Photocuring adhesive used for adhering optic glass lenses and preparation method thereof

An optical glass, light curing technology, applied in the direction of modified epoxy resin adhesives, etc., can solve the problems of poor yellowing resistance, large curing shrinkage, weak adhesion, etc., to achieve good yellowing resistance, The effect of low curing shrinkage and strong adhesion

Active Publication Date: 2011-08-31
SHENZHEN FISHER NEW MATERIALS CO LTD
View PDF6 Cites 33 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is: to overcome the shortcomings of the existing photocurable adhesives for bonding optical glass lenses, such as large curing shrinkage rate, weak adhesion, poor yellowing resistance and b

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Photocuring adhesive used for adhering optic glass lenses and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Take the following components,

[0027] Main resin: 50g cycloaliphatic epoxy resin UVR6128 (bis((3,4-epoxycyclohexyl)methyl)adipate),

[0028] Auxiliary resin: 40g modified epoxy acrylate resin EBECRYL 3701 (fatty acid modified epoxy acrylate resin),

[0029] Active monomer: 2.5g vinyl ether monomer HBVE (hydroxybutyl vinyl ether), 3g acrylate monomer IBOA (isobornyl acrylate),

[0030] Photoinitiator: 2g photoinitiator Omnicat 550 (iodonium salt), 2g photoinitiator I-184 (1-hydroxy-cyclohexyl phenone),

[0031] Auxiliary agent: 0.5g coupling agent A-174 (γ-methacryloxypropyltrimethoxysilane), stir evenly.

[0032] After conversion, the main resin accounts for 50.0%, the auxiliary resin accounts for 40.0%, the active monomer accounts for 5.5%, the photoinitiator accounts for 4%, and the auxiliary agent accounts for 0.5%.

Embodiment 2

[0034] Take the following components,

[0035] Main resin: 60g cycloaliphatic epoxy resin ERL-4221 (3,4-epoxycyclohexylmethyl, 3,4-epoxycyclohexyl carbonate),

[0036] Auxiliary resin: 25g modified epoxy acrylate resin EBECRYL3639 (polyurethane modified epoxy acrylate resin),

[0037] Active monomer: 5g vinyl ether monomer CHVE (1,4-cyclohexyldimethanol divinyl ether), 5g acrylate monomer HEMA (hydroxyethyl methacrylate),

[0038] Photoinitiator: 3g photoinitiator Omnicat650 (iodonium salt), 1g photoinitiator I-184 (1-hydroxy-cyclohexyl phenone)

[0039] Auxiliary agent: 1.0g coupling agent A-1100 (γ-aminopropyltriethoxysilane), stir evenly.

[0040] After conversion, the main resin accounts for 60.0%, the auxiliary resin accounts for 25.0%, the active monomer accounts for 10.0%, the photoinitiator accounts for 4.0%, and the auxiliary agent accounts for 1.0%.

Embodiment 3

[0042] Take the following components,

[0043] Main resin: 60g cycloaliphatic epoxy resin UVR6105 (3,4-epoxycyclohexylmethyl, 3,4-epoxycyclohexyl carboxylate)

[0044] Auxiliary resin: 20g modified epoxy acrylate resin CNUVE151 (epoxy acrylate resin),

[0045] Active monomer: 10g vinyl ether monomer DVE-3 (triethylene glycol divinyl ether), 5g acrylate monomer HDDA (1,6-hexanediol diacrylate),

[0046] Photoinitiator: 3g photoinitiator I-250 (iodonium salt), 1.5g photoinitiator I-184 (1-hydroxy-cyclohexyl phenone),

[0047] Auxiliary agent: 0.5g coupling agent A-187 (γ-glycidyl etheroxypropyltrimethoxysilane), stir evenly.

[0048] After conversion, the main resin accounts for 60.0%, the auxiliary resin accounts for 20.0%, the active monomer accounts for 15.0%, the photoinitiator accounts for 4.5%, and the auxiliary agent accounts for 0.5%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a photocuring adhesive used for adhering optic glass lenses, which consists of the following components in percentages by weight: 50-80% of main resin, 10-40% of auxiliary resin, 5-20% of active monomer, 4-4.5% of photo initiator and 0.5-1% of auxiliary. The main resin is alicyclic epoxy resin. The auxiliary resin is modified epoxy acrylate resin. The active monomer is oneor a mixture of vinyl ether monomers and acrylate monomers. The photo initiator is a radical photo initiator and a cation photo initiator. The auxiliary is a coupling agent. The photocuring optic adhesive has the characteristics of high curing speed, high refraction rate, high light transmittance, low curing shrinkage rate, small thermal deformation, strong adhesion force, small smell, yellowing resistance and the like.

Description

technical field [0001] The invention relates to an adhesive used for optical glass, in particular to an optical adhesive cured by ultraviolet light or visible light and a preparation method thereof. Background technique [0002] Optical transparent adhesives are used in the optical field, so they must meet some basic requirements, such as: colorless and transparent; the light transmittance in the specified light wave band is greater than 90%; and the refractive index of the adhesive after curing is the same as that of the optical components to be bonded The refractive index is similar; the bonding strength of the adhesive is good in the temperature range of use; the modulus of the adhesive is low, the elongation after curing is large and the curing shrinkage is small, and the change of the surface of the optical element will not be caused; the hygroscopicity is small, and the resistance to cold and heat shock , Vibration resistance, oil resistance, solvent resistance, light ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C09J163/10
Inventor 戚仁宏王胜林刘呈贵肖仁亮
Owner SHENZHEN FISHER NEW MATERIALS CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap