Preparation method of isooctanol polyoxypropylene ether sodium sulfosuccinate diester

A technology of isooctyl alcohol polyoxypropylene ether and diester sodium sulfonate, which is applied in the direction of sulfonate preparation, chemical instruments and methods, organic chemistry, etc., can solve problems such as pollution, yield decline, and cost increase, and achieve reduction Effects of side reactions, short reaction time, and reduction in energy and material consumption

Inactive Publication Date: 2012-03-28
ZHEJIANG HECHENG CHEM
View PDF2 Cites 16 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Sodium diisooctyl sulfonate maleate is more and more widely used, and the amount of use is increasing year by year. However, sodium diisooctyl sulfonate maleate is prone to produce a lot of foam during use. In addition, maleic acid The tradition

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of isooctanol polyoxypropylene ether sodium sulfosuccinate diester
  • Preparation method of isooctanol polyoxypropylene ether sodium sulfosuccinate diester

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Solid Superacid S 2 O 8 2- / ZrO 2 Preparation of Catalyst 1

[0022] Pour 1000ml of zirconium oxychloride solution with a concentration of 0.6 mol / L into a 2000ml four-necked glass flask, stir and dropwise add 25% ammonia solution to adjust the pH value to 9, control the temperature below 20°C, precipitate and age for 36h, pump filtered, washed to be free of Cl - Detected, then dried at 105°C for 24 hours, ground to below 100 mesh, and set aside. Use 554 mL of ammonium persulfate solution with a concentration of 2.0 mol / L to impregnate the sample for a certain period of time, filter, dry at 105°C for 12 hours, and roast at 600°C for 6 hours to obtain solid superacid S 2 o 8 2- / ZrO 2 Catalyst, spare.

Embodiment 2

[0024] Solid Superacid S 2 O 8 2- / ZrO 2 Preparation of Catalyst 2

[0025] Pour 1000ml of zirconium oxychloride solution with a concentration of 1.0 mol / L into a 2000ml four-neck glass flask, stir and dropwise add 25% ammonia solution to adjust the pH value to 11, control the temperature below 20°C, precipitate and age for 12 hours, pump filtered, washed to be free of Cl - Detected, then dried at 105°C for 24 hours, ground to below 100 mesh, and set aside. Use 1476mL ammonium persulfate solution with a concentration of 1.25mol / L to impregnate the sample for a certain period of time, filter, dry at 105°C for 12h, and roast at 800°C for 2h to obtain solid superacid S 2 o 8 2- / ZrO 2 Catalyst, spare.

Embodiment 3

[0027] Solid Superacid S 2 O 8 2- / ZrO 2 Preparation of Catalyst 3

[0028] Pour 1000ml of zirconium oxychloride solution with a concentration of 0.2 mol / L into a 2000ml four-neck glass flask, stir and add 25% ammonia solution dropwise to adjust the pH value to 10, control the temperature below 20°C, precipitate and age for 24 hours, pump filtered, washed to be free of Cl - Detected, then dried at 105°C for 24 hours, ground to below 100 mesh, and set aside. Use 738mL ammonium persulfate solution with a concentration of 0.5mol / L to impregnate the sample for a certain period of time, filter, dry at 105°C for 12h, and roast at 400°C for 4h to obtain solid superacid S 2 o 8 2- / ZrO 2 Catalyst, spare.

[0029] The preparation method of isooctyl alcohol polyoxypropylene ether succinic acid diester sodium sulfonate of the present invention, it comprises three main reactions, introduces condensation reaction and esterification emphatically below:

[0030] On...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a preparation method of isooctanol polyoxypropylene ether sodium sulfosuccinate diester. The method comprises the following steps of: adding epoxy propane into isooctanol serving as an initiator under the action of a modified DMC (Di Methyl Carbonate) catalyst for undergoing a condensation reaction to obtain isooctanol polyoxypropylene ether; undergoing an esterification reaction on the isooctanol polyoxypropylene ether and maleic anhydride under the catalytic action of a solid super acid S2O8<2->/ZrO2 to obtain isooctanol polyoxypropylene ether sulfosuccinate diester; and undergoing a sulfonation reaction on the isooctanol polyoxypropylene ether sulfosuccinate diester and a sodium metabisulfite solution under the action of a phase transfer catalyst, and adding a NaOH aqueous solution till the pH of a reactant is 4-7 to obtain the isooctanol polyoxypropylene ether sodium sulfosuccinate diester. The preparation method has the advantages of clean, environmentally-friendly and simple production process, higher permeability and remarkable reduction in foams produced in the using process.

Description

technical field [0001] The invention relates to a preparation method of isooctyl alcohol polyoxypropylene ether succinic acid diester sodium sulfonate. It belongs to the technical field of synthesis of anionic surfactants in organic chemistry. Background technique [0002] Sodium diisooctyl sulfonate maleate (Sodium isooctyl succinate diester sulfonate, commonly known as fast penetrating agent T) is mainly used in petrochemical, pesticide, light industry, medicine, metallurgy, textile, printing and dyeing, papermaking , tanning and other industries, especially in the textile industry to deal with cotton, linen, viscose and blended products, the treated fabric can be directly bleached and dyed without scouring, improving the dyeing defects caused by dead cotton, and the fabric feel after printing and dyeing Softer, fuller and can be used as an emulsifier, dispersant or stabilizer. Sodium diisooctyl sulfonate maleate is more and more widely used, and the amount of use is inc...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C07C309/17C07C303/32B01F17/44C09K23/44
Inventor 曾红舟金一丰颜吉校耿丽
Owner ZHEJIANG HECHENG CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap