Polyimide/polyacrylonitrile blended fiber and preparation method thereof
A technology of blending fiber and polyacrylonitrile, which is applied in the direction of wet spinning, conjugated synthetic polymer rayon, heat treatment of rayon, etc., can solve the problems not involved in the blending of polyimide fiber materials, and achieve High heat resistance, expanded application field, and improved fracture strength
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[0038] Example 1:
[0039] Synthesis and blending of spinning solution: in a three-necked bottle, put. 4.4888g p-phenylenediamine (p-PDA) was dissolved in 61mL dimethyl sulfoxide (DMSO), and 12.2740g 3,3',4,4'-biphthalic dianhydride (BPDA) was added in batches, and the cumulative The feeding time is 0.5h, and stirring is continued for 4-5h at 20-25℃, until the apparent viscosity of the PAA solution increases and remains stable; 5.5g PAN is dissolved in 20mL DMSO, and N at 20-25℃ 2 protection, continue stirring for 2-3h until the powder is completely dissolved; N 2 Under the protection conditions, take 2 mL of PAN solution and add it to the PAA system, the mass fraction of PAN in the PAA / PAN blending component (excluding the solvent) is 3%, while mechanical stirring, the temperature of the blending process is controlled within the range of 40-60 ° C , the blending and stirring time is 30-60min, until the mixing is uniform, so as to obtain the spinning solution blending precur...
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[0042] Example 2:
[0043] Synthesis and blending of spinning solution: in a three-necked flask, dissolve 11.2221gp-PDA in 100mL DMSO, add 30.8376g BPDA in batches, the cumulative feeding time is 1h, and finally add 52mL DMSO, under the condition of 20-25℃ Continue to stir for 5-6h until the apparent viscosity of the PAA solution increases and remains stable; dissolve 5.5g PAN in 20mL DMSO, under the condition of 20-25℃, N 2 protection, continue stirring for 2-3h until the powder is completely dissolved; N 2 The PAN solution was added to the PAA system under protective conditions, and the mass fraction of the PAA / PAN blending components (excluding the solvent) occupied by PAN was 12%. The mixing time is 30-60min, until the mixing is uniform, so as to obtain the spinning solution blending precursor II;
[0044] Preparation of polyamic acid / polyacrylonitrile spun fiber blend: the spinning solution blend precursor II is subjected to defoaming treatment, and the spun fiber is pr...
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[0046] Example 3:
[0047] Synthesis and blending of spinning solution: in a three-necked bottle, dissolve 5.6110g p-PDA in 50mL DMSO, add 15.4187g BPDA in batches, the cumulative feeding time is 30min, and finally add 26mL DMSO at 20-25°C Continue stirring for 4-5h under the condition of PAA solution, until the apparent viscosity of the PAA solution increases and remains stable; 5.5g PAN is dissolved in 20mL DMSO, under the condition of 20-25℃, N 2 protection, continue stirring for 2-3h until the powder is completely dissolved; N 2 The PAN solution was added to the PAA system under protective conditions, and the mass fraction of the PAA / PAN blending components (excluding the solvent) occupied by PAN was 21%. The mixing time is 30-60min, until the mixing is uniform, so as to obtain the spinning solution blending precursor III;
[0048] Polyamic acid / polyacrylonitrile primary blend fiber preparation: the spinning solution blend precursor III is subjected to defoaming treatmen...
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