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Plastic product and preparation method thereof

A plastic product and plastic technology, applied in chemical instruments and methods, layered products, thin material processing, etc., can solve the problems of complex metallization process and high energy requirement on the surface of plastic, and achieve low cost, low energy requirement and simple process Effect

Active Publication Date: 2012-05-30
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention solves the technical problems of complex plastic surface metallization process and high energy requirements in the prior art

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0016] The invention provides a kind of preparation method of plastic product, comprises the following steps:

[0017] 1) forming a plastic substrate; the plastic substrate is a thermoplastic or thermosetting plastic containing an electroless plating catalyst, and the electroless plating catalyst is evenly distributed in the thermoplastic or thermosetting plastic; the electroless plating catalyst is a compound shown in formula I, II or III;

[0018] CuFe 2 o 4-δ ................................... Formula I

[0019] Ca 0.25 Cu 0.75 TiO 3-β ................................Formula II

[0020] TiO 2-σ ...................................Formula III

[0021] Among them, δ is the degree of oxygen deficiency in the compound shown in formula I, 0.05≤δ≤0.8; β is the degree of oxygen deficiency in the compound shown in formula II, 0.05≤β≤0.5; σ is the degree of oxygen deficiency in the compound shown in formula III The degree of oxygen deficiency in the compound, 0.05≤σ≤1.0;

...

Embodiment 1

[0059] (1) Under continuous stirring, prepare Cu(NO 3 ) 2 and Fe(NO 3 ) 3 The mixed solution with a concentration of 0.5mol / L was dripped into the potassium hydroxide solution at a rate of 1ml / min with a peristaltic pump, and the temperature was rapidly raised to 80°C, and the stirring was continued for 24 hours. During the stirring process, the pH was kept within 10-11. The product was washed with distilled water and acetone, filtered, dried at 120°C for 24 hours, and ground to 300 mesh.

[0060] (2) Preparation of electroless plating catalyst:

[0061] In high purity N 2 The product of step (1) was calcined at 1000°C under protection for 4 hours, ground for 10 hours until the average particle size of the powder was 700nm, and the electroless plating catalyst CuFe of this embodiment was obtained. 2 o 4-δ , chemical analysis method to measure the degree of oxygen deficiency δ = 0.35.

[0062] (3) Plastic matrix molding:

[0063] With the CuFe of PC / ABS resin, step (2) ...

Embodiment 2

[0068] (1) Preparation of Ca by solid phase sintering method 0.25 Cu 0.75 TiO 3 :

[0069] CaCO3, CuO, TiO 2 The powder is dosed according to the stoichiometric ratio and mixed evenly, transferred to a ball mill for ball milling, using anhydrous alcohol as the grinding medium, milled for 8 hours, pre-calcined at 800°C for 10 hours after infrared drying, and obtained Ca 0.25 Cu 0.75 TiO 3 .

[0070] (2) Preparation of electroless plating catalyst:

[0071] Ca 0.25 Cu 0.75 TiO 3 , the calcination time is 4h, and the average particle size of the powder is ground to 500nm to obtain the electroless plating catalyst Ca of the present embodiment 0.25 Cu 0.75 TiO 3-β , chemical analysis method to measure the degree of oxygen deficiency β = 0.16.

[0072] 3) Plastic matrix molding:

[0073] The Ca of PP resin, step (2) 0.25 Cu 0.75 TiO 3-β (β=0.16), antioxidant 1076 and polyethylene wax are mixed in a mass ratio of 100:10:0.2:0.1, extruded and granulated, and injection...

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Abstract

The invention provides a plastic product and a preparation method thereof. The method comprises the following steps: 1) forming a plastic base, wherein the plastic base contains chemically plated catalysts which are compounds shown in the formula I, II or III; 2) removing the plastics in the selected area on the surface of the plastic base and exposing the chemically plated catalysts in the corresponding area; and 3) chemically plating copper or nickel and continuing chemical plating and / or electroplating at least once to form a metal layer on the surface of the plastic base. The preparation method provided by the invention has the advantages of simple process, low requirement for energy and low cost. In addition, the chemically plated catalysts are distributed in the plastic base, so theplating layer formed after chemical plating and the plastic base have very high adhesion.

Description

technical field [0001] The invention belongs to the field of surface metallization of non-metallic materials, and in particular relates to a preparation method of a plastic product and a plastic product. Background technique [0002] A metal layer is formed on the surface of the plastic, which is used as a channel for electromagnetic signal transmission, and is widely used in automobiles, industries, computers, communications and other fields. The selective formation of a metal layer on the plastic surface is a core link in the manufacture of such plastic products. There are many methods for plastic surface metallization production lines. In the prior art, metal nuclei are first formed on the surface of the plastic substrate as the electroless plating catalytic active center, and then electroless plating is performed. [0003] For example, US2003031803A1 discloses the use of metal oxide particles such as ZnO, TiO 2 , ZrO 2 、Al 2 o 3 , CeO 2 It is coated on the surface ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C18/20C23C18/16C23C18/38C23C18/32
CPCC23C18/22C23C18/32C23C18/204C23C18/1653H05K2201/09118C23C18/1641H05K3/182C23C18/40H05K3/384C23C18/38C25D5/56C23C18/2006C23C18/42C23C18/2013H05K2203/107H05K3/4605H05K3/422C25D5/12H05K3/4661C23C18/1651H05K3/105C23C18/1639H05K3/185Y10T428/12569C23C18/20C23C28/00B32B15/043B32B15/08H05K1/056
Inventor 宫清周良苗伟峰张雄
Owner BYD CO LTD
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