Method for manufacturing SnAgCu lead-free solder

A lead-free solder and raw material technology, applied in the direction of welding/cutting media/materials, welding media, manufacturing tools, etc., can solve the problems of rough growth interface of reactants, easy generation of tissue defects, unfavorable weld reliability, etc. Versatility, reducing the chance of false soldering, and the effect of grain refinement

Inactive Publication Date: 2012-01-25
HEFEI UNIV OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In this way, the melt structure in the droplet has a significant impact on the growth of the weld reaction layer. The size of the clusters in the solder droplet by the conventional smelting preparation method is relatively large, especially the adhesion of the Sn-Cu solid clusters to the substrate is beneficial to the intermetallic formation. Compound Cu 6 sn 5 The nucleation grows, and the reactant growth interface appears rough, which further promotes the thickening of the reaction layer; at the same time, the viscosity of the droplet is larger due to the larger cluster size, which is not conducive to the flow and spreading on the rough reactant interface
In conclusion, on the one hand, the spreading and wettability of the solder prepared by the conventional method needs to be further improved; on the other hand, the weld reaction layer is relatively thick, and the interface with the solder is relatively rough, and structural defects are prone to occur, which is unfavorable to the reliability of the weld.

Method used

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  • Method for manufacturing SnAgCu lead-free solder
  • Method for manufacturing SnAgCu lead-free solder
  • Method for manufacturing SnAgCu lead-free solder

Examples

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Effect test

Embodiment 1

[0040] Embodiment 1 and embodiment 2 are comparative experiments of embodiment 3, not the scope of protection of the present invention.

[0041] Example 1:

[0042] The raw material of SnAgCu series ternary alloy lead-free solder in the present embodiment constitutes by mass percentage:

[0043] Ag3.5%, Cu0.7%, Sn95.8%.

[0044] The present embodiment SnAgCu series ternary alloy lead-free solder is prepared according to the following steps:

[0045] Mix the raw materials according to the ratio and heat up to 500°C for 1 hour under nitrogen protection to obtain an alloy melt to ensure that the alloy is melted and mixed evenly, and then poured into an alloy ingot; finally, the alloy ingot is processed into a solder by mechanical processing . The processing form of solder can be rolling, wire drawing or other conventional mechanical processing methods according to actual requirements, so as to obtain solder in the form of foil, sheet, rod, wire, granule or powder. The solder ...

Embodiment 2

[0047] The raw material of SnAgCu series ternary alloy lead-free solder in the present embodiment constitutes by mass percentage:

[0048] Ag3.5%, Cu0.7%, Sn95.8%.

[0049] The present embodiment SnAgCu series ternary alloy lead-free solder is prepared according to the following steps:

[0050] Mix the raw materials according to the ratio and heat up to 500°C for half an hour under nitrogen protection to obtain an alloy melt, then raise the temperature of the alloy melt to 850°C and keep it for 15 minutes; then lower the temperature to 500°C and keep it for 0.5 hours, then cast into an alloy ingot; finally, the alloy ingot is processed into solder by means of mechanical processing. The processing form of solder can be rolling, wire drawing or other conventional mechanical processing methods according to actual requirements, so as to obtain solder in the form of foil, sheet, rod, wire, granule or powder. The solder in this example is in the form of flakes.

Embodiment 3

[0052] The raw material of SnAgCu series ternary alloy lead-free solder in the present embodiment constitutes by mass percentage:

[0053] Ag3.5%, Cu0.7%, Sn95.8%.

[0054] The present embodiment SnAgCu series ternary alloy lead-free solder is prepared according to the following steps:

[0055] Mix the raw materials according to the ratio and heat up to 500°C for half an hour under the protection of nitrogen to obtain an alloy melt, then raise the temperature of the alloy melt to 1050°C for 15 minutes; then lower the temperature to 500°C for 0.5 hours, then cast into an alloy ingot; finally, the alloy ingot is processed into solder by means of mechanical processing. The processing form of solder can be rolling, wire drawing or other conventional mechanical processing methods according to actual requirements, so as to obtain solder in the form of foil, sheet, rod, wire, granule or powder. The solder in this example is in the form of flakes.

[0056] The effect of the present...

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Abstract

The invention discloses a method for manufacturing SnAgCu lead-free solder, which comprises the following steps of: mixing raw materials according to proportions, heating to 500 DEG C under the protection of a covering agent and nitrogen gas or under the vacuum condition, smelting for 0.5-1h to obtain alloy melt; heating the alloy melt to a temperature not lower than a temperature range that the alloy melt generates liquid-state structure transformation, and preserving heat for 15-30min; cooling to 500 DEG C, preserving heat for 0.5h, and then casting and solidifying to obtain a lead-free solder alloy ingot; and finally machining the alloy ingot into lead-free solder by adopting a transmission machining way. According to the lead-free solder prepared by adopting the method disclosed by the invention, solidification tissues are remarkably thinned and evenly distributed; in the welding process, a reaction layer at the joint part is remarkably thinned and the roughness is reduced; the solder is easy to melt, and the expandability of the solder and the wettability of the solder with a copper substrate are remarkably improved; besides, the thermal stability of welding joint tissues is remarkably improved, and therefore the operation reliability of related products in the service process is improved.

Description

1. Technical field [0001] The invention relates to a preparation method of lead-free solder, in particular to a preparation method of SnAgCu ternary alloy lead-free solder. 2. Background technology [0002] Tin-lead (Sn-Pb) metal solder (welding rod, welding wire, solder paste, etc.) has been widely used in various countries due to its superior performance, good process performance and low cost, such as various electronics (computers, monitors, Color TVs, mobile phones, etc.), electrical appliances and instrument products, microelectronic packaging, printed circuit board (PCB) assembly, including plug-in (THT) and surface mount (SMT). However, because e-waste containing harmful substances such as lead has great harm to human beings, and lead poisoning can induce diseases such as leukemia, kidney disease, heart disease, and mental disorders, it has become the consensus of all mankind to ban lead. The EU WEEE and RoHS directives (6 hazardous substances such as Pb banned in el...

Claims

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Application Information

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IPC IPC(8): B23K35/40B23K35/26
Inventor 祖方遒刘永驰李小蕴李先芬席赟黄中月
Owner HEFEI UNIV OF TECH
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