Self-distribution seepage-regulation water-controlling acidifying technology

A water acidification and seepage technology, which is applied in the fields of production fluids, chemical instruments and methods, wellbore/well components, etc., can solve the problems such as the large influence of acid distribution on water saturation, complex construction process, and difficulty in uniform acid distribution, and achieve The effect of reducing comprehensive water content, increasing crude oil production and reducing production costs

Inactive Publication Date: 2012-10-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently used foam acid plugging removal has played a role in the acidizing process, but at the same time there are the following shortcomings or deficiencies: ①Because the conditions of most production wells are different, there are also differences in permeability between layers, and it is difficult to distribute acid uniformly; ② The water saturation of different layers has a great influence on the cloth acid; ③The construction process is complex, requiring the use of nitrogen-making vehicles, foam liquid, etc., the construction cost is high, and the construction time is too long; ④There is an increase in water output after acidification

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Preparation of self-distributed percolation regulating polymer: a, 5 parts of dimethyl diallyl ammonium chloride monomer monomer, 2 parts of acrylate monomer monomer, 1 part of acrylamide monomer monomer, deionized water 92 parts were added to the reaction kettle in turn, and stirred evenly; b, heated to a constant temperature of 95°C; c, stirred with nitrogen gas for 30 minutes, to remove the oxygen in the solution; d, added a solid initiator with a mass percentage content of 0.2%, and triggered it to proceed under normal pressure Polymerization reaction was carried out for 7 hours to obtain the target product with a molecular weight of 3.8 million. The solid initiator is a mixture of sodium bisulfite and ammonium persulfate with a mass ratio of 1:2.

[0023] The self-distributed seepage regulation and water control acidification process comprises the following steps: 1. preparing a seepage regulation acidification pre-liquid, 2. preparing a cleaning agent and 3. carry...

Embodiment 2

[0025] Preparation of self-distributed percolation regulating polymer: a, 10 parts of dimethyl diallyl ammonium chloride monomer monomer, 6 parts of acrylate monomer monomer, 4 parts of acrylamide monomer monomer, deionized water 80 parts were added to the reaction kettle in turn, and stirred evenly; b, heated to a constant temperature of 95°C; c, stirred with nitrogen gas for 30 minutes, to remove the oxygen in the solution; d, added a solid initiator with a mass percentage content of 0.4%, and triggered it to proceed under normal pressure Polymerization reaction was carried out for 8 hours to obtain the target product with a molecular weight of 4 million. The solid initiator is a mixture of sodium bisulfite and ammonium persulfate with a mass ratio of 1:2.

[0026] The self-distributed seepage regulation and water control acidification process comprises the following steps: 1. preparing a seepage regulation acidification pre-liquid, 2. preparing a cleaning agent and 3. carry...

Embodiment 3

[0028] Preparation of self-distributed percolation regulating polymer: a, 15 parts of dimethyl diallyl ammonium chloride monomer monomer, 8 parts of acrylate monomer monomer, 8 parts of acrylamide monomer monomer, deionized water 69 parts were added to the reaction kettle in turn, and stirred evenly; b, heated to a constant temperature of 95°C; c, stirred with nitrogen for 30 minutes, and removed oxygen in the solution; d, added mass percentage

[0029] The solid initiator with a content of 0.8% was initiated to carry out polymerization reaction under normal pressure, and reacted for 9 hours to obtain the target product with a molecular weight of 4.3 million. The solid initiator is sodium bisulfite and ammonium persulfate with a mass ratio of 1:3.

[0030] The self-distributed seepage regulation and water control acidification process comprises the following steps: 1. preparing a seepage regulation acidification pre-liquid, 2. preparing a cleaning agent and 3. carrying out wat...

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Abstract

The invention comprises the preparation of a self-distribution seepage-regulation polymer and a self-distribution seepage-regulation water-controlling acidifying technology. The preparation of the regulation polymer comprises the steps of: adding 5-15 parts by mass of dimethyl diallyl ammonium chloride monomer, 2-8 parts by mass of acrylate monomer, 1-8 parts by mass of crylamide monomer, and the balance deionized water into a reaction vessel in turn; stirring the mixture; keeping the mixture at a constant temperature; introducing nitrogen to remove oxygen; adding a solid initiator which accounts for 0.2-0.8% by weight of the total mass; and allowing the obtained mixture to react for 7-9 hours under normal pressure. The self-distribution seepage-regulation water-controlling acidifying technology comprises the steps of preparation of a pad fluid, preparation of a cleaning agent, and performance of water-controlling acidifying construction. The preparation of the pad fluid comprises the steps of adding 0.2%-5% by weight of the self-distribution seepage-regulation polymer, 3%-15% by weight of hydrochloric acid or mud acid, and 0.5%-2% by weight of a corrosion inhibitor to clear water; and stirring the mixture uniformly under normal temperature and pressure. The preparation of the cleaning agent comprises the step of adding 2%-3% by weight of KCl brine to 20m3 of 1% by weight of a nonionic surfactant. The performance of water-controlling acidifying construction comprises the steps of washing a well in forward and reverse directions by running a tubing string; washing an oil reservoir wherein the pad fluid is injected under the pressure of less than70% of an oil reservoir fracture pressure; injecting a routine acidifying liquid and closing the well.

Description

technical field [0001] The invention relates to a method for water-controlled acidification of water-bearing oil wells in oilfield development, in particular to a self-distributed seepage regulation water-control acidification process. Background technique [0002] The key to the success of acid liquid temporary plugging in acidizing process in oilfield development is uniform acid distribution, especially for horizontal wells. The currently used foam acid plugging removal has played a role in the acidizing process, but at the same time there are the following shortcomings or deficiencies: ①Because the conditions of most production wells are different, there are also differences in permeability between layers, and it is difficult to distribute acid uniformly; ② The water saturation of different layers has a great influence on the cloth acid; ③The construction process is complex, requiring the use of nitrogen-making vehicles, foam liquid, etc., the construction cost is high, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/524E21B43/27
Inventor 吴建平宋金波王登庆梅明霞孙秀钊郑铎姜静许霞武明鸣杨军
Owner CHINA PETROLEUM & CHEM CORP
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