Anti-counterfeiting element capable of dynamically sensing magnetic field position changes and manufacturing method of anti-counterfeiting element
A technology of anti-counterfeiting components and induction magnetic fields, which is applied in applications, computer components, authenticity inspection of banknotes, etc., can solve the problems of non-reversibility of optical effects, and achieve the effect of consistent optical colors
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Embodiment 1
[0028] Preparation of nanoparamagnetic materials:
[0029]Polyacrylic acid (PAA)-stabilized Fe3O4 nanoparticles were synthesized in one step by high-temperature pyrolysis. The specific experimental steps were as follows: First, weigh 2g (50mmol) sodium hydroxide (NaOH) and dissolve it in 20ml diethylene glycol (DEG), The mixed solution was heated to 120°C under nitrogen protection and kept stirring for one hour, then cooled to 70°C and stored for later use, and recorded as NaOH / DEG mixed solution. Weigh 4mmol of polyacrylic acid (PAA), 0.4mmol of ferric chloride (FeCl 3 ) was dissolved in 17ml of diethylene glycol (DEG), and the mixed solution was heated to 220°C under nitrogen protection and kept stirring for half an hour until a yellow transparent solution was formed. Take the newly prepared 1.75ml NaOH / DEG mixed solution and quickly inject it into the above solution, then lower the temperature to 210°C and keep it for one hour, then cool down and wash with deionized water ...
Embodiment 2
[0032] Preparation of capsules:
[0033] Put urea and 37% formaldehyde in a three-necked flask with a mass ratio of 1:2, add 30% triethanolamine to adjust the acidity, and keep the pH value at 7-8. Reflux in a 70°C water bath for 1 hour to form a water-soluble viscous transparent liquid, add 60-120ml of distilled water to dilute to obtain a urea-formaldehyde prepolymer. Add the blue electrophoretic solution to the urea-formaldehyde prepolymer, stir at 1250 rpm for 24 hours, and then use 20% glacial acetic acid to adjust the pH to 2-4. The formed microcapsules were washed with distilled water, filtered and dried to become free-flowing spherical capsules. The average particle size of the capsules is 46 microns. Example 3
Embodiment 3
[0034] Fabrication of anti-counterfeiting components that can dynamically sense changes in magnetic field positions
[0035] 30 grams of embodiment 2 capsules are mixed with 70 grams of transparent UV-curable varnish to form ink, and the mixed ink is coated on the black PET film with a scraper, and the coating thickness is 300 microns, and the appropriate solvent is evaporated, and then The ink is cured with UV light. The produced film can produce a visible light band rolling effect as the position of the magnetic field changes.
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