Colored photosensitive resin composition, color filter and display device
A photosensitive resin and composition technology, applied in the field of color filters and display devices, and colored photosensitive resin compositions, can solve the problems of insoluble, incapable of making high-contrast color filters, etc., and achieve excellent stability over time Effect
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Embodiment 1
[0078] After mixing each of the following components and stirring the mixture for 1 hour, it filtered through a 5 μm membrane filter to prepare a colored photosensitive resin composition.
[0079] · Alkali soluble resin
[0080] Resin A (solid content 55%, solvent: 3-methoxybutyl acetate)
[0081] …60 parts by mass
[0082] ·Photopolymerizable monomer
[0083] Dipentaerythritol hexaacrylate (manufactured by Nippon Kayaku Co., Ltd.)...25 parts by mass
[0084] ·Photopolymerization Initiator
[0085] 1-[9-Ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]-ethanone-1-(O-acetyloxime) "IRGACURE OXE-02" (trade name : Made by BASF Corporation)
[0086] …15 parts by mass
[0087] ·Inorganic pigments
[0088] Carbon dispersion liquid "CF BLACK" (trade name: manufactured by Mikuni Color Co., Ltd., solid content 25% Solvent: 3-methoxybutyl acetate ... 400 parts by mass
[0089] ·Solvent
[0090] 3-methoxybutyl acetate / 1,1,3,3-tetramethylurea / propylene glycol monomethyl acetate=55 / 10 / 35...
Embodiment 2~10 and comparative example 1~9
[0098] Except having changed the mixing ratio (mass ratio) of a solvent as shown in Table 1, it carried out similarly to Example 1, and prepared the colored photosensitive resin composition.
[0099] [Table 1]
[0100]
[0101] MBA: 3-methoxybutyl acetate
[0102] PGME A: Propylene Glycol Monomethyl Ether Acetate
[0103] EL: ethyl lactate
[0104] Ethyl Cellosolve: Ethylene Glycol Monoethyl Ether
[0105] AN: Cyclohexanone
[0106] γ-BL: γ-butyrolactone
[0107] δ-VL: δ-valerolactone
[0108] ε-CL: ε-caprolactone
[0109] TMU: 1,1,3,3-Tetramethylurea
[0110] DMF: Dimethylformamide
[0111] DMAC: Dimethylacetamide
[0112] DMI: 1,3-Dimethyl-2-imidazolinone
[0113]
[0114] [Evaluation of Viscosity Stability]
[0115] About the colored photosensitive resin composition of Examples 1-10 and Comparative Examples 1-9, the viscosity was measured using the E-type viscometer at the initial stage of preparation and after storage at 25 degreeC for 7 days, and the visco...
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