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Tantalum tape and preparation method thereof

A technology of tantalum powder and pickling, applied in the field of metal materials, can solve the problems of uneven grain size of tantalum strips, poor isotropy of plates, difficulty in achieving high performance and high reliability, etc.

Active Publication Date: 2013-08-14
NINGXIA ORIENT TANTALUM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the grain size of the tantalum strips produced by the above process is not uniform, and there are large grains; the isotropy of the final plate is poor, and there is a big difference between the mechanical properties of the other directions and the transverse and longitudinal directions, so that the tantalum strips can be used in deep drawing. Cracking, wrinkling, orange peel, and earing are easy to occur when stretching the tantalum shell, which will result in low yield of tantalum capacitors, and it is difficult to meet the requirements of high performance and high reliability.

Method used

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Examples

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preparation example Construction

[0020] The embodiment of the present invention discloses a method for preparing a tantalum strip, which includes the following steps:

[0021] a) Sintering the tantalum powder to obtain a tantalum rod, and forging the tantalum rod;

[0022] b) rolling the tantalum rod obtained in step a), and heat-treating the rolled tantalum rod;

[0023] c) Rolling the tantalum strip obtained in step b) again, and heat-treating the tantalum strip obtained by rolling again to obtain a tantalum strip.

[0024] According to the present invention, in order to make the final tantalum strip have a uniform and fine internal structure, in the process of preparing the tantalum strip, the method of powder sintering is used to prepare the tantalum rod. The tantalum rod prepared by powder sintering has a fine and uniform internal structure, and the tantalum rod prepared by this method can ensure that the final product has high tensile strength and elongation. The sintering temperature is 2350°C-2450°C...

Embodiment 1

[0034] 1) Put tantalum powder with a purity of 99.95wt% in a vacuum sintering furnace for two sinterings at a temperature of 2350-2450°C for 6-8 hours to obtain a tantalum rod with a diameter of 30mm and a length of 700mm ;

[0035] 2) The tantalum rod obtained in step 1) is cold-forged with a 10,000-ton hydraulic press, that is, the tantalum rod is radially flattened, and the forging processing rate is controlled to 60%;

[0036] 3) Pickling the tantalum rod obtained in step 2): the volume ratio of hydrofluoric acid, nitric acid and hydrochloric acid is 1:2:3, the concentration of hydrofluoric acid is 35.35wt%, the concentration of nitric acid is 68wt%, and the concentration of hydrochloric acid The concentration is 30wt%, and the metallic luster can be seen without speckles by naked eyes;

[0037] 4) Cold rolling the tantalum rod obtained in step 3), first widening the tantalum rod and then reverse rolling, the processing rate of rolling is 60%;

[0038] 5) Heat treatment th...

Embodiment 2

[0046] 1) Put carbon powder with a purity of 99.95wt% in a vacuum sintering furnace for two sinterings at a temperature of 2350-2450°C for 6-8 hours to obtain a tantalum rod with a diameter of 32mm and a length of 650mm ;

[0047] 2) Radially flatten the tantalum rod obtained in step 1) with a 10,000-ton hydraulic press to obtain a tantalum rod with a width of 60 mm and a length of 700 mm;

[0048] 3) Pickling the tantalum rod obtained in step 2): the volume ratio of hydrofluoric acid, nitric acid and hydrochloric acid is 1:2:3, the concentration of hydrofluoric acid is 35.35wt%, the concentration of nitric acid is 68wt%, and the concentration of hydrofluoric acid is 68wt%. The concentration is 30wt%, and the metallic luster can be seen without specks by naked eyes;

[0049] 4) Cold rolling the tantalum rods obtained in step 3): first widen the tantalum rods and then perform reverse rolling to obtain tantalum rods with a width of 100mm and a length of 1600mm;

[0050] 5) Hea...

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Abstract

The invention relates to the technical field of metal materials. The invention provides a tantalum tape and a preparation method thereof. The preparation method of the tantalum tape particularly comprises the steps of: a) sintering tantalum powder to obtain a tantalum rod and forging the tantalum rod; b) rolling the tantalum rod obtained in the step a) and carrying out heat treatment for a tantalum strip obtained by rolling; c) rolling the tantalum strip obtained in the step b) again, and carrying out the heat treatment again for the tantalum strip obtained by rolling so as to obtain the tantalum tape. In the process of preparing the tantalum tape, the initial tantalum rod with uniform and fine crystal particles is firstly obtained through high-temperature sintering; then the tantalum rod is forged to be deformed; and finally, the tantalum rod is subjected to rolling for twice to enable the tantalum rod to be machined in multiple directions and facilitate to uniformity of the tantalum rod in each direction. Meanwhile, heat treatment is carried out after the rolling, so that residual stress in the machining process is removed, and the finally prepared tantalum tape is composed of uniform and fine isometric crystals.

Description

technical field [0001] The invention relates to the technical field of metal materials, in particular to a tantalum strip and a preparation method thereof. Background technique [0002] Tantalum and tantalum alloys have high melting point, good electrical and thermal conductivity, high chemical stability, excellent high temperature strength, good processing performance, low plastic-brittle transition temperature, excellent kinetic properties, and the surface forms dense, The advantages of stability and high dielectric constant are widely used in the fields of electronics, chemical industry, aerospace, military weapons, medical and health, etc., and are known as the rising star in the "Kingdom of Metals". Metal tantalum is mainly used in the electronics industry, among which tantalum capacitors are widely used in communications, computer integrated circuits, automotive electronic control systems and digital appliances due to their small size, large capacity, high reliability,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F3/17C22F1/18
Inventor 李桂鹏张亚军汪凯张全朱军李瑞莲
Owner NINGXIA ORIENT TANTALUM IND
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