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Method for improving recovery ratio of oil field by use of blasting type pre-crosslinking gel particles

A gel particle, recovery factor technology, applied in chemical instruments and methods, production fluids, earthwork drilling, etc., can solve the problems of large loss of effective viscosity, difficult on-site implementation, and inability to achieve results by water flooding. The effect of shear thinning and enhanced oil recovery

Active Publication Date: 2012-07-18
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, although tertiary oil recovery measures such as polymer flooding have achieved better results, there are still problems such as high cost of oil displacement and difficulty in field implementation; ” in the reservoirs, there are still serious problems of channeling and accumulation in some wells, which affects the effect of polymer injection, and due to the limitations of the polymer itself, the effective viscosity loss in high-temperature and high-salinity formations is very large, often Can't achieve the expected purpose
ASP flooding technology has gradually been widely used in Daqing and other old oilfields. The use of surfactants to reduce interfacial tension greatly reduces capillary force, and oil and water achieve miscible flow, thus starting the low permeability reservoir. Residual oil, but ASP flooding technology and polymer flooding have similar problems: shear thinning, affected by reservoir conditions, and both polymer flooding and ASP flooding will pollute oil-bearing low-permeability layers, making subsequent water flooding unable to achieve best results
Flexible particles can form dynamic plugging in the deep part of the reservoir, but for fractures and ultra-high permeability layers caused by high-intensity water erosion near the well, high-strength plugging agents must be used for anti-channeling operations, otherwise the flexible diverting agent can improve recovery The effect of the rate cannot be brought into full play
[0007] To sum up, so far, in the water plugging and profile control technology of oil production, the profile control and the adjustment of the oil-water mobility ratio cannot be carried out simultaneously, and no prior art reports have solved this problem.

Method used

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  • Method for improving recovery ratio of oil field by use of blasting type pre-crosslinking gel particles
  • Method for improving recovery ratio of oil field by use of blasting type pre-crosslinking gel particles
  • Method for improving recovery ratio of oil field by use of blasting type pre-crosslinking gel particles

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073] formula

[0074] Acrylamide 24 grams

[0075] Acrylic 6 grams

[0076] Polyethylene glycol dimethacrylate (polyethylene glycol 200dimethacrylate) 0.15 g

[0077] NaCO 3 1.5 grams

[0078] Tetramethylethylenediamine (TMEDA) 80mg

[0079] Urea 750mg

[0080] Ammonia 150mg

[0081] Sodium Hydroxide 15mg

[0082] Potassium persulfate (K 2 S 2 o 8 )15mg

[0083] Solvent water 110g

[0084] Total: 142.66g

[0085] The mass percent concentration of the monomer (AA+AM) is 30g / 142.66=21%. The ratio of unstable crosslinking agent to complex monomer is 1:200.

[0086] Polymerization process

[0087] Add acrylamide, acrylic acid and polyethylene glycol dimethacrylate into 110 g of water to fully dissolve. Add NaCO after dissolving 3 Neutralize the solution. Then add TMEDA, urea, ammonia and sodium hydroxide. The solution was purged with nitrogen gas for 30 min, and then K was added to the solution 2 S 2 o 8 , The obtained solution was purged with nitrogen ag...

Embodiment 2

[0095] formula

[0096] Acrylamide 13.5g

[0097] Acrylic acid 1.5g

[0098] Polyethylene glycol dimethacrylate (polyethylene glycol 200dimethacrylate): 0.0375 grams

[0099] Tetramethylethylenediamine (TMEDA) 80mg

[0100] NaCO 3 1.5 grams

[0101] Urea 750mg

[0102] Ammonia 150mg

[0103] Sodium Hydroxide 15mg

[0104] K 2 S 2 o 8 15mg

[0105] Solvent water 110g

[0106] Total: 127.4675g

[0107] The mass percent concentration of the monomer (AA+AM) is 15g / 127.4675=11.76%

[0108] The ratio of unstable crosslinking agent to composite monomer is 1:400

[0109] Polymerization process

[0110] Add acrylamide, acrylic acid and polyethylene glycol dimethacrylate to fully dissolve in water. Add NaCO after dissolving 3 Neutralize the solution. Then add TMEDA, urea, ammonia and sodium hydroxide. The solution was purged with nitrogen gas for 30 min, and then K was added to the solution 2 S 2 o 8 , The obtained solution was purged with nitrogen again...

Embodiment 3

[0116] formula

[0117] Acrylamide 18g

[0118] Acrylic 6 grams

[0119] AMPS 6 grams

[0120] Polyethylene glycol 200 dimethacrylate: 0.03 g

[0121] NaCO 3 1.5 grams

[0122] Tetramethylethylenediamine (TMEDA) 80mg

[0123] Urea 750mg

[0124] Ammonia 150mg

[0125] Sodium Hydroxide 15mg

[0126] K 2 S 2 o 8 15mg

[0127] Solvent water 110g

[0128] Total: 142.54g

[0129] The mass percent concentration of the monomer (AA+AM+AMPS) is 30 / 136.54=22.0%

[0130] The ratio of unstable crosslinking agent to complex monomer is 1:1000

[0131] Polymerization process

[0132] With embodiment 1.

[0133] Hydrolysis test

[0134] The hydrolysis experimental procedure is the same as in Example 1.

[0135] At 80°C, it takes 6 days for the pre-crosslinked gel particles to be hydrolyzed into a polymer solution, and the viscosity of the polymer solution obtained after hydrolysis is 100cp; at 60°C, it takes about 35 days for complete hydrolysis, and the viscosity o...

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Abstract

The invention provides a method for improving the recovery ratio of an oil field by use of blasting type pre-crosslinking gel particles, and particularly relates to a method for improving the recovery ratio of an old oil field with high water cut. The method adopts a kind of pre-crosslinking gel particles; the pre-crosslinking gel particles absorb water to expand and form a solution after staying for a certain time at the formation temperature and pH condition; and the method for improving the recovery ratio of an old oil field with high water cut comprises the following steps of: mixing the pre-crosslinking gel particles with water so that the pre-crosslinking gel particles absorb water to expand; injecting the pre-crosslinking gel particles underground so that the pre-crosslinking gel particles firstly block big pore channels and ultrahigh-permeability layers near the well in an oil pool, wherein after the pre-crosslinking gel particles experience the action of the oil pool temperature for a certain time, the gel particles automatically blast to form a polymer viscose solution which enters the deep of the oil pool to realize control on oil-water fluidity; and performing oil extraction. The method provided by the invention is suitable for improving the petroleum recovery ratio of the oil pool at the stage of high water cut.

Description

technical field [0001] The present invention relates to a method for increasing the recovery rate of an oilfield, especially an old oilfield with a high water content, in oil exploitation, and in particular to a method for improving the recovery rate of an oilfield by using a blasting pre-crosslinked gel particle with dual functions of profile control and polymer flooding method. Background technique [0002] With the continuous development of the oil field, the heterogeneity of the reservoir is becoming more and more serious. A large amount of injected water scours, the clay and cement in the oil layer expand and dissolve, the migration of particles, and the sand production become heavier, which further deteriorates the geological heterogeneity. During the development process, the following problems often appear, such as: prominent plane contradictions, plane injection water rushes along the high permeability zone to form waterways; prominent interlayer contradictions, unev...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E21B43/22E21B33/13C09K8/588C09K8/44
Inventor 贾旭唐孝芬王家禄刘玉章白宝君唐廷基杨立民
Owner PETROCHINA CO LTD
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