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Zinc oxide transparent conductive film and production method thereof

A technology of transparent conductive film and manufacturing method, applied in chemical instruments and methods, circuits, electrical components, etc., can solve the problems of inability to precisely control the quality and morphology of the film, and achieve improved LED external quantum efficiency, excellent conductivity and transparency. Features, the effect of high light transmittance

Active Publication Date: 2014-06-25
FOSHAN EVERCORE OPTOELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] One of the technical problems to be solved by the present invention is to provide a zinc oxide transparent conductive film, which solves the problem that the zinc oxide transparent conductive film cannot accurately control the quality and morphology of the epitaxial film in the prior art

Method used

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  • Zinc oxide transparent conductive film and production method thereof
  • Zinc oxide transparent conductive film and production method thereof
  • Zinc oxide transparent conductive film and production method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The purpose of this specific embodiment is to provide a method for manufacturing ZnO TCL, so as to manufacture a new type of ZnO TCL. The ZnO TCL produced by this method is as figure 1 As shown, it includes a ZnO nucleation layer, a ZnO main body layer and a round crown nano-columnar ZnO layer attached to one side of the GaN-LED epitaxial wafer in sequence. After testing, the ZnO TCL has low resistivity, high visible light transmittance, and the surface morphology of the film can be controlled around the photonic crystal size, and has a high degree of lattice matching with GaN; this method is applied to GaN- In the case of LEDs, the quantum efficiency outside the GaN-LED chip can be significantly improved.

[0032] In order to obtain the above-mentioned ZnO TCL, the preliminary idea of ​​the present invention is:

[0033] Using existing industrial mass-production equipment such as MOCVD (Metal-organic Chemieal Vapor DePosition, metal organic compound chemical vapor de...

Embodiment 2

[0062] The basic steps of this embodiment are the same as those of Embodiment 1, except that the relevant parameters are not the same, and there are some differences in the relevant parameters of the final ZnO film samples. Specifically, when the nucleation layer grows, a ZnO nucleation layer with a thickness of 15nm is generated. layer.

[0063] After testing, the transmittance of 454nm visible light of the generated ZnO TCL sample is as high as 93.1%, and the resistivity is lower than 3.4E-4Ω·cm. The distance between the top of the dome and the layered film is 80nm.

Embodiment 3

[0065] The differences between this embodiment and Embodiment 1 are:

[0066] When the nucleation layer grows, the temperature is controlled at 250 degrees centigrade, the pressure is controlled at 80 torr, and the thickness of the grown ZnO nucleation layer is 22 nm.

[0067] During the growth process of the layered ZnO main layer, when doping metal Ga to grow the N-type ZnO layer, the temperature is 450 degrees Celsius, and the thickness of the generated N-type ZnO layer is 600 nm.

[0068] Then, under other conditions unchanged, the organometallic Al is introduced, and the molar weight of the organic metal Al is controlled to be 5 times higher than that of the metal Ga, and the growth is continued to 200nm.

[0069] After testing, the transmittance of the obtained ZnO TCL sample to 468nm visible light is as high as 92.1%, while the resistivity is lower than 7.4E-4Ω cm. The surface morphology presents a self-assembled circular crown island structure, and the span of the circ...

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Abstract

The invention discloses a zinc oxide transparent conductive film and a production method thereof. The zinc oxide transparent conductive film comprises a ZnO nucleating layer, a ZnO main body layer and a crown nano-cylindrical ZnO layer which are sequentially attached to the surface at one side of a lining material, wherein the crown nano-cylindrical ZnO layer is provided with a plurality of crown nano-cylindrical surfaces; the span of a crown of the crown nano-cylindrical ZnO layer is 10-1000nm; and the distance between the top of the crown to the ZnO main body layer is 10-600nm. The production method comprises the following steps of: pre-treating a growth substrate; pre-depositing; growing the ZnO nucleating layer; growing the ZnO main body layer; and growing the crown nano-cylindrical ZnO layer. ZnOTCL obtained by using the production method of the zinc oxide transparent conductive film can be used for accurately controlling the growth quality and the morphology except for meeting excellent conductive and transparent characteristics and has the surface morphology of the photonic crystal characteristic and higher optical extraction efficiency; and the LED (Light Emitting Diode) external quantum efficiency can be greatly improved, the considerable development of the LED industry is promoted and the realization on the purposes of environment friendliness, energy saving and sustainable development is facilitated.

Description

technical field [0001] The invention relates to the technical field of semiconductors, in particular to a transparent conductive film and a manufacturing method thereof, in particular to a zinc oxide transparent conductive film and a manufacturing method thereof. Background technique [0002] Gallium Nitride Light-Emitting Diode (GaN-LED) is the core device to realize solid-state lighting, and its low external quantum efficiency is a major obstacle to its further development. In order to improve the external quantum efficiency of GaN-LED, people have done a lot of research work over the years, using TCL (Transparent Conductive Layer, transparent conductive layer) is the most effective way to improve the external quantum efficiency known so far. [0003] At present, the TCL of GaN-LED mainly adopts Ni / Au (nickel-gold alloy) or ITO (Indium Tin Oxides, tin-doped indium oxide) material, and the coating method is electron beam evaporation. In order to ensure uniform current diff...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L33/00C30B25/02C30B29/16C30B33/02
Inventor 王钢王孟源童存声雷秀铮江灏
Owner FOSHAN EVERCORE OPTOELECTRONICS TECH