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Organic-silicon pouring sealant composition with high thermal conductivity and application thereof

A technology of organic silica gel and composition, which is applied in the treatment of dyed organic silicon compounds, other chemical processes, fibrous fillers, etc., can solve the problem of limited surface coating effect of inorganic powders, increase the viscosity of thermally conductive silicone mixtures, and silicone mixtures Viscosity increase and other problems, achieve good organic coating effect, prevent the increase of adhesive viscosity, and reduce the effect of van der Waals force

Active Publication Date: 2013-05-15
FOSHAN SANSHUI JINGE NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The above-mentioned method of treating alumina organically can reduce the processing viscosity of organic silicon materials to a certain extent, and increase its addition amount in resin, but there are still the following deficiencies: (1) small molecular weight coupling agents, due to organic molecular chain segments Short, the coating effect on the surface of inorganic powder is limited; (2) The long chain of silicone is conducive to coating the surface of the powder, and has good compatibility with the resin, but it will also interact with the molecular chain segment of the resin Form entanglement between them, especially when the powder filling amount is large, to a certain extent, through the bridging effect of the powder particles, the resin molecular segments are physically cross-linked, thereby increasing the viscosity of the thermally conductive silicone mixture , affecting its construction process
The thermal conductivity of the obtained silicone material can be improved by increasing the filling amount of alumina powder, but this in turn will lead to an increase in the viscosity of the silicone mixture

Method used

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  • Organic-silicon pouring sealant composition with high thermal conductivity and application thereof
  • Organic-silicon pouring sealant composition with high thermal conductivity and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0050] This example is used to illustrate the silicone potting compound composition provided by the present invention and its preparation method.

[0051] Add 1000g of α-alumina powder (average particle size of 30μm) and 400g of isobutanol into a 2L reaction kettle, heat the formed suspension to 90°C while stirring, and add 4g of vinyl tris (β-methoxyethoxy) silane, after 90min of heat preservation, stop heating, after the temperature drops to room temperature, add 50g of polymethylvinylsiloxane (ethylene content is 1.2% by weight, viscosity at 25°C is 100mm 2 / s) and 3g of hydrogen-containing silicone oil (hydrogen content 1.5% by weight, viscosity at 25°C is 30mm 2 / s), then drip the ethanol solution 100g (concentration is 1.5% by weight) of the platinum complex compound coordinated by methylpolysiloxane, the rate of addition is 5g / min, after the dropwise addition, continue to stir for 4h, and suction filter , put the obtained powder into a blast oven at 100° C. for 2 hours...

Embodiment 2

[0070] This example is used to illustrate the silicone potting compound composition provided by the present invention and its preparation method.

[0071] Except that 600 g of the silicone-coated alumina prepared in Example 1 was weighed for components A and B, instead of 400 g, the rest was the same as that of Example 1.

Embodiment 3

[0080] This example is used to illustrate the silicone potting compound composition provided by the present invention and its preparation method.

[0081] Except that components A and B weigh 900 g of the silicone-coated alumina prepared in Example 1 instead of 400 g, the rest is the same as that of Example 1.

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Abstract

The invention provides an organic-silicon pouring sealant composition with high thermal conductivity and an application thereof. The composition comprises a component A and a component B, wherein the component A comprises 100 parts of vinyl silicone oil, 6-14 parts of hydrogen silicone oil, 400-1000 parts of organic-silicon coated alumina powder and 0.1-0.8 part of inhibitor; and the component B comprises 100 parts of vinyl silicone oil, 400-1000 parts of organic-silicon coated alumina powder and 0.2-1.5 parts of catalyst. The composition can still achieve high alumina addition volume under the premise of ensuring low viscosity of the organic-silicon pouring sealant, thus improving the thermal conductivity of the pouring sealant.

Description

technical field [0001] The invention relates to a high thermal conductivity silicone potting adhesive composition and its application, in particular to a high thermal conductivity two-component silicone potting adhesive composition, which is especially suitable for potting applications in electronic appliances. Background technique [0002] Insulating thermally conductive silicone materials not only overcome the shortcomings of the traditional methods of solving the heat dissipation of electronic equipment, such as laying a layer of insulating medium between the heating element and the radiator as a thermally conductive material (such as mica, beryllium oxide ceramics, etc.). Poor performance, low mechanical properties, high price and other disadvantages, but also has good thermal conductivity, high and low temperature resistance, high elasticity, excellent insulation, and light weight, easy processing and excellent fatigue resistance, etc., for the improvement of electrical ...

Claims

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Application Information

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IPC IPC(8): C08L83/07C08L83/05C08K9/10C08K9/06C08K3/22C09C1/40C09C3/12C09K3/10
Inventor 姜宏伟程宪涛
Owner FOSHAN SANSHUI JINGE NEW MATERIALS CO LTD
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