Light hydrocarbon aromatization catalyst and preparation method thereof
A catalyst and aromatization technology, which is applied in the field of aromatization catalyst containing zinc and its preparation field, can solve the problems of less than 20% of total utilization rate, low utilization rate of refinery gas, large amount of carbon deposits on catalyst, etc. The effect of low yield, low carbon deposition and long life per pass
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preparation example Construction
[0024] The preparation method of the catalyst of the present invention includes adding silica sol to HZSM-5 powder, making the mass ratio of silica sol and HZSM-5 0.3 to 20.0:1, preferably 0.5 to 15.0:1, kneading evenly, and extrusion molding , drying and calcining to obtain a composite carrier, impregnating the composite carrier with a solution containing a zinc compound and a rare earth compound, then drying, calcining, and treating with water vapor at 450-700°C.
[0025] The pH value of the silica sol is not greater than 6.0, preferably not greater than 4.0, and more preferably 1.0 to 4.0. If the pH value of the acidic silica sol does not meet the requirements, nitric acid, hydrochloric acid, formic acid or acetic acid can be added, preferably nitric acid to adjust the pH of the silica sol. pH. The silicon oxide content of the silica sol is 5-70% by mass, preferably 30-40% by mass, and the particle size of the solid particles in the silica sol is 10-50 nm, preferably 20-30 ...
example 1
[0032] Preparation of the catalyst of the present invention.
[0033] (1) Preparation of composite carrier
[0034] Get 50g of HZSM-5 zeolite powder (zeolite content 95% by mass) with a silica / alumina molar ratio of 55, add 68g of acidic silica sol with a pH value of 4 and a particle size of 20 nm (with a silica content of 30% by mass, Beijing Hengtai Kaida Science and Trade Co., Ltd.), kneaded evenly, then extruded, dried at 110°C for 4 hours, and roasted at 550°C for 4 hours to obtain a composite carrier, which contained 70% by mass of HZSM-5 zeolite, 30% by mass of silica.
[0035] (2) Preparation of catalyst
[0036] Get 50 grams of composite carrier, use 50 grams of zinc nitrate containing 4.7 mass %, mixed rare earth chloride (its oxide composition is 31 mass % of lanthanum oxide, 51 mass % of cerium oxide, 14 mass % of praseodymium oxide, 4 mass % of neodymium oxide) The solution of 4.5% by mass was soaked at 25°C for 1 hour, dried at 110°C for 8 hours, calcined at 5...
example 2
[0038] Composite carrier is prepared according to the method of example 1 (1) step, the difference is that the acidic silica sol used is 158g, after extruding, drying and roasting, the obtained HZSM-5 zeolite content is 50% by mass, and the silicon oxide content is 50% by mass Composite carrier b. Get above-mentioned composite carrier, introduce zinc and mixed rare earth according to the method for example 1 (2) step, make catalyst B after steam treatment, its composition and physical property are shown in Table 1.
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