Tantalum tape and preparation method thereof
A technology of tantalum powder and pickling, applied in the field of metal materials, can solve the problems of uneven grain size of tantalum strips, poor isotropy of plates, difficulty in achieving high performance and high reliability, etc.
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[0020] The embodiment of the present invention discloses a method for preparing a tantalum strip, which includes the following steps:
[0021] a) Sintering the tantalum powder to obtain a tantalum rod, and forging the tantalum rod;
[0022] b) rolling the tantalum rod obtained in step a), and heat-treating the rolled tantalum rod;
[0023] c) Rolling the tantalum strip obtained in step b) again, and heat-treating the tantalum strip obtained by rolling again to obtain a tantalum strip.
[0024] According to the present invention, in order to make the final tantalum strip have a uniform and fine internal structure, in the process of preparing the tantalum strip, the method of powder sintering is used to prepare the tantalum rod. The tantalum rod prepared by powder sintering has a fine and uniform internal structure, and the tantalum rod prepared by this method can ensure that the final product has high tensile strength and elongation. The sintering temperature is 2350°C-2450°C...
Embodiment 1
[0034] 1) Put tantalum powder with a purity of 99.95wt% in a vacuum sintering furnace for two sinterings at a temperature of 2350-2450°C for 6-8 hours to obtain a tantalum rod with a diameter of 30mm and a length of 700mm ;
[0035] 2) The tantalum rod obtained in step 1) is cold-forged with a 10,000-ton hydraulic press, that is, the tantalum rod is radially flattened, and the forging processing rate is controlled to 60%;
[0036] 3) Pickling the tantalum rod obtained in step 2): the volume ratio of hydrofluoric acid, nitric acid and hydrochloric acid is 1:2:3, the concentration of hydrofluoric acid is 35.35wt%, the concentration of nitric acid is 68wt%, and the concentration of hydrochloric acid The concentration is 30wt%, and the metallic luster can be seen without speckles by naked eyes;
[0037] 4) Cold rolling the tantalum rod obtained in step 3), first widening the tantalum rod and then reverse rolling, the processing rate of rolling is 60%;
[0038] 5) Heat treatment th...
Embodiment 2
[0046] 1) Put carbon powder with a purity of 99.95wt% in a vacuum sintering furnace for two sinterings at a temperature of 2350-2450°C for 6-8 hours to obtain a tantalum rod with a diameter of 32mm and a length of 650mm ;
[0047] 2) Radially flatten the tantalum rod obtained in step 1) with a 10,000-ton hydraulic press to obtain a tantalum rod with a width of 60 mm and a length of 700 mm;
[0048] 3) Pickling the tantalum rod obtained in step 2): the volume ratio of hydrofluoric acid, nitric acid and hydrochloric acid is 1:2:3, the concentration of hydrofluoric acid is 35.35wt%, the concentration of nitric acid is 68wt%, and the concentration of hydrofluoric acid is 68wt%. The concentration is 30wt%, and the metallic luster can be seen without specks by naked eyes;
[0049] 4) Cold rolling the tantalum rods obtained in step 3): first widen the tantalum rods and then perform reverse rolling to obtain tantalum rods with a width of 100mm and a length of 1600mm;
[0050] 5) Hea...
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Abstract
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