Method for preparing concrete superplasticizer by utilizing synthesized aspirin waste liquor
A technology of high-efficiency water-reducing agent and aspirin, which is applied in the field of preparing high-efficiency water-reducing agent for concrete, can solve environmental pollution and other problems, and achieve the effect of solving environmental pollution problems, high water-reducing rate, and not easy to bleed
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Example Embodiment
[0043] Example 1
[0044] Add 133g (1.3mol) of chemically pure acetic anhydride into a 500ml four-necked flask equipped with a stirrer, thermometer and reflux condenser, add 0.5ml of concentrated sulfuric acid, heat on a water bath at 80℃, add chemically pure water in batches with stirring 138 g (1.0 mol) of salicylic acid, maintain the reaction temperature at 80-85°C, and continue to stir and react for 60 minutes after the addition is complete. Cool the reaction solution to 40°C, add 5.4g of distilled water to decompose the excess acetic anhydride, further cool to 10°C to crystallize, filter and separate the aspirin crystals, wash with a small amount of water to obtain 153g of aspirin product (after drying), the synthesis yield is 85%, The reaction mother liquor is about 124g. Using a rotary thin film evaporator to distill the reaction mother liquor under a vacuum of -0.8Mpa, recover about 86.4 g of acetic acid and about 30 g of phenol residues.
Example Embodiment
[0045] Example 2
[0046] In a four-necked flask equipped with a thermometer, stirrer, dropping funnel and reflux condenser, add 30 g of recovered phenol residues, add 100 g of deionized water, and adjust the pH of the solution to 10-11 with 30% sodium hydroxide to make most of the residues Dissolve and filter to remove insoluble residues to obtain a sodium salt solution of phenolic residues. Add 15.0g of p-aminobenzenesulfonic acid to the solution, stir until it is completely dissolved, adjust the pH to 8.0-8.5 with 30% sodium hydroxide solution, heat to 90-95°C and start to add 30.4g of 37% formaldehyde solution dropwise. After the addition is completed, the condensation reaction is carried out at reflux temperature for 6 hours, and the pH is adjusted to 10-11 with 30% sodium hydroxide solution, and the reflux condensation is continued for 1 hour. Then 1.0 g of urea is added to completely convert the residual formaldehyde, concentrated in vacuo, and cooled to obtain 40% sulfam...
Example Embodiment
[0048] Example 3
[0049] In a four-necked flask equipped with a thermometer, stirrer, dropping funnel and reflux condenser, add 15g of recovered phenol residues, add 100g of deionized water, and adjust the pH of the solution to 10-11 with 30% sodium hydroxide to make most of the residues Dissolve and filter to remove insoluble residues to obtain a sodium salt solution of phenolic residues. Add 10g of phenol to the solution, add 15g (0.15mol) of p-aminobenzenesulfonic acid, stir until it is completely dissolved, adjust the pH to 8.0-8.5 with 30% sodium hydroxide solution, heat to 90-95℃ and start to add 37 % Formaldehyde aqueous solution 30.4g, after dripping, carry out condensation reaction at reflux temperature for 6 hours, then adjust pH 10-11 with 30% sodium hydroxide solution, continue reflux condensation for 1 hour, then add 1.0g urea to completely convert residual formaldehyde , Concentrate in vacuum and cool to obtain a 40% amino aromatic sulfonate superplasticizer liqui...
PUM
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap