Epoxy-terminated silicon oil modified carboxyl-terminated hyperbranched polyester, and preparation method and application thereof
A technology of hyperbranched polyester and epoxy-terminated silicone oil, applied in polyester coatings, coatings, etc., can solve the problems of cracking, poor flexibility of carboxyl-terminated hyperbranched polyester, etc., achieve high heat resistance, improve heat resistance , the effect of good flexibility
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[0040] Example 1
[0041] 1) Preparation of epoxy-terminated silicone oil
[0042] After adding 200g of octamethylcyclotetrasiloxane, 0.02g of tetramethylammonium hydroxide and 4g of concentrated sulfuric acid to the reactor equipped with condenser, thermometer, dropping funnel and stirrer according to the ratio, the reaction was protected by nitrogen for 7h The temperature was raised to 180°C, and the low-boiling substances were removed under reduced pressure to obtain the terminal hydrogen silicone oil; the prepared terminal hydrogen silicone oil, 2 g of allyl glycidyl ether, 200 g of toluene and 0.02 g of chloroplatinic acid were added to the reactor; The reaction was performed at 70°C under nitrogen protection for 8 hours, and the solvent was distilled off under reduced pressure to obtain epoxy-terminated silicone oil. The weight average molecular weight of the epoxy-terminated silicone oil was detected by gel permeation chromatography, and the result was 1015; the result was ...
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[0055] Example 2:
[0056] 1) Preparation of epoxy-terminated silicone oil
[0057] After adding 200g of octamethylcyclotetrasiloxane, 0.02g of tetramethylammonium hydroxide and 4g of concentrated sulfuric acid to the reactor equipped with condenser, thermometer, dropping funnel and stirrer, the reaction was protected by nitrogen for 7h; At 190°C, the low-boiling substances were removed under reduced pressure to obtain the hydrogen-terminated silicone oil; the obtained hydrogen-terminated silicone oil, 2g of allyl glycidyl ether, 200g of toluene and 0.02g of chloroplatinic acid were added to the reactor; The reaction was protected for 8.0 h, and the solvent was distilled off under reduced pressure to obtain epoxy-terminated silicone oil.
[0058] The weight average molecular weight of epoxy-terminated silicone oil was detected by gel permeation chromatography, and the result was 1015; the epoxy value content of epoxy-terminated silicone oil was determined by the hydrochloric acid-ac...
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[0070] Example 3:
[0071] 1) Preparation of epoxy silicone oil
[0072] After adding 200g of octamethylcyclotetrasiloxane, 0.06g of tetramethylammonium hydroxide and 10g of concentrated sulfuric acid into a reactor equipped with a condenser, a thermometer, a dropping funnel and a stirrer, the reaction was protected by nitrogen for 8h; At 185°C, distill under reduced pressure to remove low boilers to obtain hydrogen-terminated silicone oil; add the obtained hydrogen-terminated silicone oil, 18 g of allyl glycidyl ether, 350 g of toluene and 0.07 g of chloroplatinic acid into the reactor; increase the temperature to 80° C., The reaction was protected for 9 hours, and the solvent was distilled off under reduced pressure to obtain epoxy-terminated silicone oil.
[0073] The weight average molecular weight of the epoxy-terminated silicone oil was measured by gel permeation chromatography, and the result was 492; the epoxy value content of the epoxy-terminated silicone oil was determined...
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