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Nanometer drag reducer for sandstone surface pretreatment and preparation method of nanometer drag reducer

A technology for surface pretreatment and drag reducing agent, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of insufficient hydrophobicity, reducing water injection pressure, restrictions, etc., to facilitate industrial production, reduce construction costs, The effect of simple and easy preparation process

Inactive Publication Date: 2012-12-26
SHAANXI RES DESIGN INST OF PETROLEUM CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Only two cases of patents related to nano-drag reducing and injection-increasing agents have been found. Patent 201010138382.6 involves a nano-polysilicon particle and its preparation method and application. The nano-polysilicon particle has a small particle size, uniform distribution, and good hydrophobicity. It has good dispersibility in organic medium, and it has a good application effect on water injection wells in low-permeability oilfields or ultra-low-permeability oilfields as a drag-reducing and injection-increasing agent; the disadvantage is that diesel oil is required to carry it into the well, and the cost is high, and there are transportation, Safety issues in storage and use, etc.
Patent 200910200548.X relates to a water-based oilfield injection booster based on nanomaterials and its preparation method. After the injection booster is mixed with water in a certain proportion and injected into the oilfield by a specific process, the water injection pressure can be significantly reduced. The contact angle of the core surface treated with nano-water-based injection agent solution is greater than 90°, but the disadvantage is that the hydrophobicity is insufficient, which limits the application in oilfield water injection

Method used

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  • Nanometer drag reducer for sandstone surface pretreatment and preparation method of nanometer drag reducer
  • Nanometer drag reducer for sandstone surface pretreatment and preparation method of nanometer drag reducer
  • Nanometer drag reducer for sandstone surface pretreatment and preparation method of nanometer drag reducer

Examples

Experimental program
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Effect test

Embodiment 1

[0020] Pour 125g of surfactant tetradecyl α-olefin sulfonate, OP-1030g, 65g of PO-EO copolymer with molecular weight of 2400, 150g of auxiliary surfactant propylene glycol and 100g of triethanolamine into the mixer, mechanically Stir for 8 minutes, after stirring evenly, slowly add 30g of γ-(2,3 glycidoxy)propyltrimethoxysilane modified nano-silica at a speed of 5000r / min, keep stirring for 10 minutes after all the addition is complete, and then Keep the temperature in a water bath at 60°C for 20 minutes, pour it into a high-pressure homogenizer for dispersion, homogenization and emulsification to obtain 500 g of nano drag reducer 1 for sandstone surface pretreatment.

Embodiment 2

[0022] Pour 60g of surfactant dodecylbenzenesulfonate, OP-1060g, Span-8055g and co-surfactants 160g of isopropanol and 140g of glycerol into the mixer, mechanically stir for 12min at room temperature, and stir evenly Then slowly add 15g of γ-(2,3 glycidoxy) propyltrimethoxysilane modified nano silicon dioxide and 10g of γ-aminopropyl triethoxy silane modified nano silicon dioxide at a speed of 3000r / min. After adding all the silicon oxide, keep stirring for 8 minutes, then keep the temperature in a water bath at 60°C for 20 minutes, pour it into a high-pressure homogenizer for dispersion, homogenization and emulsification to obtain 500 g of nano drag reducer 2 for sandstone surface pretreatment.

Embodiment 3

[0024] Pour surfactant cetyl quaternary ammonium salt 80g, OP-1045g, Tween-8040g and auxiliary surfactant ethylene glycol 130g and glycerol 170g into the mixer, mechanically stir at normal temperature for 10min, after stirring evenly Slowly add 25g of nano-silica modified by N-β (aminoethyl) γ-aminopropyltrimethoxysilane and 10g of nano-silica modified by γ-chloropropyltrimethoxysilane at a speed of 6000r / min, all After the addition, keep stirring for 10 minutes, then keep the temperature in a water bath at 60°C for 30 minutes, pour into a high-pressure homogenizer to disperse, homogenize and emulsify to obtain 500 g of nano drag reducer 3 for sandstone surface pretreatment.

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Abstract

The invention relates to a nanometer drag reducer for the sandstone surface pretreatment and a preparation method of the nanometer drag reducer. The nanometer drag reducer comprises following components: 5-15% of nano-silica material modified by a silane coupling agent, 25-50% of surfactant and 40-70% of cosurfactant, wherein the surfactant is one or two kinds of an anion active agent, a cation surface active agent, a non-ionic surface active agent and an amphoteric surfactant. The nanometer drag reducer has the advantages that the nanometer drag reducer can be mixed with water in a certain proportion to form an uniform and transparent micro-emulsion, and diesel is replaced by water in the work progress, so that the construction cost is greatly lowered; the nanometer drag reducer can be firmly adsorbed on the surface of rocks so as to form a layer of strong nano hydrophobic membrane, so that the flow resistance of the formation water is effectively reduced and the water flooding effect is enhanced.

Description

technical field [0001] The invention belongs to the technical field of oilfield chemicals, in particular to a nano drag reducer for sandstone surface pretreatment and a preparation method thereof, which is a chemical additive capable of reducing water flow resistance in the near wellbore zone of a water injection well, and is especially suitable for low permeability oilfields Water injection development. Background technique [0002] As an irreplaceable basic energy, petroleum occupies a very important strategic position in the national economy. According to relevant statistics, as of the end of 2002, among the proven oil reserves in my country, the geological reserves of low-permeability oil reservoirs accounted for about 30.9%. The proportion of low-permeability reservoirs will be gradually increased, and low-permeability reservoirs will be an important reserve resource for the stable and increased production of oil and gas in my country for a considerable period of time i...

Claims

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Application Information

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IPC IPC(8): C09K8/86
Inventor 李俊华李俊莉周会强王佳
Owner SHAANXI RES DESIGN INST OF PETROLEUM CHEM IND
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