Method for detecting phenolic antibacterial agents in textiles through in-situ derivatization and dispersive liquid phase microextraction

A technology for dispersion liquid and textiles, applied in the field of product safety and detection, can solve the problems of inability to detect chlorophenol and o-phenylphenol at the same time, consumption of organic solvents, long detection process time, etc., and achieves low cost, environmental friendliness, Simple to use effects

Inactive Publication Date: 2013-07-24
中华人民共和国苏州出入境检验检疫局
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

[0006] The technical problem to be solved by the present invention is to provide a method that integrates sampling, extraction and concentration, is simple, fast, low-cost, environmentally friendly and has high enrichment efficiency, and realizes the detection of phenolic antibacterial agents in textiles. Solve the problems in the prior art that the processing and detection process takes a long time, consumes a large amount of organic solvents, and cannot detect various chlorophenols and o-phenylphenols at the same time

Method used

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  • Method for detecting phenolic antibacterial agents in textiles through in-situ derivatization and dispersive liquid phase microextraction
  • Method for detecting phenolic antibacterial agents in textiles through in-situ derivatization and dispersive liquid phase microextraction
  • Method for detecting phenolic antibacterial agents in textiles through in-situ derivatization and dispersive liquid phase microextraction

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Embodiment

[0042] Example In situ derivatization-dispersive liquid phase microextraction-gas chromatography / mass spectrometry detection of phenolic antibacterial agents in textiles

[0043] 1 Materials and methods

[0044] 1.1. Instruments and reagents:

[0045] Gas chromatography-mass spectrometer (6890A / 5975C, Agilent, USA), DB-5MS capillary column (30m×0.25mm×0.25μm); BUCHI R-215 rotary evaporator, equipped with circulating cooling water system (Buehi, Switzerland); KQ5200DE Type ultrasonic cleaner (Kunshan Ultrasonic Co., Ltd.); MettlerAL204 analytical balance (Mettler-Toledo, Shanghai). 2,4,6-Trichlorophenol, 2,3,5,6-tetrachlorophenol, 2,3,4,5-tetrachlorophenol, 2,3,4,6-tetrachlorophenol, pentachlorophenol, O-phenylphenol (Dr. Ehrenstorfer, Germany); dichloromethane, chloroform, carbon tetrachloride, chlorobenzene, methanol, acetonitrile, acetone, isopropanol (all chromatographically pure); acetic anhydride, potassium carbonate ( All were analytically pure); water was high-purity...

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Abstract

The invention discloses a method for detecting phenolic antibacterial agents in textiles through the combined use of in-situ derivatization, dispersive liquid phase microextraction and gas chromatography / mass spectrometry. A technical program suitable for the simultaneous detection on five types of chlorinated phenols and o-phenylphenol in the textiles is established, a target compound is extracted by utilizing a dispersive liquid phase microextraction technology after being subjected to extraction and derivatization, and qualitative and quantitative analysis is carried out by using a gas chromatograph / mass spectrometer. The method can be applicable to the determination of the five types of chlorinated phenols and o-phenylphenol in the textiles such as clothes, fiber packing, yarns, clothing materials and household decoration products. The method is simple and rapid to operate, low in cost, environment-friendly and high in enrichment efficiency.

Description

technical field [0001] The invention belongs to the technical field of product safety and detection, and specifically relates to a method for detecting phenolic antibacterial agents in textiles by in-situ derivation-dispersion liquid phase microextraction-gas chromatography / mass spectrometry Background technique [0002] Chlorine-containing phenolic compounds (pentachlorophenol PCP, tetrachlorophenol TeCP, trichlorophenol TCP, etc.) and o-phenylphenol (OPP) are commonly used as fungicides and preservatives, and their residues in leather and textiles have attracted much attention . With the continuous deepening of research on toxicity and toxicology, relevant laws, regulations and standards have been constantly amending the residue limits in textiles. [0003] At present, the pretreatment methods for the determination of chlorophenols and o-phenylphenols at home and abroad are mainly ultra-extraction, Soxhlet extraction or accelerated solvent extraction, high performance liq...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N30/06G01N30/88
Inventor 顾娟红朱振华陈军潘葵柳艳严敏
Owner 中华人民共和国苏州出入境检验检疫局
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