Special modified thermoset ultrahigh-molecular epoxy resin electric-strip fastener baffle seat for railway track

An epoxy resin and ultra-high polymer technology, applied in the direction of fixed rails, roads, tracks, etc., can solve problems such as uneven strength, failure to meet strength requirements, backward technology, etc., to avoid linear expansion coefficient and excellent mechanical properties , perfect size effect

Inactive Publication Date: 2013-03-06
HANGZHOU DAGU NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the chain molecular structure of thermoplastic resin, many molecular chains are combined together by physical action. Due to the limitation of its process, the amount of residual low molecular solvent in the drying process cannot be guaranteed to overflow completely. The arrangement is not uniform, and the residual solvent cannot escape completely, resulting in uneven strength per unit area. There are bubbles in it, which cannot guarantee the consistency of material strength and quality, making this composite material unable to be used in some special high-demand products such as rail fasteners. , automotive gearboxes, pressure vessels, ship plates, armor protection, etc. to replace existing metal materials
[0004] The epoxy resin hand lay-up process currently used for composite materials, due to the backward process, the resin content cannot be accurately controlled, and the quality cannot be guaranteed. In addition, it uses ordinary epoxy resin and curing crosslinking agent, which cannot meet the requirements of replacing metal materials. strength requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Embodiment 1: a kind of modified thermosetting ultra-high polymer epoxy resin railway special elastic strip type fastener baffle seat, it is characterized in that the modified thermosetting epoxy resin containing 12-18% by weight, 4-6% by weight Hyperbranched curing cross-linking agent, 60-86% by weight of fibrous reinforcement, 5.5-8.5% by weight of powder reinforcement additive.

[0014] The modified thermosetting epoxy resin contains 14-16% (14% or 14.8% or 15% or 15.5% or 16%) of bisphenol A epoxy resin and 0.15-0.25% (0.15% or 0.2% or 0.25%) by weight of polyether-modified methyltetrahydrophthalic anhydride toughener; the 14-16% by weight of bisphenol A epoxy resin is composed of E-51 epoxy resin and E-44 ring Oxygen resin is formed in a ratio of 2:1; the hyperbranched imidazole amidated derivative curing agent is made of trimethylolpropane 15-20% (15% or 16% or 17% or 18% or 19% or 20%), 2,2-dimethylolpropionic acid 15-21% (15% or 16% or 17% or 18% or 19% or 20% ...

Embodiment 2

[0018] Embodiment 2: On the basis of embodiment 1, the modified thermosetting epoxy resin containing 15% by weight, the hyperbranched curing crosslinking agent of 5% by weight, the fibrous reinforcing material of 73% by weight, 7% by weight powder reinforcement additives.

Embodiment 3

[0019] Embodiment 3: On the basis of Embodiment 1 or 2, a method for preparing a modified thermosetting ultra-high molecular weight epoxy resin railway special elastic strip fastener baffle seat, 12-18% by weight of the modified thermosetting ring Oxygen resin and 5.5-8.5% by weight of powder reinforcing material additives are mixed and ground to form a uniform slurry, and 4-6% by weight of hyperbranched curing cross-linking agent is added in proportion to stir evenly, and then infiltrate quantitative 60-86% The fiber reinforced material in parts by weight is made into a thick paste or paste prepreg with a viscosity of 50000-100000Pa.S, and then the prepreg is placed in a heated mold (155-165°C), and 1000KN is applied after exhausting The above pressure is controlled at 165-175° C., and secondary curing is performed for 3-6 minutes to obtain the finished modified thermosetting ultra-high molecular epoxy resin railway-specific elastic strip fastener baffle seat. The impregnated...

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PUM

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Abstract

The invention relates to a special modified thermoset ultrahigh-molecular epoxy resin electric-strip fastener baffle seat for a railway track, which is high in corrosion resistance and weather resistance as well as intensity, and can achieve performance like that of low carbon steel (such as a Q235 steel workpiece the intensity of which can meet the requirement stated in GB/T700-1988Q235). The baffle seat comprises the following raw materials in percentage by weight: 12% to 18% of modified thermoset epoxy resin, 4% to 6% of hyperbranched curing cross-linking agent, 60% to 86% of fibrous reinforcing materials and 5.5% to 8.5% of power reinforced material additives. The baffle seat provided by the invention has the advantages that a molecular structure contains not only a great amount of flexible segments for relieving crisp and rigidity of the epoxy resin, but also end-capped epoxy groups which can participate in curing reaction, so that a toughening effect is obvious, the bonding strength of a system is improved, and the compression strength and the shearing strength of the materials are improved greatly.

Description

technical field [0001] The invention relates to a modified thermosetting ultra-high polymer epoxy resin specially used for railways, which has good corrosion resistance, good weather resistance, high strength, and performance that can reach low-carbon steel (such as the strength requirements of Q235 steel workpieces specified in GB / T700-1988 Q235). The utility model relates to a baffle plate seat of an elastic strip type fastener, which belongs to the field of manufacturing modified polymer plates. Background technique [0002] At present, the raw materials used for the baffle seats of type I and II railway clips are metal carbon steel, nylon 6 (polyamide 6) and modified nylon 66 (modified polyamide 66). Not resistant to rust, rusted workpieces quickly lose their proper performance; nylon 6 baffle seat and modified nylon 66 due to their structural characteristics (anti-fatigue strength loss and low temperature difference, etc.) Embrittlement generally occurs in arid areas, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L63/02E01B9/00C08G59/48C08G59/20C08K13/04C08K7/14C08K7/06C08K7/10C08K3/04C08K3/34B29C43/02B29C43/58
CPCE01B9/62E01B9/00C08L63/00
Inventor 高原
Owner HANGZHOU DAGU NEW MATERIAL
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