Acrylic pressure-sensitive adhesive sheet, acrylic pressure-sensitive adhesive sheet manufacturing method, and laminated construction
A technology of pressure-sensitive adhesive sheet and pressure-sensitive adhesive layer, applied in the field of lamination structure, can solve problems such as insufficient cohesion, and achieve the effects of high corrosion resistance and high adhesion reliability
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Embodiment 1
[0173] To 100 parts by mass of a mixture containing 86.5 parts by mass of 2-ethylhexyl acrylate, 12 parts by mass of N-vinyl-2-pyrrolidone and 1.5 parts by mass of hydroxyethylacrylamide, blend 0.05 parts by mass of 2,2-dimethoxy Base-1,2-diphenylethane-1-one (trade name "IRGACURE 651", manufactured by Ciba Japan K.K.) and 0.05 parts by mass of 1-hydroxy-cyclohexyl-benzophenone (trade name "IRGACURE 184", manufactured by Ciba Japan K.K.) was used as a photopolymerization initiator, and nitrogen gas was sufficiently introduced. The resulting mixture was exposed to ultraviolet light under a nitrogen atmosphere to allow photopolymerization, thereby obtaining a partially polymerized product (syrup or slurry-type composition) in which the conversion rate was 11%.
[0174] To the aforementioned partially polymerized product, 0.3 parts by mass of a reaction product of trimethylolpropane and toluene diisocyanate (trade name "CORONATE L", manufactured by Nippon Polyurethane Industry Co...
Embodiment 2
[0178] In addition to using 100 parts by mass of a mixture containing 70 parts by mass of 2-ethylhexyl acrylate, 26 parts by mass of N-vinyl-2-pyrrolidone and 4 parts by mass of hydroxyethylacrylamide; and adding 0.01 parts by mass of 1,6- A pressure-sensitive adhesive layer was prepared in the same manner as in Example 1 except that hexanediol diacrylate was used as a crosslinking agent.
[0179] The gel fraction of the pressure-sensitive adhesive layer was 63.2% by mass.
Embodiment 3
[0181] Except using 100 parts by mass of a mixture containing 70 parts by mass of 2-ethylhexyl acrylate, 26 parts by mass of N-vinyl-2-pyrrolidone and 4 parts by mass of methylolacrylamide (N-methylolacrylamide); and A pressure-sensitive adhesive layer was prepared in the same manner as in Example 1 except that 0.03 parts by mass of 1,6-hexanediol diacrylate was added as a crosslinking agent.
[0182] The gel fraction of the pressure-sensitive adhesive layer was 73.1% by mass.
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Abstract
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