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Method for manufacturing chip type organic solid electrolyte electrolytic capacitor

A technology of electrolytic capacitors and organic solids, applied in the direction of solid electrolytic capacitors, electrolytic capacitors, capacitors, etc., can solve the problems of poor voltage withstand capacity of capacitors, deteriorated dielectric film withstand voltage performance, and unable to increase the rated working voltage of capacitors, etc., to achieve good control , Improve the effect of pressure resistance

Active Publication Date: 2012-03-28
SICHUAN ANKETE ELECTRONICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the introduction of oxidants in the method of chemical in-situ deposition, oxidant ions will accumulate in the defects of the dielectric film, deteriorating the withstand voltage performance of the dielectric film, resulting in poor withstand voltage of the obtained capacitor, and the rated working voltage of the capacitor cannot be increased.

Method used

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  • Method for manufacturing chip type organic solid electrolyte electrolytic capacitor
  • Method for manufacturing chip type organic solid electrolyte electrolytic capacitor
  • Method for manufacturing chip type organic solid electrolyte electrolytic capacitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Press the tantalum powder into a tantalum block according to a certain pressing density, and sinter the obtained tantalum block in a vacuum sintering furnace to obtain a tantalum block core with a certain strength. At this time, the state of the tantalum block core is a sponge-like sintered porous state; then The sintered tantalum block is formed into Ta in acidic aqueous solution 2 o 5 Dielectric oxide film, the oxide film is used as the dielectric layer of the organic chip electrolytic capacitor; the tantalum block core formed with the dielectric oxide film is alternately dipped in the polycation solution and the polyanion solution for several times to obtain a certain thickness of conductive polymer The composite polyelectrolyte is used as the cathode of the chip electrolytic capacitor; finally, the capacitor core coated with the cathode is impregnated with graphite and silver paste respectively to obtain a chip organic solid electrolyte tantalum electrolytic capacit...

Embodiment 2

[0056] Such as figure 1 As shown, the manufacturing process of the capacitor is similar to Embodiment 1, and the formation voltage of ③ in the embodiment is changed to 38V.

[0057] The basic parameters of the obtained chip type organic solid electrolyte tantalum electrolytic capacitor are: rated voltage: 10V; capacity: 337μF; equivalent series resistance: 40mΩ; leakage current (measured at 12V): 26μA.

Embodiment 3

[0059] Such as figure 1 As shown, the manufacturing process of the capacitor is similar to Embodiment 1, the number of ⑤ cycles in the embodiment is 7 times, and the number of ⑥ cycles in the embodiment is 6 times.

[0060] The basic parameters of the obtained chip organic solid electrolyte tantalum electrolytic capacitor are: rated voltage: 10V; capacity: 468μF; equivalent series resistance: 55mΩ; leakage current (measured at 12V): 12μA. Due to the adjustment of the thickness of the cathode film, the equivalent series resistance of the capacitor becomes larger.

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PUM

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Abstract

The invention discloses a method for manufacturing a chip type organic solid electrolyte electrolytic capacitor. The method comprises the steps of preparing an anode body; preparing a dielectric oxidation film; and preparing a polymer cathode structure. The method is characterized in that the cathode of the chip type organic solid electrolyte electrolytic capacitor is obtained by employing an electrostatic self-assembling method; and by alternately assembling polyelectrolyte with reverse charges on the surface of the dielectric oxidation film in a solution, an electroconductive polymer composite polyelectrolyte is further stably structured as a cathode film of the chip type organic solid electrolyte electrolytic capacitor. By employing the manufacturing method provided by the invention, the obtained chip type organic solid electrolyte electrolytic capacitor has the characteristics of low equivalent series resistance and favorable voltage withstand property. The method can be used for manufacturing other capacitors or electronic elements.

Description

technical field [0001] The invention relates to the field of electronic materials and electronic components, in particular to a method for preparing a conductive polymer composite polyelectrolyte as a chip capacitor cathode. Background technique [0002] With the high-performance requirements of electronic products, it is urgent to improve the performance of chip electrolytic capacitors, especially the high-frequency characteristics of products, that is, the ESR value of products. Among them, the conductivity of the solid electrolyte has a great influence on the internal resistance, leakage current and high frequency characteristics. Organic polymers represented by conductive polymers are used as solid electrolytes (with a conductivity of 1-500s / cm) than traditional chip-type solid tantalum electrolytic capacitor cathode materials MnO 2 (Conductivity 0.1s / cm) has lower resistance and can exhibit excellent high-frequency characteristics. Therefore, in recent years, people h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/15H01G9/042
Inventor 刘江萍王锦梅
Owner SICHUAN ANKETE ELECTRONICS TECH
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