Solventless polyurethane adhesive and method for paper plastic packaging
A polyurethane adhesive, solvent-free technology, applied in the direction of adhesive additives, non-polymer adhesive additives, etc., can solve the problem of high cost of hot melt adhesives, and achieve the effects of cost saving, fast curing speed, and strong adaptability
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Embodiment 1
[0030] First synthetic special polyester polyol A, the composition of this polyester polyol A is as follows:
[0031] Adipic acid: 47%
[0032] Isophthalic acid: 3.9%
[0033] Diethylene glycol: 32%
[0034] 2-Methyl-1,3-propanediol: 10%
[0035] Neopentyl glycol 7.1%
[0036] The obtained polyester polyol A has a molecular weight of 850, a moisture content of 300ppm, and an acid value of 1.2
[0037] Then through the following formula design, the composition is as follows:
[0038] Polyester polyol A33.5%
[0039] Polyether polyol (molecular weight 1000) 20%
[0040] Polyether polyol (molecular weight 2000) 15%
[0041] 4,4'-Diphenylmethane diisocyanate (MDI) 30%
[0042] Anilinomethyltriethoxysilane: 1%
[0043] 1,4-Butanediol 0.48%
[0044] Bis(2,2-morpholine ethyl) ether 0.02%
[0045] The preparation process is as follows:
[0046] a. Ensure that the moisture content of polyester and polyether polyols is less than 350ppm, and the maximum cannot exceed 1000ppm,...
Embodiment 2
[0053] First synthetic special polyester polyol B, the composition of this polyester polyol B is as follows:
[0054] Adipic acid: 45%
[0055] Isophthalic acid: 10.2%
[0056] Diethylene glycol: 18%
[0057] 2-Methyl-1,3-propanediol: 20.6%
[0058] Neopentyl glycol 5.9%
[0059] 1,6-Hexanediol 0.3%
[0060] Then through the following formula design, the composition is as follows:
[0061] Polyester polyol B23.5%;
[0062] Polyether polyol (molecular weight 1000, ethylene oxide (EO) content is 15%) 22%;
[0063] Polyether polyol (molecular weight 3000) 20%;
[0064] 4,4'-Diphenylmethane diisocyanate (MDI) 34%;
[0065] γ-glycidyl etheroxypropyl trimethoxysilane: 0.5%;
[0066] Stannous octoate 0.005%
[0067] The preparation process is as follows:
[0068] a. Ensure that the moisture content of polyester and polyether polyols is less than 350ppm, and the maximum cannot exceed 1000ppm, and take necessary measures to remove moisture;
[0069] b Add polyester polyol A...
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