Method for improving recovery ratio of oil field by use of blasting type pre-crosslinking gel particles
A gel particle, recovery factor technology, applied in chemical instruments and methods, production fluids, earthwork drilling, etc., can solve the problems of large loss of effective viscosity, difficult on-site implementation, and inability to achieve results by water flooding. The effect of shear thinning and enhanced oil recovery
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Embodiment 1
[0073] formula
[0074] Acrylamide 24 grams
[0075] Acrylic 6 grams
[0076] Polyethylene glycol dimethacrylate (polyethylene glycol 200dimethacrylate) 0.15 g
[0077] NaCO 3 1.5 grams
[0078] Tetramethylethylenediamine (TMEDA) 80mg
[0079] Urea 750mg
[0080] Ammonia 150mg
[0082] Potassium persulfate (K 2 S 2 o 8 )15mg
[0083] Solvent water 110g
[0084] Total: 142.66g
[0085] The mass percent concentration of the monomer (AA+AM) is 30g / 142.66=21%. The ratio of unstable crosslinking agent to complex monomer is 1:200.
[0086] Polymerization process
[0087] Add acrylamide, acrylic acid and polyethylene glycol dimethacrylate into 110 g of water to fully dissolve. Add NaCO after dissolving 3 Neutralize the solution. Then add TMEDA, urea, ammonia and sodium hydroxide. The solution was purged with nitrogen gas for 30 min, and then K was added to the solution 2 S 2 o 8 , The obtained solution was purged with nitrogen ag...
Embodiment 2
[0095] formula
[0096] Acrylamide 13.5g
[0097] Acrylic acid 1.5g
[0098] Polyethylene glycol dimethacrylate (polyethylene glycol 200dimethacrylate): 0.0375 grams
[0099] Tetramethylethylenediamine (TMEDA) 80mg
[0100] NaCO 3 1.5 grams
[0101] Urea 750mg
[0102] Ammonia 150mg
[0104] K 2 S 2 o 8 15mg
[0105] Solvent water 110g
[0106] Total: 127.4675g
[0107] The mass percent concentration of the monomer (AA+AM) is 15g / 127.4675=11.76%
[0108] The ratio of unstable crosslinking agent to composite monomer is 1:400
[0109] Polymerization process
[0110] Add acrylamide, acrylic acid and polyethylene glycol dimethacrylate to fully dissolve in water. Add NaCO after dissolving 3 Neutralize the solution. Then add TMEDA, urea, ammonia and sodium hydroxide. The solution was purged with nitrogen gas for 30 min, and then K was added to the solution 2 S 2 o 8 , The obtained solution was purged with nitrogen again...
Embodiment 3
[0116] formula
[0117] Acrylamide 18g
[0118] Acrylic 6 grams
[0119] AMPS 6 grams
[0120] Polyethylene glycol 200 dimethacrylate: 0.03 g
[0121] NaCO 3 1.5 grams
[0122] Tetramethylethylenediamine (TMEDA) 80mg
[0123] Urea 750mg
[0124] Ammonia 150mg
[0126] K 2 S 2 o 8 15mg
[0127] Solvent water 110g
[0128] Total: 142.54g
[0129] The mass percent concentration of the monomer (AA+AM+AMPS) is 30 / 136.54=22.0%
[0130] The ratio of unstable crosslinking agent to complex monomer is 1:1000
[0131] Polymerization process
[0132] With embodiment 1.
[0133] Hydrolysis test
[0134] The hydrolysis experimental procedure is the same as in Example 1.
[0135] At 80°C, it takes 6 days for the pre-crosslinked gel particles to be hydrolyzed into a polymer solution, and the viscosity of the polymer solution obtained after hydrolysis is 100cp; at 60°C, it takes about 35 days for complete hydrolysis, and the viscosity o...
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