Aqueous UV (ultraviolet) printing ink dispersed by utilizing vermiculate micelle system and preparation method thereof

A worm-like micelle and system technology, applied in the field of water-based UV ink and its preparation, can solve the problems of time-consuming, manpower, material and financial resources, water-based ink adaptability is not as good as oil-based ink, poor adhesion, etc., to achieve smooth surface, High gloss, good adhesion effect

Inactive Publication Date: 2012-03-21
中国印刷科学技术研究所 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the polymer resin binder in the water-based ink cannot provide high enough viscosity, so that the adaptability of the water-based ink to the substrate is not as good as that of the oil-based ink, and the adhesion is poor. To increase the adhesion, a layer of UV primer must be added to the substrate in advance. Oil or surface treatment such as frosting, corona, surface oxidation, etc., consumes a certain amount of time, manpower, material resources and financial resources

Method used

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  • Aqueous UV (ultraviolet) printing ink dispersed by utilizing vermiculate micelle system and preparation method thereof
  • Aqueous UV (ultraviolet) printing ink dispersed by utilizing vermiculate micelle system and preparation method thereof
  • Aqueous UV (ultraviolet) printing ink dispersed by utilizing vermiculate micelle system and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A kind of water-based UV ink, according to weight percentage, comprises following components:

[0037] 28% R-303 and sodium polystyrene sulfonate composite surfactant;

[0038] 5% 2959 and BTC composite UV photoinitiator;

[0039] 15% dimethylquinacridone magenta pigment;

[0040] 5% light reflective functional filler;

[0041] 1.5% Silok 4650 water-based defoamer;

[0042] 0.5% Silok 50 slip agent;

[0043] 40% water;

[0044] 5% methyl acrylate and acrylic monomers.

[0045] Among them, the molar ratio of R-303 and sodium polystyrene sulfonate is 1:2; the number average molecular weight of sodium polystyrene sulfonate is 20,000; the molar ratio of 2959 and BTC is 2:1; the molar ratio of methyl acrylate and acrylic acid The ratio is 1:1.

[0046] The preparation method is as follows: (1) dimethyl quinacridone pigment, light reflective filler, defoamer, slip agent, photoinitiator and monomer that have been ground to a particle size of 5 μm or less are ultrasonica...

Embodiment 2

[0048] A kind of water-based UV ink, according to weight percentage, comprises following components:

[0049] 20% KJH-2 and sodium polystyrene sulfonate composite surfactant;

[0050] 10% 2959 and BTC composite UV photoinitiator;

[0051] 15% nigrosine black pigment;

[0052] 10% light reflective functional filler;

[0053] 3% Silok 4650 water-based defoamer;

[0054] 2% Silok 50 slip agent;

[0055] 30% water;

[0056] 10% methyl acrylate and acrylic monomers.

[0057] Among them, the molar ratio of KJH-2 and sodium polystyrene sulfonate is 3:1; the number average molecular weight of sodium polystyrene sulfonate is 30,000; the molar ratio of 2959 and BTC is 1:1; the molar ratio of methyl acrylate and acrylic acid The ratio is 1:1.

[0058] The preparation method is as follows: (1) The nigrosine pigment, light reflective filler, defoamer, slip agent, photoinitiator and monomer that have been ground to a particle size of 5 μm or less are dispersed in the aqueous solution o...

Embodiment 3

[0060] A kind of water-based UV ink, according to weight percentage, comprises following components:

[0061] 20% KJH-3 and polyacrylic acid composite surfactant;

[0062] 8% 2959 and QTX composite UV photoinitiator;

[0063] 30% anthraquinone yellow pigment;

[0064] 5% light reflective functional filler;

[0065] 1.5% Silok 4830 water-based defoamer;

[0066] 0.5% Silok 50 slip agent;

[0067] 30% water;

[0068] 5% styrene monomer.

[0069] Among them, the molar ratio of KJH-3 and polyacrylic acid is 0.9:1.05; the number average molecular weight of polyacrylic acid is 35000; the molar ratio of 2959 and QTX is 2:1.

[0070] The preparation method is as follows: (1) disperse anthraquinone pigments, light reflective fillers, defoamers, slip agents, photoinitiators and monomers that have been ground to a particle size of 5 μm or less in an aqueous solution of KJH-3 for 1 hour, Remove ununiformly dispersed solid particles by filtration, the ultrasonic frequency is 40kHz, ...

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Abstract

The invention relates to an aqueous UV (ultraviolet) printing ink dispersed by utilizing a vermiculate micelle system and a preparation method thereof. According to the preparation method, a vermiculate micelle phase is formed in an aqueous solution by using a composite surfactant composed of a polymerizable type cationic surfactant and organic acids / organic salts, and various printing ink components (solid pigment, an aqueous ultraviolet light initiator, and various functional additives and a small amount of monomers) are encapsulated in the vermiculate micelle phase; and the aqueous UV printing ink with viscoelasticity is prepared by the steps of ultrasonic dispersion, centrifugal filtration and the like. According to the invention, an organic solvent is prevented from being used, so that the aqueous printing ink is environmentally-friendly; the aqueous printing ink has UV initiating activity, can be rapidly crosslinked and solidified on the surface of a printing stock, and embodiesgood water tolerance and abrasive resistance; and the vermiculate micelle in the system endows the printing ink with changeable fluid properties at different temperatures, and enables the printing ink to have better leveling property at high temperature and higher adhesion at low temperature, thus the aqueous printing ink is suitable for high-speed printing on various printing stocks such as plastic, metal and the like and has excellent gloss and color reproducibility.

Description

technical field [0001] The invention relates to a water-based UV ink dispersed by a worm-like micellar system and a preparation method thereof. The ink has excellent water resistance, abrasion resistance and storage stability, and is suitable for use in various types of printing paper, plastic films, metal foils, etc. High print quality on the substrate. Background technique [0002] At present, the worm-like micelle system composed of surfactant molecules is an important class of viscoelastic fluids, which has important application value in oil fields, drag reduction of hot and cold fluids in communities, thickening of personal care and household cleaning products, etc. . Many surfactants have been developed, which can be used to construct worm-like micellar systems, such as the composite system of cationic surfactants and organic acids or organic salts; the combination of anionic surfactants and organic cationic salts or organic bases Composite system; a composite system...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/02C09D11/10C09D11/03C09D11/101
Inventor 王欢褚庭亮
Owner 中国印刷科学技术研究所
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