Efficient liquid antifreezing agent for concrete, and preparation method thereof

A concrete and antifreeze technology, which is applied in the field of building materials, can solve the problems of alkali-aggregate reaction, steel bar corrosion, high dosage, etc., achieve high water reduction rate and work performance, reduce water-cement ratio, and simple preparation

Inactive Publication Date: 2012-01-18
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The above-mentioned antifreeze agents can lower the freezing point of water and enable concrete to develop strength at negative temperatures, but the dosage is relatively high, which will have varying degrees of adverse effects on the durability of concrete, such as chloride ions causing corrosion of steel bars and excessive alkali content. High prone to alkali-aggregate reaction, etc.

Method used

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  • Efficient liquid antifreezing agent for concrete, and preparation method thereof
  • Efficient liquid antifreezing agent for concrete, and preparation method thereof
  • Efficient liquid antifreezing agent for concrete, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A preparation method for a liquid antifreeze agent for concrete, comprising the steps of:,

[0028] 1) Refer to the following mass ratio ingredients:

[0029] serial number

name

mass (kg)

1

Superplasticizer

55

2

Formate

5.0

3

Organic alcohol amine

2.2

4

carbonate

45

5

ethylene glycol

55

6

air entraining agent

1.2

7

water

200

[0030] Wherein, the high-efficiency water reducer is Nai series high-efficiency water reducer FDN-5, the formate is calcium formate, the organic alcohol amine is triethanolamine, the carbonate is sodium carbonate, and the air-entraining agent is dodecylbenzene sodium sulfonate.

[0031] 2) Put the high-efficiency water reducer into a container (such as a beaker), add water with a total water content of 30% (60kg), heat to 25°C to 40°C and stir until the high-efficiency water reducer dissolve...

Embodiment 2

[0034] A preparation method for a liquid antifreeze agent for concrete, comprising the steps of:,

[0035] 1) Refer to the following mass ratio ingredients:

[0036] serial number

name

mass (kg)

1

Superplasticizer

60

2

Formate

5.4

3

Organic alcohol amine

2.4

4

carbonate

45

5

ethylene glycol

65

6

air entraining agent

1.2

7

water

180

[0037] Wherein, the high-efficiency water-reducing agent is Nai series high-efficiency water-reducing agent (HSN), the formate is calcium formate, the organic alcohol amine is triethanolamine, the carbonate is sodium carbonate, and the air-entraining agent is dodecylbenzene sodium sulfonate.

[0038]2) Put the high-efficiency water-reducing agent into the container, add water with 35% of the total amount of water, heat to 25°C-40°C and stir until the high-efficiency water-reducing agent is d...

Embodiment 3

[0041] A preparation method for a liquid antifreeze agent for concrete, comprising the steps of:,

[0042] 1) Refer to the following mass ratio ingredients:

[0043] serial number

name

mass (kg)

1

Superplasticizer

65

2

Formate

5.4

3

Organic alcohol amine

2.6

4

carbonate

45

5

ethylene glycol

65

6

air entraining agent

1.2

7

water

165

[0044] Wherein, the high-efficiency water reducer is polycondensed acid high-efficiency water reducer (HXJ-1), the formate is calcium formate, the organic alcohol amine is triethanolamine, the carbonate is sodium carbonate, and the air-entraining agent is twelve Sodium Alkylbenzene Sulfonate.

[0045] 2) Put the high-efficiency water reducer into the container, add water with a total water content of 20% (33kg), heat to 25°C-40°C and stir until the high-efficiency water reducer dissolves t...

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PUM

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Abstract

The present invention relates to an efficient liquid antifreezing agent for concrete, and a preparation method thereof, and belongs to the technical field of building materials. The efficient liquid antifreezing agent for the concrete is characterized in that: the efficient liquid antifreezing agent is prepared from an efficient water reducing agent, a formate, an organic alcohol amine, a carbonate, ethylene glycol, an air entraining agent and water, wherein a ratio of the efficient water reducing agent to the formate to the organic alcohol amine to the carbonate to the ethylene glycol to the air entraining agent to the water is (48-75):(2.0-7.6):(1.2-3.0):(30-57):(65-92):(0.8-1.6):(60-275). The antifreezing agent has characteristics of good freezing resistance, high early strength, chloride-free property, high water reducing rate and high working performance. More importantly that, the addition amount of the antifreezing agent in the cement concrete is small so as to promote the early hydration rate of the cement, such that the early strength of the cement is improved while the high late strength of the cement is ensured so as to improve the mechanical property and the durability of the concrete. In addition, the antifreeze can be used under a negative temperature environment having a temperature more than -18 DEG C.

Description

technical field [0001] The invention relates to a high-efficiency liquid antifreeze agent for concrete and a preparation method thereof, belonging to the technical field of building materials. Background technique [0002] In many areas of our country, the temperature of concrete in winter construction is mostly below 0°C. In some areas in the north, the lowest winter temperature sometimes reaches minus 20-30°C, and in the central region, the winter temperature sometimes reaches about -10°C. If the temperature drops below the freezing point of concrete hydration water, the hydration water will freeze and affect the concrete hydration process, the strength will develop slowly and fail to meet the age requirements, and the ice expansion stress will cause the internal structure of the concrete to be damaged. It will adversely affect the strength and durability of concrete. [0003] In order to prevent the concrete under negative temperature from being damaged by freezing, addi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/12C04B24/24
Inventor 陈友治韩汪洋赵磊陈奇欧阳康
Owner WUHAN UNIV OF TECH
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