Carbon monoxide room-temperature catalytic oxidation catalyst and preparation method thereof
A technology for catalytic oxidation and carbon monoxide, applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, chemical instruments and methods, etc., can solve problems such as difficult to reach 100%, poor elimination ability, etc., and achieve high catalytic oxidation efficiency and good stability The effect of sex and simple process
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Embodiment 1
[0022] (1) Mix 64g of cerium ammonium nitrate and 200g of urea, heat the solution to 90°C, react for 4-5h, filter and wash, and roast at 400°C for 4-5h;
[0023] (2) Accurately weigh 0.076g of palladium chloride powder and 0.107g of copper chloride, and dissolve them in 5mL of 25% ammonia solution;
[0024] (3) Immerse 2g of the cerium oxide carrier into the prepared palladium chloride solution, mix the carrier with the impregnating solution, fully mix evenly under the action of electromagnetic stirring, immerse at room temperature for 24 hours and let it cool naturally at 25-35°C. drying;
[0025] (4) Calcining the prepared powder at 300° C. for 4 hours to obtain the required palladium chloride-copper chloride / cerium oxide catalyst.
[0026] Catalyst evaluation method: The catalytic oxidation reaction of carbon monoxide at room temperature was evaluated in an atmospheric fixed-bed microreactor (8 mm inner diameter). The raw gas composition used is: CO: 50ppm, the rest is ai...
Embodiment 2
[0029] (1) Mix 32g of cerium ammonium nitrate and 200g of urea, heat the solution to 90°C, react for 4-5h, filter and wash, and roast at 400°C for 4-5h;
[0030] (2) Accurately weigh 0.076g of palladium chloride powder and 0.107g of copper chloride, and dissolve them in 5mL of 25% ammonia solution;
[0031] (3) Immerse 2g of the cerium oxide carrier into the prepared palladium chloride solution, mix the carrier with the impregnating solution, fully mix evenly under the action of electromagnetic stirring, impregnate at room temperature for 24 hours and let it cool naturally at 25-35°C. drying;
[0032] (4) Calcining the prepared powder at 300° C. for 4 hours to obtain the required palladium chloride-copper chloride / cerium oxide catalyst.
[0033] Catalyst evaluation method: The catalytic oxidation reaction of carbon monoxide at room temperature was evaluated in an atmospheric fixed-bed microreactor (8mm inner diameter). The raw gas composition used is: CO: 50ppm, the rest is ...
Embodiment 3
[0036] (1) Accurately weigh 0.076g of palladium chloride powder and 0.107g of copper chloride, and dissolve them in 5mL of 25% ammonia solution;
[0037] (2) Immerse 2g of titanium oxide carrier into the prepared palladium chloride solution, mix the carrier and impregnating solution, fully mix evenly under the action of electromagnetic stirring, impregnate at room temperature for 24 hours, and naturally drying;
[0038] (3) Calcinate the prepared powder at 300°C for 4 hours to obtain the required catalyst.
[0039]Catalyst evaluation method: The catalytic oxidation reaction of carbon monoxide at room temperature was evaluated in an atmospheric fixed-bed microreactor (8 mm inner diameter). The raw gas composition used is: CO: 50ppm, the rest is air, the space velocity is 30000mL / (gh), and the catalyst mass is 0.4g. The feed gas passes directly through the catalyst bed. Use Fuli 7970III gas chromatograph to analyze product composition, carbon molecular sieve column separation...
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