol through oxidative coupling. It is a high heat-resistant engineering plastic with good creep resistance. , at 23°C and 14MPa load, the creep value after 300 hours is less than 0.5%, and the creep value changes little with the increase of temperature. However, it has high brittleness, poor processability and solvent resistance, its melting temperature is 262-267°C, and its melt viscosity is very high below 300°C, making it impossible to process and shape, which limits its application range. For this reason, it is necessary to realize its wide industrial application through alloying or compound modification. [0003] Nylon (Polyamide, referred to as PA) is a tough angular ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K5/55C07F5/04C08L71/12C08L77/00C08L77/02C08L77/06
Inventor 张亚通李英李立邸玉龙瞿雄伟
Owner 山东三岭汽车内饰有限公司
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