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Filter medium for removing dioxin from water and preparation method for filter medium

A filter medium and dioxin technology, applied in the field of water treatment, can solve the problems of difficult biodegradation, complex process, difficult natural degradation and elimination of dioxin

Inactive Publication Date: 2013-06-26
QIDI ELECTRIC GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Dioxins have high stability in the environment and are difficult to biodegrade. Therefore, it is difficult to naturally degrade and eliminate dioxins in the environment
[0005] Conventional methods for removing dioxins in water include thermal decomposition, chemical decomposition, ozonolysis, photolysis, biological decomposition, catalytic oxidation, critical water decomposition, and reverse osmosis. It is difficult to remove dioxins from water; in addition, the wastewater generated by reverse osmosis will cause new problems

Method used

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  • Filter medium for removing dioxin from water and preparation method for filter medium

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preparation example Construction

[0021] The invention discloses a preparation method of a filter medium for removing dioxins in water, comprising the following steps:

[0022] Under the protection of an inert gas, the mixture is molded in a mold press, then sintered at 160-220° C. for 50-80 minutes, cooled and demoulded to obtain a filter medium, and the mixture includes 300-500 parts by weight of activated carbon, 3 ~10 parts by weight of aluminum powder, 50~70 parts by weight of oleic acid modified titanium dioxide nanomaterials, 80~150 parts by weight of modified natural calcium carbonate, the modified natural calcium carbonate is natural calcium carbonate, carbon dioxide reaction product with oxalic acid.

[0023] The activated carbon used in the present invention is generally prepared as follows: charcoal prepared from plants such as peat, charcoal, wood, coconut shells and petroleum is activated by high-temperature pyrolysis in steam containing oxidizing gas, and then cleaned and dried by inorganic pick...

Embodiment 1

[0038] At 55°C, react limestone with carbon dioxide and oxalic acid to obtain modified limestone with a specific surface area of ​​50m 2 / g;

[0039] Under the protection of argon, weigh 400g with a specific surface area of ​​1200m 2 / g of medical wood activated carbon, 3g of aluminum powder with a particle size of 200 meshes, 50g of oleic acid-modified titanium dioxide nanomaterials and 120g of modified limestone particles were placed in a mixer and stirred for 120 minutes, and the removed part was loaded into a tubular mold and pressed , sintered at 200° C. for 60 minutes, and demolded after cooling to obtain a filter element.

Embodiment 2

[0041] At 55°C, react limestone with carbon dioxide and oxalic acid to obtain modified limestone with a specific surface area of ​​50m 2 / g;

[0042] Under the protection of argon, weigh 300g with a specific surface area of ​​1200m 2 / g of medical wood activated carbon, 3g of aluminum powder with a particle size of 200 meshes, 50g of oleic acid-modified titanium dioxide nanomaterials and 120g of modified limestone particles were placed in a mixer and stirred for 120 minutes, and the removed part was loaded into a tubular mold and pressed , sintered at 200° C. for 60 minutes, and demolded after cooling to obtain a filter element.

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Abstract

The invention discloses a preparation method for a filter medium for removing dioxin from water, which comprises the following steps of: putting a mixture into a mould pressing device for mould pressing, sintering at the temperature of between 160 and 220 DEG C for 50 to 80 minutes, cooling, and demoulding to obtain the filter medium, wherein the mixture comprises the following components in partby weight: 300 to 500 parts of activated carbon, 3 to 10 parts of aluminum powder, 50 to 70 parts of oleic acid modified titanium dioxide nanometer material and 80 to 150 parts of modified natural calcium carbonate; and the modified natural calcium carbonate is a reaction product of natural calcium carbonate, carbon dioxide and oxalic acid. The adopted activated carbon, titanium dioxide nanometermaterial and modified natural calcium carbonate have a high adsorption effect on the dioxin, and the aluminum powder can react with the dioxin to generate harmless substances such as water, sodium chloride and the like; and a filter element prepared from the filter medium can effectively remove the dioxin from the water to be treated under the synergic addition action of the raw materials.

Description

technical field [0001] The invention relates to the technical field of water treatment, in particular to a filter medium for removing dioxins in water, a preparation method thereof and a filter element made of the filter medium. Background technique [0002] Polychlorinated dibenzodioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are collectively referred to as dioxins, which are polychlorinated dibenzodioxins connected by two oxygen atoms and two benzene rings substituted by chlorine atoms English (PCDDs); two benzene rings substituted by chlorine atoms linked by an oxygen atom are polychlorinated dibenzofurans (PCDFs). Since 1 to 4 chlorine atoms can be substituted on each benzene ring, dioxins have many isomers, among which PCDDs have 75 isomers and PCDFs have 135 isomers. [0003] Dioxins are widely distributed in the earth's environment. For example, dioxins have been detected in the downstream rivers of some paper mills in the United States, Germany, the Nethe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/30B01J20/28B01D39/14C02F1/28C02F1/58C02F101/36
Inventor 周奇迪栾云堂
Owner QIDI ELECTRIC GROUP